Subject: Re: How do I make Speed in message-id <4v4uv6$1oc$2@mhafn.production.compuserve.com>.,Jon Whale <106075.121@CompuServe.COM> transcends simple ignorance and enters the elite realm of absolute cluelessness by offering the following speculations: >Well that's a pretty good job too because the only speed recipe >they have there is bloody_bull_shit! and we offer the following example so that you may, in the future, be able recognize SPAM on a WebSite >It describes extraction of >d-methamphetamine from vicks inhalers. please reveal your source of Vicks Inhalers, that way all this SPAM about MethSynth will become 'academic' if you'll pardon the expression >Fistly, they don't even use >d-meth, they use phenylephrine, secondly, d-meth is inactive, So please mail all your d-meth to ME ! >l-meth is what you want, I'll trade ya gram for gram >and that d isn't gonna magically convert >to l. thank GOD for small favors > Now AFOAF tells me that meth is easily made by direct >hydrogenation of (pseudo)ephedrine over raney nickel or >palladium/charcoal in the presence of a little H2SO4. YFOAF is mistaken > This is a >very simple and efficient process which yields about 10% of mutant ephedrine salt that'll give you a special sort of speed Buzz you wish would go away >which can be done in your >kitchen provided you have a Parr hydrogenation flask well actually a Parr Hydrogenation Flask is a simple matter, it's the fuckin' apparatus that'll set you back 3 Grand > or some kind >of improvisation, make that 'careful improvisation' >and a canister of hydrogen (not to mention >getting the ephedrine in the first place...). None of these will make a difference, nor can you PETITION the Lord with PRAYER!! > >Hope this helps, Jon Whale It was somewhat entertaining, and you're a good guesser, you just happened to get every fucking detail WRONG this time.... but hang in there. All you guys that've been hangin' around here for years, once more, PLEASE excuse the redundancy of the repetitious redundancy again, once more, again. There HAS to be someone who hangs out here that has a job.... how about a small WebSite donation for a FAQ or an Archive or somethin'... neither Raney Nickel or Pd/C will work correct catalyst is Pd on BaSO4 Perchloric acid, not Sulfuric acid hydrogenation temperature is 80-90C, either the l-eph HCl or the p-fed HCl may be used In a pressure vessel, dissolve 100g ephedrine in 1 L glacial acetic acid, then add: 5 g of Pd on BaSO4 premoistened with the solvent 40mL of 70% perchloric acid Seal the vessel, flush with H2, heat blanket and shake at 80-90 C until H2 is no longer taken up (10-30min). Filter off the catalyst, precipitate the perchloric acid as the potassium salt with KOH soln. Evaporate the acetic acid under vaccuum. Take up the residue in water, make basic (~pH 11-12) with either KOH or NaOH soln, extract with ether (3x 100 mL), dry over MgSO4, bubble dry HCl through the dried ether and collect the precipitate. Yields 80-90% where modern hydrogenation practices are applied. Who says so? According to Hartung and Simonoff in chapter 5 of "Organic Reactions" the article is entitled "Hydrogenolysis of Benzyl Groups Attached to Oxygen, Nitrogen, or Sulfur", pp 263-326; "Hydrogenolysis of Benzyl Groups"], "The hydrochlorides of arylalpha-aminoalkyl ketones are reduced only to the amino alcohol when paladium catalyst is employed; however, if the amino ketone or the amino alcohol is hydrogenated in acetic acid at 80-90 C with palladium on barium sulfate in the presence of perchloric acid, excellent yields of the desoxy compound are obtained. It is suggested that in the presence of perchloric acid the reduction proceeds through the acetic acid ester of the amino alcohol." They reference Rosenmund and Karg, Ber., (Berichte Chemische), v 75, p 1850, 1942. the right hand Man sez: Presumably the reduction past the alcohol stage using the Pd/C method is hindered due to steric effects and/or activity of the catalyst. It is my guess that the reaction actually proceeds through an (-OH2)+ intermediate formed by protonation via the perchloric acid, which is then displaced on the catalyst surface by a hydrogen radical. Anyway, yields of 80% of the desoxyephedrine at 80-90 C using the Pd/BaSO4 in CH3COOH with HClO4 under 1 atm H2 is complete in about 30-45 minutes, with yields of the desired isomer of 75-85%. Higher yields are achieved starting with ephedrine, but the pseudo still yields typically 75-80% d-meth. -the Secular Cheminist -POPeye reports the Methamphetamine News at ADC