Hit 1

Reference List

FAIDE(1); FLST(31); XREF(9); RSTR(1); INP(51); CDER(4); PUR(2); MP(4); BP(18); DEN(11); MEC(1); ST(1); DV(1); OTHE(2); RI(27); OPT(2); ORP(1); NMR(4); IR(5); RAMAN(1); UV(9); FLU(1); MS(1); POT(2); LVSM(1); AZE(21); TRAM(2); ENEM(1); ASSM(3); PHARM(41); FINFO(1); RX(229); CNR(367)

Substance (1 of 1)
Beilstein Registry Number136380
Beilstein Preferred RN94-59-7
CAS Registry Number94-59-7
Chemical Name5-allyl-benzo[1,3]dioxole; 1-allyl-3,4-methylenedioxybenzene; safrole; 4-allyl-1,2-(methylenedioxy)benzene; 5-(2-propenyl)-1,3-benzodioxole
Autoname5-allyl-benzo[1,3]dioxole
Molecular FormulaC10H10O2
Molecular Weight162.19
Lawson Number21033
Compound Typeheterocyclic
Constitution ID120352
Tautomer ID109325
Beilstein Reference0-19-00-00039; 1-19-00-00617; 2-19-00-00029; 4-19-00-00275; 5-19-01-00553; 6-19
Entry Date1988/06/27
Update Date2002/07/19

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CODENGCITA9; CHBEAM
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Language CodeGE
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CODENYKKZAJ; CHZEA6
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Language CodeGE
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CODENGCITA9
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CODENRTCPA3
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CODENCZCAA5; CHZEA6
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Language CodeGE
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Document TypeJournal
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CODENCHBEAM
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CODENRTCPA3
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CODENJCSOA9; ZRKOAC
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CODENZRKOAC; CHZEA6
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CODENJCSOA9
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CODENCHZEA6
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CODENCHZEA6
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Document TypeJournal
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CODENPEORAA; CHZEA6
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Language CodeGE
(Series) Volume13; 93
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CODENCHZEA6
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(Series) Volume13; 94
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Publication Year1928
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CODENGCITA9
Journal TitleGazz.Chim.Ital.
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Publication Year1929
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Document TypeJournal
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CODENRTCPA3
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Document TypeJournal
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CODENJCSOA9
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CODENANCHAM
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Document TypeJournal
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CODENROCHAC; CHZEA6
Journal TitleRocz.Chem.; Chem.Zentralbl.
Language CodeGE
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Publication Year1938; 1939
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Document TypeJournal
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CODENBSCFAS
Journal TitleBull.Soc.Chim.Fr.
Publication Year1957
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Document TypeJournal
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CODENNPKZAZ
Journal TitleNippon Kagaku Zasshi
Journal/Review Without CODENChem.Abstr.
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Document TypeJournal
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CODENJACSAT
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CODENJACSAT
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CODENPHBUA9
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CODENBSCFAS
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Journal TitleYakugaku Zasshi
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Document TypeJournal
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Journal TitleNippon Kagaku Zasshi
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Document TypePatent
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Document TypeJournal
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CODENNPKZAZ
Journal TitleNippon Kagaku Zasshi
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Document TypeJournal
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CODENYKKZAJ
Journal TitleYakugaku Zasshi
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CODENCHINAG
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CODENCHBEAM
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CODENJLACBF
Journal TitleJustus Liebigs Ann. Chem.
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Document TypeJournal
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CODENJCSOA9
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Document TypeJournal
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CODENJCSOA9
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Document TypeJournal
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CODENJACSAT
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CODENCHBEAM
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Document TypeJournal
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CODENJACSAT
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Document TypeJournal
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CODENCHBEAM
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Journal/Review Without CODENTables azeotropiques, 2. Aufl. <Bruessel 1949>

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Document TypeJournal
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CODENASEFAR
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(Series) Volume<B> 44
Publication Year1948
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Document TypeJournal
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CODENJOCEAH
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Document TypeJournal
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CODENYKKZAJ
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Document TypeJournal
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CODENROCHAC; CHZEA6
Journal TitleRocz.Chem.; Chem.Zentralbl.
Language CodeGE
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Publication Year1936; 1937
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Document TypeJournal
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Publication Year1929
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Document TypeJournal
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Journal/Review Without CODENBer. Schimmel
Publication Year1929
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Document TypeJournal
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CODENZPCAAI
Journal TitleZ.Phys.Chem.Abt.A
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Publication Year1934
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Document TypeJournal
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Journal/Review Without CODENBl. Acad. Med. Belgique
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Document TypeJournal
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Journal/Review Without CODENPhys. Rad.
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Publication Year1931
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Document TypeJournal
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CODENCOREAF
Journal TitleC.R.Hebd.Seances Acad.Sci.
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Publication Year1931
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Document TypeJournal
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CODENRTCPA3
Journal TitleRecl.Trav.Chim.Pays-Bas
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Publication Year1938
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Document TypeJournal
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Journal/Review Without CODENRev. Quim. ind.
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Document TypeJournal
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Journal/Review Without CODENBl. Acad. Med. Belgique
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Document TypeJournal
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CODENJPHAA3
Journal TitleJ.Am.Pharm.Assoc.
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Publication Year1938
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Document TypeJournal
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CODENNKAKB8
Journal TitleNippon Kagaku Kaishi
Journal/Review Without CODENChem.Abstr.
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Publication Year1944; 1947
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Document TypeJournal
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CODENNKAKB8
Journal TitleNippon Kagaku Kaishi
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Document TypeJournal
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CODENJPRSA5
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Publication Year1928
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Document TypeJournal
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CODENYKKZAJ
Journal TitleYakugaku Zasshi
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Document TypeBook Review / Secondary Ref.
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Document TypeJournal
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CODENYKKZAJ; CHZEA6
Journal TitleYakugaku Zasshi; Chem.Zentralbl.
Language CodeGE
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NumberII
Publication Year1937; 1937
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Document TypeJournal
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CODENGCITA9
Journal TitleGazz.Chim.Ital.
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Publication Year1952
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Document TypeJournal
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CODENYKKZAJ
Journal TitleYakugaku Zasshi
Journal/Review Without CODENChem.Abstr.
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Document TypeJournal
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CODENYKKZAJ
Journal TitleYakugaku Zasshi
Journal/Review Without CODENChem.Abstr.
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Publication Year1952; 1953
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Document TypeJournal
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CODENYKKZAJ
Journal TitleYakugaku Zasshi
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CODENJLACBF
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CODENBSCFAS
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CODENPHBUA9
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Document TypeJournal
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CODENYKKZAJ
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Journal/Review Without CODENChem.Abstr.
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Document TypeJournal
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CODENCHBEAM
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Document TypeJournal
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CODENBSCFAS
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Document TypeJournal
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CODENCHBEAM; ARPMAS
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CODENKGKZA7
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CODENCOREAF
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CODENJCSOA9
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Language CodeGE
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CODENCHZEA6
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CODENNKAKB8
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Document TypeJournal
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CODENCBTIAE
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CODENJACSAT
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CODENBSCFAS
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Document TypeJournal
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CODENANCPAC
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CODENZRKOAC; CHBEAM
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CODENJACSAT
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CODENJACSAT
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CODENJPCEAO
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CODENJCSOA9
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Document TypeJournal
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CODENJPCEAO
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Document TypeJournal
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CODENBCSJA8
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Document TypeJournal
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CODENHCACAV
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Document TypeJournal
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CODENBSCFAS
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Document TypeJournal
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CODENANCPAC; COREAF
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CODENCHBEAM
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Patent Year1927

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Document TypePatent
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Patent Year1926

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Document TypePatent
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Patent NumberDE 505404
Patent Year1925
CODENFTFVA6
Journal TitleFortschr.Teerfarbenfabr.Verw.Industriezweige
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Language CodeGE
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Document TypePatent
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Document TypePatent
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Country CodeDE
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Patent NumberDE 505404
Patent Year1925
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Document TypeJournal
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CODENBCSJA8
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Publication Year1935
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Document TypeJournal
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CODENNKAKB8
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CODENNKAKB8
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CODENNKAKB8
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Document TypeJournal
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Journal/Review Without CODENActa Sch. med. Univ. Kioto
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Document TypeJournal
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CODENZEAPAA
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Document TypeJournal
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CODENBSCFAS
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Document TypeJournal
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CODENNKAKB8
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CODENCOREAF
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Document TypeJournal
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CODENHCACAV
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CODENYKKZAJ
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CODENJOCEAH
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CODENRFIQA6
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CODENCPBTAL
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Document TypeJournal
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CODENBSCFAS
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Publication Year1965
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CODENMOCMB7
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CODENCHCCAL; KGSSAQ
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(Series) Volume2; 2
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CODENCJCHAG
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Document TypeJournal
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CODENAJCHAS
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Publication Year1961
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CODENBPBLEO
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Document TypeJournal
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CODENRJOCEQ; ZORKAE
Journal TitleRuss.J.Org.Chem.; Zh.Org.Khim.
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CODENMUREAV
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(Series) Volume370
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CODENMUREAV
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Document TypeJournal
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Document TypeJournal
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CODENOPPIAK
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(Series) Volume24
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Document TypeJournal
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CODENEMMUEG
Journal TitleEnviron.Mol.Mutagen.
Language CodeEN
(Series) Volume24
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Journal TitleJ.Nat.Prod.
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Document TypeJournal
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CODENRJACEO; ZPKHAB
Journal TitleRuss.J.Appl.Chem.; Zh.Prikl.Khim.(Leningrad)
Language CodeEN; RU
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Document TypeJournal
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(Series) Volume445
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Document TypeJournal
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CODENMUTAEX
Journal TitleMutagenesis
Language CodeEN
(Series) Volume14
Number4
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Document TypeJournal
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CODENFCTOD7
Journal TitleFood Chem.Toxicol.
Language CodeEN
(Series) Volume37
Number7
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Document TypeJournal
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(Series) Volume64
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Document TypeJournal
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Document TypeJournal
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CODENEJMCA5
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Language CodeEN
(Series) Volume35
Number2
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CODENORLEF7
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(Series) Volume2
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Document TypeJournal
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CODENMUREAV
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Language CodeEN
(Series) Volume468
Number2
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Document TypeJournal
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CODENCRTOEC
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Language CodeEN
(Series) Volume9
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Document TypeJournal
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CODENBMCLE8
Journal TitleBioorg.Med.Chem.Lett.
Language CodeEN
(Series) Volume10
Number17
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Document TypeJournal
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CODENTCMUD8
Journal TitleTeratoc.Carcinog.Mutagen.
Language CodeEN
(Series) Volume17
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Document TypeJournal
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Journal TitlePost Manage.Sci.
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Document TypeJournal
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CODENTETRAB
Journal TitleTetrahedron
Language CodeEN
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Number32
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Document TypeJournal
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CODENCRTOEC
Journal TitleChem.Res.Toxicol.
Language CodeEN
(Series) Volume9
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Document TypeJournal
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CODENHCOMEX
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(Series) Volume7
Number5
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Document TypeJournal
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CODENIJSBDB
Journal TitleIndian J.Chem.Sect.B
Language CodeEN
(Series) Volume40
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Document TypeJournal
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CODENJICSAH
Journal TitleJ.Indian Chem.Soc.
Language CodeEN
(Series) Volume77
Number9
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Document TypeJournal
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CODENCRTOEC
Journal TitleChem.Res.Toxicol.
Language CodeEN
(Series) Volume14
Number11
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Document TypeJournal
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CODENSYNCAV
Journal TitleSynth.Commun.
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(Series) Volume32
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Document TypeJournal
AuthorsTrost, Barry M.; Pinkerton, Anthony B.; Toste, F. Dean; Sperrle, Martin
CODENJACSAT
Journal TitleJ.Amer.Chem.Soc.
Language CodeEN
(Series) Volume123
Number50
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Document TypeJournal
AuthorsUchida, Mihoko; Nakajin, Shizuo; Toyoshima, Satoshi; Shinoda, Masato
CODENBPBLEO
Journal TitleBiol.Pharm.Bull.
Language CodeEN
(Series) Volume19
Number4
Publication Year1996
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Reaction (1 of 229)
Reaction ID35585
Reactant BRN136380; 106909
Reactant5-allyl-benzo[1,3]dioxole; maleic acid anhydride
Product BRN276953
Product(3-benzo[1,3]dioxol-5-yl-allyl)-succinic acid-anhydride
No. of Reaction Details1
Reaction ClassificationPreparation
Temperature140
CommentHandbook
Citation Pointer535939; Journal; Lora Tamayo; Larraz; ASEFAR; An.R.Soc.Esp.Fis.Quim.; <B> 44; 1948; 223, 228;

Reaction (2 of 229)
Reaction ID65491
Reactant BRN136380; 109945
Reactant5-allyl-benzo[1,3]dioxole; benzonitrile N-oxide
Product BRN280762
Product3-phenyl-5-piperonyl-4,5-dihydro-isoxazole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentdiethyl ether
CommentHandbook
Citation Pointer761146; Journal; Stagno d'Alcontres; GCITA9; Gazz.Chim.Ital.; 82; 1952; 823, 825;

Reaction (3 of 229)
Reaction ID68217
Reactant BRN110153; 136380
Reactantthiophene-2-carboxylic acid amide; 5-allyl-benzo[1,3]dioxole
Product BRN260798
Product7-methyl-5-[2]thienyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationPreparation
ReagentPOCl3; benzene
CommentHandbook
Citation Pointer954247; Journal; Kametani et al.; PHBUA9; Pharm.Bull.; 3; 1955; 263, 265; Chem.Abstr.; 1956; 11343;

Reaction (4 of 229)
Reaction ID132127
Reactant BRN136380; 1209224
Reactant5-allyl-benzo[1,3]dioxole; bromoethane
Product BRN1868082
Product5-Allyl-2-methoxy-phenol
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentmagnesium; benzene
CommentHandbook
Citation Pointer1223242; Journal; Grignard; COREAF; C.R.Hebd.Seances Acad.Sci.; 151; 1910; 323;

Reaction (5 of 229)
Reaction ID132128
Reactant BRN136380; 1209226
Reactant5-allyl-benzo[1,3]dioxole; methylmagnesium iodide
Product BRN2257830
Product2-ethoxy-5-allyl-phenol
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentbenzene; diethyl ether
CommentHandbook
Citation Pointer506318; Journal; Kafuku; APCJA8; Acta Phytochim.; 2; 1924/1925; 117; YKKZAJ; Yakugaku Zasshi; 521; 1925; 1; CHZEA6; Chem.Zentralbl.; GE; 97; I; 1926; 69;506380; Journal; Kafuku; YKKZAJ; Yakugaku Zasshi; 521; 1925; 1; CHZEA6; Chem.Zentralbl.; GE; 97; I; 1926; 69;

Reaction (6 of 229)
Reaction ID132129
Reactant BRN136380; 1209226
Reactant5-allyl-benzo[1,3]dioxole; methylmagnesium iodide
Product BRN3268096
Product1,2-diethoxy-4-allyl-benzene
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentdiethyl ether; toluene
Other ConditionsErwaermen des Reaktionsprodukts mit Aethyljodid und aethanol. KOH
CommentHandbook
Citation Pointer1943845; Journal; Hirao; NKAKB8; Nippon Kagaku Kaishi; 52; 1931; 519,523; Chem.Abstr.; 1932; 5085;

Reaction (7 of 229)
Reaction ID132130
Reactant BRN136380; 1209228
Reactant5-allyl-benzo[1,3]dioxole; formaldehyde
Product BRN174506
Product5-allyl-6-chloromethyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentzinc chloride; dichloromethane; hydrogen chloride
CommentHandbook
Citation Pointer512521; Journal; Ichikawa; NPKZAZ; Nippon Kagaku Zasshi; 71; 1950; 303; Chem.Abstr.; 1951; 6599;

Reaction (8 of 229)
Reaction ID132131
Reactant BRN136380; 1209228
Reactant5-allyl-benzo[1,3]dioxole; formaldehyde
Product BRN174515
Product5-allyl-6-bromomethyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1,1,2,2-tetrachloro-ethane; zinc chloride; hydrogen bromide
CommentHandbook
Citation Pointer512208; Journal; Sugasawa et al.; PHBUA9; Pharm.Bull.; 1; 1953; 80, 82;

Reaction (9 of 229)
Reaction ID132132
Reactant BRN1209228; 136380
Reactantformaldehyde; 5-allyl-benzo[1,3]dioxole
Product BRN9656; 16713
Product4x-benzo[1,3]dioxol-5-yl-but-3-en-1-ol; formic acid-(4x-benzo[1,3]dioxol-5-yl-but-3-enyl ester)
No. of Reaction Details1
Reaction ClassificationChemical behaviour
Temperature220
CommentHandbook
Citation Pointer514831; Journal; Kuraoka; Sugawara; NPKZAZ; Nippon Kagaku Zasshi; 79; 1958; 1161; Chem.Abstr.; 1960; 4479;

Reaction (10 of 229)
Reaction ID132133
Reactant BRN1209252; 136380
Reactantacetaldehyde oxime; 5-allyl-benzo[1,3]dioxole
Product BRN172577
Product5,7-dimethyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationPreparation
ReagentPOCl3; benzene
CommentHandbook
Citation Pointer781478; Journal; Kametani; YKKZAJ; Yakugaku Zasshi; 73; 1953; 12, 14; Chem.Abstr.; 1953; 10539;

Reaction (11 of 229)
Reaction ID132134
Reactant BRN136380; 1236342
Reactant5-allyl-benzo[1,3]dioxole; cyclohexanethiol
Product BRN229091
Product5-(3-cyclohexylmercapto-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (12 of 229)
Reaction ID132135
Reactant BRN136380; 1697333
Reactant5-allyl-benzo[1,3]dioxole; 2-butoxy-ethanethiol
Product BRN233531
Product1-benzo[1,3]dioxol-5-yl-3-(2-butoxy-ethylmercapto)-propane
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (13 of 229)
Reaction ID132136
Reactant BRN136380; 1698799
Reactant5-allyl-benzo[1,3]dioxole; butyraldehyde oxime
Product BRN194438
Product7-methyl-5-propyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationPreparation
ReagentPOCl3
CommentHandbook
Citation Pointer780546; Journal; Kametani; Otsuki; YKKZAJ; Yakugaku Zasshi; 73; 1953; 685; Chem.Abstr.; 1954; 8789;

Reaction (14 of 229)
Reaction ID132137
Reactant BRN136380; 1719328
Reactant5-allyl-benzo[1,3]dioxole; (+-)-octane-2-thiol
Product BRN235948
Product1-benzo[1,3]dioxol-5-yl-3-(1-methyl-heptylmercapto)-propane
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (15 of 229)
Reaction ID132138
Reactant BRN136380; 1730908
Reactant5-allyl-benzo[1,3]dioxole; butane-1-thiol
Product BRN190877
Product5-(3-butylmercapto-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (16 of 229)
Reaction ID132139
Reactant BRN136380; 1730979
Reactant5-allyl-benzo[1,3]dioxole; pentane-1-thiol
Product BRN196651
Product5-(3-pentylmercapto-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (17 of 229)
Reaction ID132140
Reactant BRN136380; 1731295
Reactant5-allyl-benzo[1,3]dioxole; hexane-1-thiol
Product BRN215841
Product5-(3-hexylmercapto-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (18 of 229)
Reaction ID132141
Reactant BRN136380; 1731366
Reactant5-allyl-benzo[1,3]dioxole; 2-ethoxy-ethanethiol
Product BRN212839
Product1-(2-ethoxy-ethylmercapto)-3-benzo[1,3]dioxol-5-yl-propane
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (19 of 229)
Reaction ID132142
Reactant BRN136380; 1731687
Reactant5-allyl-benzo[1,3]dioxole; heptane-1-thiol
Product BRN221266
Product5-(3-heptylmercapto-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (20 of 229)
Reaction ID132143
Reactant BRN136380; 1733101
Reactant5-allyl-benzo[1,3]dioxole; octane-1-thiol
Product BRN235880
Product5-(3-octylmercapto-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (21 of 229)
Reaction ID132144
Reactant BRN136380; 1735223
Reactant5-allyl-benzo[1,3]dioxole; decane-1-thiol
Product BRN253895
Product5-(3-decylmercapto-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (22 of 229)
Reaction ID132145
Reactant BRN136380; 1740275
Reactant5-allyl-benzo[1,3]dioxole; tetrafluoroethene
Product BRN221343
Product5-(2,2,3,3-tetrafluoro-cyclobutylmethyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagenthydroquinone
Temperature150
CommentHandbook
Citation Pointer1384149; Journal; Coffman et al.; JACSAT; J.Amer.Chem.Soc.; 71; 1949; 490, 492;

Reaction (23 of 229)
Reaction ID132146
Reactant BRN136380; 1787170
Reactant5-allyl-benzo[1,3]dioxole; bromo-trinitro-methane
Product BRN181744
Product5-(3-bromo-2-methoxy-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentmethanol
CommentHandbook
Citation Pointer506390; Journal; Schmidt; Bartholome; CHBEAM; Chem.Ber.; 57; 1924; 2040;

Reaction (24 of 229)
Reaction ID132147
Reactant BRN136380; 1937271
Reactant5-allyl-benzo[1,3]dioxole; 3-phenyl-propionamide
Product BRN275851
Product7-methyl-5-phenethyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationPreparation
ReagentPOCl3
CommentHandbook
Citation Pointer781478; Journal; Kametani; YKKZAJ; Yakugaku Zasshi; 73; 1953; 12, 14; Chem.Abstr.; 1953; 10539;

Reaction (25 of 229)
Reaction ID132148
Reactant BRN2049534; 136380
Reactant4-nitroso-benzoic acid ethyl ester; 5-allyl-benzo[1,3]dioxole
Product BRN336139
Product4-[(3-benzo[1,3]dioxol-5-yl-allyliden)-oxy-amino]-benzoic acid ethyl ester
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentdiethyl ether
Other Conditionsim Dunkeln
CommentHandbook
Citation Pointer506383; Journal; Alessandri; GCITA9; Gazz.Chim.Ital.; 54; 1924; 449;

Reaction (26 of 229)
Reaction ID132149
Reactant BRN215975; 136380
Reactant[2,2']biindolyl-3,3'-dione; 5-allyl-benzo[1,3]dioxole
Product BRN365476
Product6-piperonyl-6,7-dihydro-pyrazino[1,2-a;4,3-a']diindole-13,14-dione
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentbenzene
CommentHandbook
Citation Pointer795153; Journal; Pummerer; Fiesselmann; JLACBF; Justus Liebigs Ann. Chem.; 544; 1940; 206, 230;

Reaction (27 of 229)
Reaction ID132150
Reactant BRN136380; 2345114
Reactant5-allyl-benzo[1,3]dioxole; 2-(2-butoxy-ethoxy)-ethanethiol
Product BRN287002
Product1-(3-benzo[1,3]dioxol-5-yl-propylmercapto)-2-(2-butoxy-ethoxy)-ethane
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (28 of 229)
Reaction ID132151
Reactant BRN136380; 3530350
Reactant5-allyl-benzo[1,3]dioxole; 2,3-dimethyl-4-nitroso-aniline
Product BRN750281; 271541
Producttetra-N-methyl-4,4'-azo-di-aniline; 3,4-methylenedioxy-cinnamaldehyde-(4-dimethylamino-phenylimine)
No. of Reaction Details1
Reaction ClassificationPreparation
CommentHandbook
Citation Pointer507506; Journal; Quilico; GCITA9; Gazz.Chim.Ital.; 58; 1928; 322;

Reaction (29 of 229)
Reaction ID132152
Reactant BRN3530350; 136380
Reactant2,3-dimethyl-4-nitroso-aniline; 5-allyl-benzo[1,3]dioxole
Product BRN750281
Producttetra-N-methyl-4,4'-azo-di-aniline
No. of Reaction Details1
Reaction ClassificationPreparation
CommentHandbook
Citation Pointer507506; Journal; Quilico; GCITA9; Gazz.Chim.Ital.; 58; 1928; 322;

Reaction (30 of 229)
Reaction ID132153
Reactant BRN136380; 3563831
Reactant5-allyl-benzo[1,3]dioxole; acetic acid; mercury(II) salt
Product BRN4926040
Product3-benzo[1,3]dioxol-5-yl-2-hydroxy-propylmercury (1+); iodide
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentwater
Other Conditionsanschliessendes Behandeln mit Kaliumjodid
CommentHandbook
Citation Pointer514787; Journal; Tsukamoto; YKKZAJ; Yakugaku Zasshi; 50; 1930; 7, 16, dtsch. Ref. S. 2, 4; Chem.Abstr.; 1930; 1853;

Reaction (31 of 229)
Reaction ID132154
Reactant BRN136380; 3563831
Reactant5-allyl-benzo[1,3]dioxole; acetic acid; mercury(II) salt
Product BRN4928792
Product3-benzo[1,3]dioxol-5-yl-2-methoxy-propylmercury (1+); acetate
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentmethanol
CommentHandbook
Citation Pointer533447; Journal; Matejka; CHBEAM; Chem.Ber.; 69; 1936; 274, 277;

Reaction (32 of 229)
Reaction ID132155
Reactant BRN3593646; 136380
Reactantethanol; sodium salt; 5-allyl-benzo[1,3]dioxole
Product BRN82640
Product5-propenyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour
Temperature200
CommentHandbook
Citation Pointer500467; Journal; Angeli; GCITA9; Gazz.Chim.Ital.; 23 II; 1893; 101;

Reaction (33 of 229)
Reaction ID132156
Reactant BRN136380; 383905
Reactant5-allyl-benzo[1,3]dioxole; benzo[1,3]dioxol-5-carboxylic acid amide
Product BRN325544
Product5-benzo[1,3]dioxol-5-yl-7-methyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationPreparation
ReagentPOCl3
CommentHandbook
Citation Pointer780876; Journal; Kametani; Nikomiya; YKKZAJ; Yakugaku Zasshi; 72; 1952; 1539; Chem.Abstr.; 1953; 10538;

Reaction (34 of 229)
Reaction ID132157
Reactant BRN136380; 385876
Reactant5-allyl-benzo[1,3]dioxole; benzamide
Product BRN260283
Product7-methyl-5-phenyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentbenzene
CommentHandbook
Citation Pointer542450; Journal; Kametani; YKKZAJ; Yakugaku Zasshi; 72; 1952; 1090, 1092; Chem.Abstr.; 1953; 10538;

Reaction (35 of 229)
Reaction ID132158
Reactant BRN4149750; 136380
Reactantpentan-1-ol; sodium salt; 5-allyl-benzo[1,3]dioxole
Product BRN82640
Product5-propenyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer1973069; Journal; Gassmann; COREAF; C.R.Hebd.Seances Acad.Sci.; 124; 1897; 38;

Reaction (36 of 229)
Reaction ID132159
Reactant BRN136380; 471171
Reactant5-allyl-benzo[1,3]dioxole; cyclopenta-1,3-diene
Product BRN187284
Product5-piperonyl-norborn-2-ene
No. of Reaction Details1
Reaction ClassificationPreparation
CommentHandbook
Citation Pointer512874; Patent; Resinous Prod. & Chem. Co.; US 2411516; 1944;

Reaction (37 of 229)
Reaction ID132160
Reactant BRN136380; 3632802; 506007
Reactant5-allyl-benzo[1,3]dioxole; Pyridinium-tribromid; acetic acid
Product BRN171593
Product5-(2,3-dibromo-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Temperature3 - 6
CommentHandbook
Citation Pointer506322; Journal; Rosenmund; Kuhnhenn; CHBEAM; Chem.Ber.; 56; 1923; 1265;

Reaction (38 of 229)
Reaction ID132161
Reactant BRN136380; 506166
Reactant5-allyl-benzo[1,3]dioxole; mercaptoacetic acid
Product BRN238210
Product(3-benzo[1,3]dioxol-5-yl-propylmercapto)-acetic acid
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (39 of 229)
Reaction ID132162
Reactant BRN136380; 506893
Reactant5-allyl-benzo[1,3]dioxole; benzonitrile
Product BRN260283
Product7-methyl-5-phenyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentconcentrated H2SO4
CommentHandbook
Citation Pointer942499; Journal; Lora-Tamayo et al.; BSCFAS; Bull.Soc.Chim.Fr.; 1958; 1331;

Reaction (40 of 229)
Reaction ID132163
Reactant BRN136380; 507886
Reactant5-allyl-benzo[1,3]dioxole; 2-phenyl-acetamide
Product BRN272421
Product5-benzyl-7-methyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationPreparation
CommentHandbook
Citation Pointer542450; Journal; Kametani; YKKZAJ; Yakugaku Zasshi; 72; 1952; 1090, 1092; Chem.Abstr.; 1953; 10538;

Reaction (41 of 229)
Reaction ID132164
Reactant BRN605688; 136380
Reactantnitrosobenzene; 5-allyl-benzo[1,3]dioxole
Product BRN259846
Product3-benzo[1,3]dioxol-5-yl-acrylaldehyde-(N-phenyl oxime )
No. of Reaction Details1
Reaction ClassificationPreparation
CommentHandbook
Citation Pointer504612; Journal; Angeli; Alessandri; Pegna; AANLAW; Atti Accad.Naz.Lincei Cl.Sci.Fis.Mat.Nat.Rend.; <5> 19 I; 1910; 654;

Reaction (42 of 229)
Reaction ID132165
Reactant BRN136380; 773638
Reactant5-allyl-benzo[1,3]dioxole; ethanethiol
Product BRN172313
Product5-(3-ethylmercapto-propyl)-benzo[1,3]dioxole
No. of Reaction Details2
Reaction ClassificationPreparation
Reagentmercury (II)-ethanethiolate; oxygen
Other Conditionsim Sonnenlicht
CommentHandbook
Citation Pointer1176490; Journal; Nakatsuchi; Yamaguchi; KGKZA7; Kogyo Kagaku Zasshi; 60; 1957; 694; Chem.Abstr.; 1959; 10092;

Reaction (43 of 229)
Reaction ID132166
Reactant BRN136380; 773648
Reactant5-allyl-benzo[1,3]dioxole; 2-mercapto-ethanol
Product BRN189127
Product2-(3-benzo[1,3]dioxol-5-yl-propylmercapto)-ethanol
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (44 of 229)
Reaction ID132167
Reactant BRN774229; 136380; 1209228
Reactant1-methoxy-4-propenyl-benzene; 5-allyl-benzo[1,3]dioxole; formaldehyde
Product BRN1209228
Productformaldehyde
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer1311967; Journal; Prisn; CHZEA6; Chem.Zentralbl.; GE; 91; I; 1920; 424;504585; Journal; Prins; CHZEA6; Chem.Zentralbl.; GE; 90; III; 1919; 1001;1311969; Journal; Prins; CHZEA6; Chem.Zentralbl.; GE; 89; I; 1918; 168;

Reaction (45 of 229)
Reaction ID132168
Reactant BRN1209226; 969212; 1696894; 136380
Reactantmethylmagnesium iodide; benzene; diethyl ether; 5-allyl-benzo[1,3]dioxole
Product BRN2257830
Product2-ethoxy-5-allyl-phenol
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer506318; Journal; Kafuku; APCJA8; Acta Phytochim.; 2; 1924/1925; 117; YKKZAJ; Yakugaku Zasshi; 521; 1925; 1; CHZEA6; Chem.Zentralbl.; GE; 97; I; 1926; 69;506380; Journal; Kafuku; YKKZAJ; Yakugaku Zasshi; 521; 1925; 1; CHZEA6; Chem.Zentralbl.; GE; 97; I; 1926; 69;

Reaction (46 of 229)
Reaction ID132169
Reactant BRN136380; 969335
Reactant5-allyl-benzo[1,3]dioxole; allylmagnesium bromide
Product BRN3267528
Product5-allyl-2-but-3-enyloxy-phenol
No. of Reaction Details1
Reaction ClassificationPreparation
CommentHandbook
Citation Pointer1641168; Journal; Takahashi; Senda; Acta Sch. med. Univ. Kioto; 27; 1949; 34, 41;

Reaction (47 of 229)
Reaction ID132170
Reactant BRN136380; 969337
Reactant5-allyl-benzo[1,3]dioxole; dodecane-1-thiol
Product BRN274759
Product5-(3-dodecylmercapto-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentascaridole
CommentHandbook
Citation Pointer1367253; Journal; Prill; Hartzell; Arthur; CBTIAE; Contrib.Boyce Thompson Inst.; 14; 1946; 130; Chem.Abstr.; 1946; 4839;

Reaction (48 of 229)
Reaction ID132171
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN11451
Product3-benzo[1,3]dioxol-5-yl-propane-1,2-diol
No. of Reaction Details7
Reaction ClassificationPreparation
ReagentKMnO4-solution
Temperature70 - 80
CommentHandbook
Citation Pointer500498; Journal; Tiemann; CHBEAM; Chem.Ber.; 24; 1891; 2881;

Reaction (49 of 229)
Reaction ID132172
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN131188
Product5-propyl-benzo[1,3]dioxole
No. of Reaction Details8
Reaction ClassificationPreparation
ReagentH2
Catalyst10 percent Pd/C
Solventmethanol
Citation Pointer6286194; Journal; Pap, Laszlo; Arvai, Geza; Bertok, Bela; Kuruczne Ribai, Zsuzsanna; Bakonyvary, Ildiko; PMSCFC; Post Manage.Sci.; EN; 57; 2; 2001; 186 - 190;

Reaction (50 of 229)
Reaction ID132173
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN131691
Productbenzo[1,3]dioxole-5-carbaldehyde
No. of Reaction Details2
Reaction ClassificationPreparation
Reagentglacial acetic acid; ozone
Temperature50
CommentHandbook
Citation Pointer500503; Patent; Otto; Verley; DE 97620; FTFVA6; Fortschr.Teerfarbenfabr.Verw.Industriezweige; DE; GE; 4; 1281;

Reaction (51 of 229)
Reaction ID132174
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN150206; 131691
Productbenzo[1,3]dioxole-5-carboxylic acid; benzo[1,3]dioxole-5-carbaldehyde
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentpotassium permanganate
CommentHandbook
Citation Pointer500500; Journal; Poleck; CHBEAM; Chem.Ber.; 19; 1886; 1094; CHBEAM; Chem.Ber.; 22; 1889; 2862;

Reaction (52 of 229)
Reaction ID132175
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN150196
Product2-benzo[1,3]dioxol-5-yl-1-methyl-ethylamine
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentaqueous hydrobromic acid
Temperature0
Other ConditionsErhitzen des Reaktionsprodukts mit konz. Ammoniak auf 120grad
CommentHandbook
Citation Pointer500347; Patent; Merck; DE 274350; FTFVA6; Fortschr.Teerfarbenfabr.Verw.Industriezweige; DE; GE; 12; 768;

Reaction (53 of 229)
Reaction ID132176
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN150206
Productbenzo[1,3]dioxole-5-carboxylic acid
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentpotassium permanganate
CommentHandbook
Citation Pointer500500; Journal; Poleck; CHBEAM; Chem.Ber.; 19; 1886; 1094; CHBEAM; Chem.Ber.; 22; 1889; 2862;500501; Journal; Eijkman; RTCPA3; Recl.Trav.Chim.Pays-Bas; 4; 1885; 39;

Reaction (54 of 229)
Reaction ID132177
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN150206; 177739
Productbenzo[1,3]dioxole-5-carboxylic acid; benzo[1,3]dioxol-5-yl-acetic acid
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentpotassium permanganate; acetic acid
CommentHandbook
Citation Pointer500496; Journal; Miller; ARPMAS; Arch.Pharm.(Weinheim Ger.); 240; 1902; 377;500498; Journal; Tiemann; CHBEAM; Chem.Ber.; 24; 1891; 2881;

Reaction (55 of 229)
Reaction ID132178
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN150219
Product5-(2-bromo-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentwater; hydrobromic acid
CommentHandbook
Citation Pointer512146; Journal; Sakakibara; NPKZAZ; Nippon Kagaku Zasshi; 73; 1952; 235; Chem.Abstr.; 1953; 10511;512147; Journal; Orcutt; Bogert; JACSAT; J.Amer.Chem.Soc.; 58; 1936; 2055;512148; Journal; Lieberman et al.; JACSAT; J.Amer.Chem.Soc.; 69; 1947; 1540;

Reaction (56 of 229)
Reaction ID132179
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN158675
Product(2-benzo[1,3]dioxol-5-yl-1-methyl-ethyl)-methyl-amine
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentaqueous hydrobromic acid
Temperature0
Other ConditionsErhitzen des Reaktionsprodukts mit alkoh. Methylamin-Loesung auf 130grad
CommentHandbook
Citation Pointer500347; Patent; Merck; DE 274350; FTFVA6; Fortschr.Teerfarbenfabr.Verw.Industriezweige; DE; GE; 12; 768;

Reaction (57 of 229)
Reaction ID132180
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN163628
Product5-oxiranylmethyl-benzo[1,3]dioxole
No. of Reaction Details6
Reaction ClassificationPreparation
Reagentiodine; yellow mercury oxide; water containing diethyl ether
Other ConditionsBehandeln der entwaesserten Loesung mit Kaliumhydroxyd
CommentHandbook
Citation Pointer504055; Journal; Fourneau; Tiffeneau; COREAF; C.R.Hebd.Seances Acad.Sci.; 141; 1905; 662; COREAF; C.R.Hebd.Seances Acad.Sci.; 140; 1905; 1595;

Reaction (58 of 229)
Reaction ID132181
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN170166
Product3-ethoxy-3-benzo[1,3]dioxol-5-yl-propene
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentselenium dioxide; ethanol
CommentHandbook
Citation Pointer542456; Journal; Wierzchowski; ROCHAC; Rocz.Chem.; 16; 1936; 451, 454, 455; CHZEA6; Chem.Zentralbl.; GE; 108; I; 1937; 3136;

Reaction (59 of 229)
Reaction ID132182
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN170585
Product5-nitro-6-propenyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagenthydrobromic acid
Other ConditionsNitrieren des Reaktionsprodukts mit Salpetersaeure in Eisessig und Kochen des Reaktionsprodukts mit alkoh. Kalilauge
CommentHandbook
Citation Pointer506374; Journal; Robinson; Zaki; JCSOA9; J.Chem.Soc.; 1927; 2489;

Reaction (60 of 229)
Reaction ID132183
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN171593
Product5-(2,3-dibromo-propyl)-benzo[1,3]dioxole
No. of Reaction Details2
Reaction ClassificationPreparation
Reagentchloroform; bromine
CommentHandbook
Citation Pointer500368; Journal; Woy; ARPMAS; Arch.Pharm.(Weinheim Ger.); 228; 1890; 40;

Reaction (61 of 229)
Reaction ID132184
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN177739
Productbenzo[1,3]dioxol-5-yl-acetic acid
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentpermanganate
CommentHandbook
Citation Pointer504615; Journal; Luff; Perkin; Robinson; JCSOA9; J.Chem.Soc.; 97; 1910; 1139;505540; Journal; Decker; JLACBF; Justus Liebigs Ann. Chem.; 395; 1913; 295;

Reaction (62 of 229)
Reaction ID132185
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN1929705
Product3-Propyl-phenol
No. of Reaction Details1
Reaction ClassificationPreparation
Reagenthydrogen; nickel
Temperature200
CommentHandbook
Citation Pointer500344; Journal; Henrard; CHZEA6; Chem.Zentralbl.; GE; 78; II; 1907; 1512;

Reaction (63 of 229)
Reaction ID132186
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN197687
Product1-bromo-3-(6-bromo-benzo[1,3]dioxol-5-yl)-propan-2-ol
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentpotassium bromide; water; bromine
CommentHandbook
Citation Pointer514786; Journal; Terada; NPKZAZ; Nippon Kagaku Zasshi; 77 <1956< 1121, 1123; Chem.Abstr.; 1959; 5173;

Reaction (64 of 229)
Reaction ID132187
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN197687; 197708
Product1-bromo-3-(6-bromo-benzo[1,3]dioxol-5-yl)-propan-2-ol; 2-bromo-3-(6-bromo-benzo[1,3]dioxol-5-yl)-propan-1-ol
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentpotassium bromide; water; bromine
CommentHandbook
Citation Pointer514807; Journal; Terada; NPKZAZ; Nippon Kagaku Zasshi; 77; 1956; 1121; Chem.Abstr.; 1959; 5173;

Reaction (65 of 229)
Reaction ID132188
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN199286
Product5-allyl-6-nitro-benzo[1,3]dioxole
No. of Reaction Details3
Reaction ClassificationPreparation
Yield70 percent (BRN=199286)
Reagentconc. nitric acid
Solventacetic acid
Time2 hour(s)
Citation Pointer6315729; Journal; Silva, Kezia Peixoto da; Souza, Ivone A. de; Faria, Antonio Rodolfo de; Brondani, Dalci Jose; Leite, Ana Cristina Lima; HCOMEX; Heterocycl.Commun.; EN; 7; 5; 2001; 445 - 448;

Reaction (66 of 229)
Reaction ID132189
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN2039682
Product4-Allyl-phenol
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentliquid NH3; ethanol; sodium
CommentHandbook
Citation Pointer511789; Journal; Birch; JCSOA9; J.Chem.Soc.; 1947; 102, 104;

Reaction (67 of 229)
Reaction ID132190
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN2327875; 2046156
Product2-Methoxy-5-trans-propenyl-phenol; 2-methoxy-4-trans-propenyl-phenol
No. of Reaction Details5
Reaction ClassificationPreparation
Reagentethanolic KOH
Temperature130 - 140
Other ConditionsBehandeln des Reaktionsprodukts mit Dimethylsulfat und anschliessendes Kochen mit wss.-aethanol. HCl
CommentHandbook
Citation Pointer506385; Journal; Wagner; CZCAA5; Chem.-Ztg.Chem.Appar.; 52; 1928; 379; CHZEA6; Chem.Zentralbl.; GE; 99; I; 1928; 3056;1587059; Patent; Stockelbach; US 1792716; 1927;1587060; Patent; Stockelbach; US 1792717; 1927;1587061; Patent; Boedecker; US 1812132; 1926;1587062; Patent; Riedel-de Haen; DE 505404; 1925; FTFVA6; Fortschr.Teerfarbenfabr.Verw.Industriezweige; DE; GE; 17; 569, 18 571;1587063; Patent; Riedel-de Haen; DE 539880; 1925;

Reaction (68 of 229)
Reaction ID132191
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN212873
Product5-benzo[1,3]dioxol-5-yl-[1,2]dithiol-3-thione
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentsulfur
Temperature200
CommentHandbook
Citation Pointer512464; Journal; Lozac'h; BSCFAS; Bull.Soc.Chim.Fr.; 1949; 840, 844;

Reaction (69 of 229)
Reaction ID132192
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN2259898; 3200087
Product2-ethoxy-5-trans-propenyl-phenol; 2-ethoxy-4-trans-propenyl-phenol
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentmethanol. KOH
Temperature130 - 140
Other Conditionsanschliessendes Behandeln mit Aethylbromid und aethanol. KOH bei 100grad und Kochen des Reaktionsprodukts mit wss.-aethanol. HCl
CommentHandbook
Citation Pointer1587167; Patent; Riedel-de Haen; DE 562007; 1927; FTFVA6; Fortschr.Teerfarbenfabr.Verw.Industriezweige; DE; GE; 19; 754;

Reaction (70 of 229)
Reaction ID132193
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN3136418; 3134130
Product2-ethoxymethoxy-5-trans-propenyl-phenol; 2-ethoxymethoxy-4-trans-propenyl-phenol
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentethanolic alkaline solution
CommentHandbook
Citation Pointer1641078; Journal; Hirao; NKAKB8; Nippon Kagaku Kaishi; 51; 1930; 579, 583; Chem.Abstr.; 1931; 5156;1641074; Journal; Hirao; NKAKB8; Nippon Kagaku Kaishi; 52; 1931; 583;

Reaction (71 of 229)
Reaction ID132194
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN3137327; 3135148
Product5-trans-Propenyl-2-propoxymethoxy-phenol; 4-trans-Propenyl-2-propoxymethoxy-phenol
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentpropan-1-ol; aqueous KOH
CommentHandbook
Citation Pointer1641075; Journal; Hirao; NKAKB8; Nippon Kagaku Kaishi; 52; 1931; 142, 145, 269; Chem.Abstr.; 1932; 1594, 5062;

Reaction (72 of 229)
Reaction ID132195
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN3159329; 3160239
Product3-ethoxymethoxy-4-benzoyloxy-1-trans-propenyl-benzene; 4-ethoxymethoxy-3-benzoyloxy-1-trans-propenyl-benzene
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentethanolic alkaline solution
Other ConditionsBehandeln des Reaktionsprodukts mit Benzoylchlorid und wss. Kalilauge
CommentHandbook
Citation Pointer1641078; Journal; Hirao; NKAKB8; Nippon Kagaku Kaishi; 51; 1930; 579, 583; Chem.Abstr.; 1931; 5156;

Reaction (73 of 229)
Reaction ID132196
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN3193976
Product1r-Propyl-cyclohexanol-(4t)
No. of Reaction Details1
Reaction ClassificationPreparation
ReagentRaney nickel
Temperature150
Pressure58840.6
Other ConditionsHydrogenation
CommentHandbook
Citation Pointer1585208; Journal; Gauthier; ANCPAC; Ann.Chim.(Paris); <11> 20; 1945; 581, 608; COREAF; C.R.Hebd.Seances Acad.Sci.; 217; 1943; 28;

Reaction (74 of 229)
Reaction ID132197
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN323255
Product5-(3,4-dimethoxy-phenyl)-7-methyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationPreparation
ReagentPOCl3
CommentHandbook
Citation Pointer781478; Journal; Kametani; YKKZAJ; Yakugaku Zasshi; 73; 1953; 12, 14; Chem.Abstr.; 1953; 10539;

Reaction (75 of 229)
Reaction ID132198
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN3285051
Product2-ethoxymethoxy-4-propenyl-phenol
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentalcoholic KOH-solution
Temperature150
CommentHandbook
Citation Pointer500490; Patent; Pomeranz; DE 122701;

Reaction (76 of 229)
Reaction ID132199
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN4927196
Product(+-)-3-(4-mercurio(1+)-benzo[1,3]dioxol-5-yl)-2-methoxy-propylmercury (1+); dichloride
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentmercury (II)-acetate; methanol
Other Conditionsanschl. mit wss. NaCl
CommentHandbook
Citation Pointer533447; Journal; Matejka; CHBEAM; Chem.Ber.; 69; 1936; 274, 277;

Reaction (77 of 229)
Reaction ID132200
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN72253
Productsafrole-pseudo nitrosite
No. of Reaction Details3
Reaction ClassificationPreparation
Reagentpetroleum ether; diluted sulfuric acid; sodium nitrite
CommentHandbook
Citation Pointer501556; Journal; Angeli; Rimini; GCITA9; Gazz.Chim.Ital.; 25 II; 1895; 205;

Reaction (78 of 229)
Reaction ID132201
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN7729
Productbenzo[1,3]dioxol-5-yl-acetaldehyde
No. of Reaction Details3
Reaction ClassificationPreparation
Reagentozone; carbon tetrachloride; chloroform
Other Conditionsweiteres Reagens: Petrolaether; Zersetzung des Ozonids durch Ruehren seiner Loesung in Eisessig mit Wasser und Zinkstaub
CommentHandbook
Citation Pointer507360; Journal; Nagai; J. Fac. Eng. Tokyo Univ.; 13; 185; CHZEA6; Chem.Zentralbl.; GE; 94; III; 1923; 750;

Reaction (79 of 229)
Reaction ID132202
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN82640
Product5-propenyl-benzo[1,3]dioxole
No. of Reaction Details17
Reaction ClassificationPreparation
Reagentsodium
Temperature200
Other Conditionsim Rohr
CommentHandbook
Citation Pointer500454; Journal; Eijkman; CHBEAM; Chem.Ber.; 23; 1890; 862;500471; Journal; Schiff; CHBEAM; Chem.Ber.; 17; 1884; 1937;

Reaction (80 of 229)
Reaction ID132203
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN82641
Product5-cis-propenyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Other ConditionsIsolierung durch fraktionierte Destillation
CommentHandbook
Citation Pointer512137; Journal; Naves; Ardizio; BSCFAS; Bull.Soc.Chim.Fr.; 1957; 1053, 1056;

Reaction (81 of 229)
Reaction ID170702
Reactant BRN1696892; 1937030
Reactantdiiodomethane; 4-allyl-pyrocatechol
Product BRN136380
Product5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentacetone; potassium carbonate
CommentHandbook
Citation Pointer506403; Journal; Perkin; Trikojus; JCSOA9; J.Chem.Soc.; 1927; 1665;

Reaction (82 of 229)
Reaction ID808981
Reactant BRN136380; 82640
Reactant5-allyl-benzo[1,3]dioxole; 5-propenyl-benzo[1,3]dioxole
Product BRN3160239; 3159329
Product4-ethoxymethoxy-3-benzoyloxy-1-trans-propenyl-benzene; 3-ethoxymethoxy-4-benzoyloxy-1-trans-propenyl-benzene
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentethanolic alkaline solution
Other ConditionsBehandeln des Reaktionsprodukts mit Benzoylchlorid und wss. Kalilauge
CommentHandbook
Citation Pointer1641078; Journal; Hirao; NKAKB8; Nippon Kagaku Kaishi; 51; 1930; 579, 583; Chem.Abstr.; 1931; 5156;

Reaction (83 of 229)
Reaction ID810541
Reactant BRN83661; 136380
Reactantbenzo[1,3]dioxole-5-carbaldehyde oxime; 5-allyl-benzo[1,3]dioxole
Product BRN325544
Product5-benzo[1,3]dioxol-5-yl-7-methyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationPreparation
ReagentPOCl3
CommentHandbook
Citation Pointer781478; Journal; Kametani; YKKZAJ; Yakugaku Zasshi; 73; 1953; 12, 14; Chem.Abstr.; 1953; 10539;

Reaction (84 of 229)
Reaction ID958724
Reactant BRN136380; 1209226
Reactant5-allyl-benzo[1,3]dioxole; methylmagnesium iodide
Product BRN2257824
Product2-ethoxy-4-allyl-phenol
No. of Reaction Details1
Reaction ClassificationPreparation
Solventbenzene
Other ConditionsHeating
Citation Pointer250767; Journal; Cabiddu,S. et al.; GCITA9; Gazz.Chim.Ital.; IT; 98; 1968; 800-809;

Reaction (85 of 229)
Reaction ID958725
Reactant BRN1842445; 136380
Reactant3-phenyl-sydnone; 5-allyl-benzo[1,3]dioxole
Product BRN2997705
Product3-benzo[1,3]dioxol-5-ylmethyl-1-phenyl-4,5-dihydro-1H-pyrazole
No. of Reaction Details1
Reaction ClassificationPreparation
Temperature150
Citation Pointer39497; Journal; Gotthardt,H.; Huisgen,R.; CHBEAM; Chem.Ber.; GE; 101; 1968; 552-563;

Reaction (86 of 229)
Reaction ID958726
Reactant BRN610924; 136380
ReactantN'-phenyl-benzohydrazonoyl chloride; 5-allyl-benzo[1,3]dioxole
Product BRN3008857
Product5-benzo[1,3]dioxol-5-ylmethyl-1,3-diphenyl-4,5-dihydro-1H-pyrazole
No. of Reaction Details1
Reaction ClassificationPreparation
ReagentEt3N
Citation Pointer39172; Journal; Huisgen,R. et al.; CHBEAM; Chem.Ber.; GE; 100; 5; 1967; 1580-1592;

Reaction (87 of 229)
Reaction ID958727
Reactant BRN136380; 741857
Reactant5-allyl-benzo[1,3]dioxole; acetonitrile
Product BRN1575822
Product7-iodomethyl-5-methyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationPreparation
ReagentI2, SnCl4
Citation Pointer214554; Journal; Hassner,A. et al.; TELEAY; Tetrahedron Lett.; EN; 1968; 1241-1245;

Reaction (88 of 229)
Reaction ID958728
Reactant BRN879051; 136380; 1209228
Reactantpyrimidine-2,4,6-trione; 5-allyl-benzo[1,3]dioxole; formaldehyde
Product BRN1030178
Product7-benzo[1,3]dioxol-5-ylmethyl-1,5,6,7-tetrahydro-pyrano[2,3-d]pyrimidine-2,4-dione
No. of Reaction Details1
Reaction ClassificationPreparation
Solventacetic acid
Citation Pointer104449; Journal; Schulte,K.E.; von Weissenborn,V.; ARPMAS; Arch.Pharm.(Weinheim Ger.); GE; 305; 1972; 354-359;

Reaction (89 of 229)
Reaction ID1113770
Reactant BRN2458; 136380
Reactantbenzylidene-methyl-amine oxide; 5-allyl-benzo[1,3]dioxole
Product BRN1592388
Product5-benzo[1,3]dioxol-5-ylmethyl-2-methyl-3-phenyl-isoxazolidine
No. of Reaction Details1
Reaction ClassificationPreparation
Time24 hour(s)
Temperature110
Citation Pointer39660; Journal; Huisgen,R. et al.; CHBEAM; Chem.Ber.; GE; 101; 6; 1968; 2043-2055;

Reaction (90 of 229)
Reaction ID1767827
Reactant BRN1072149; 136380
Reactant4-methoxy-benzaldehyde oxime; 5-allyl-benzo[1,3]dioxole
Product BRN4819636
Product3-(4-methoxy)phenyl-4-(3,4-methylenedioxy)benzyl-4,5-dihydroisoxazole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1.) iodobenzene dichloride, pyridine
Other Conditions1.) chloroform, RT, 0.5 h, 2.) chloroform, reflux, 5 h
CommentYield given. Multistep reaction
Citation Pointer5589730; Journal; Radhakrishna, A S; Sivaprakash, K; Singh, B B; SYNCAV; Synth.Commun.; EN; 21; 15,16; 1991; 1625-1629;

Reaction (91 of 229)
Reaction ID1767828
Reactant BRN136380; 1098229
Reactant5-allyl-benzo[1,3]dioxole; methanol
Product BRN5078664; 164033; 5022958
Product5-(2-methoxy-3-nitrooxy-propyl)-benzo[1,3]dioxole; benzo[1,3]dioxol-5-yl-propan-2-one; 5-(2,3-dimethoxy-propyl)-benzo[1,3]dioxole
No. of Reaction Details2
Reaction ClassificationPreparation
Yield38 percent (BRN=5022958); 30 percent (BRN=5078664); 10 percent (BRN=164033)
Reagentthallium(III) nitrate trihydrate
Citation Pointer5617635; Journal; Niwa, Masatake; Noda, Hitoshi; Kobayashi, Hiroki; Yamamura, Shosuke; CMLTAG; Chem.Lett.; EN; 1980; 85-88;

Reaction (92 of 229)
Reaction ID1767829
Reactant BRN136380; 1098229
Reactant5-allyl-benzo[1,3]dioxole; methanol
Product BRN3283428; 3274789
Product2-methoxymethoxy-5-propenyl-phenol; 2-Methoxymethoxy-4-propenyl-phenol
No. of Reaction Details1
Reaction ClassificationPreparation
ReagentMeONa
Solventhexamethylphosphoric acid triamide
Time2 hour(s)
Temperature150
CommentYield given. Title compound not separated from byproducts
Citation Pointer5714561; Journal; Imakura, Yasuhiro; Okimoto, Kazuto; Konishi, Tatsuya; Hisazumi, Mariko; Yamazaki, Junyo; et al.; CPBTAL; Chem.Pharm.Bull.; EN; 40; 7; 1992; 1691-1696;

Reaction (93 of 229)
Reaction ID1767830
Reactant BRN136380; 1098229
Reactant5-allyl-benzo[1,3]dioxole; methanol
Product BRN3608957; 3613201; 3607929
Product5-allyl-2-methoxy-benzo[1,3]dioxole; 2-methoxy-5-(1-methoxy-allyl)-benzo[1,3]dioxole; 5-(1-methoxy-allyl)-benzo[1,3]dioxole
No. of Reaction Details3
Reaction ClassificationPreparation
Yield2 percent Chromat. (BRN=3608957); 8 percent Chromat. (BRN=3613201); 14 percent Chromat (BRN=3607929)
Reagentsodium methoxide, sodium perchlorate
Time15 min
Temperature30
Other Conditionselectrolysis
Citation Pointer5512529; Journal; Barba, Isidoro; Chinchilla, Rafael; Gomez, Cecilia; JOCEAH; J.Org.Chem.; EN; 55; 10; 1990; 3270-3272;

Reaction (94 of 229)
Reaction ID1767831
Reactant BRN136380; 1098295; 1900508; 1718733
Reactant5-allyl-benzo[1,3]dioxole; tetrachloromethane; carbon monoxide; ethanol
Product BRN4448026; 4524942
Product1,2-methylenedioxy-4-(2,4,4,4-tetrachlorobutyl)benzene; 2-benzo[1,3]dioxol-5-ylmethyl-4,4,4-trichloro-butyric acid ethyl ester
No. of Reaction Details1
Reaction ClassificationPreparation
Yield29 percent (BRN=4524942); 35 percent (BRN=4448026)
ReagentPd(OAc)2, PPh3K2CO3
Time48 hour(s)
Temperature80
Pressure30400.004
Citation Pointer5543032; Journal; Tsuji, Jiro; Sato, Koji; Nagashima, Hideo; TELEAY; Tetrahedron Lett.; EN; 23; 8; 1982; 893-896;

Reaction (95 of 229)
Reaction ID1767832
Reactant BRN136380; 1098295; 1718733; 3587209
Reactant5-allyl-benzo[1,3]dioxole; tetrachloromethane; ethanol; carbon monoxide
Product BRN4524942; 4448026
Product2-benzo[1,3]dioxol-5-ylmethyl-4,4,4-trichloro-butyric acid ethyl ester; 1,2-methylenedioxy-4-(2,4,4,4-tetrachlorobutyl)benzene
No. of Reaction Details2
Reaction ClassificationPreparation
Yield35 percent (BRN=4448026); 29 percent (BRN=4524942)
ReagentK2CO3
CatalystPd(OAc)2, PPh3
Time48 hour(s)
Temperature80
Pressure30400.004
Citation Pointer5619185; Journal; Tsuji, Jiro; Sato, Koji; Nagashima, Hideo; TETRAB; Tetrahedron; EN; 41; 21; 1985; 5003-5006;

Reaction (96 of 229)
Reaction ID1767833
Reactant BRN1098295; 136380
Reactanttetrachloromethane; 5-allyl-benzo[1,3]dioxole
Product BRN4448026
Product1,2-methylenedioxy-4-(2,4,4,4-tetrachlorobutyl)benzene
No. of Reaction Details1
Reaction ClassificationPreparation
Yield39 percent (BRN=4448026)
ReagentK2CO3
CatalystPd(OAc)2, PPh3
Time38 hour(s)
Temperature110
Other ConditionsCO atmosphere
Citation Pointer5609012; Journal; Tsuji, Jiro; Sato, Koji; Nagashima, Hideo; TETRAB; Tetrahedron; EN; 41; 2; 1985; 393-398;

Reaction (97 of 229)
Reaction ID1767834
Reactant BRN136380; 1098295
Reactant5-allyl-benzo[1,3]dioxole; tetrachloromethane
Product BRN4524942; 4448026
Product2-benzo[1,3]dioxol-5-ylmethyl-4,4,4-trichloro-butyric acid ethyl ester; 1,2-methylenedioxy-4-(2,4,4,4-tetrachlorobutyl)benzene
No. of Reaction Details1
Reaction ClassificationPreparation
Yield35 percent (BRN=4448026); 29 percent (BRN=4524942)
ReagentPd(OAc)2, PPh3, K2CO3, CO
Solventethanol
Time48 hour(s)
Temperature80
Pressure30400.004
Citation Pointer5543032; Journal; Tsuji, Jiro; Sato, Koji; Nagashima, Hideo; TELEAY; Tetrahedron Lett.; EN; 23; 8; 1982; 893-896;

Reaction (98 of 229)
Reaction ID1767835
Reactant BRN136380; 1209228
Reactant5-allyl-benzo[1,3]dioxole; formaldehyde
Product BRN174506; 5132930; 5152904; 174502
Product5-allyl-6-chloromethyl-benzo[1,3]dioxole; di(3,4-methylenedioxy-6-allylphenyl)methane; di(3,4-methylenedioxy-6-allylbenzyl) ether; (6-allyl-benzo[1,3]dioxol-5-yl)-methanol
No. of Reaction Details2
Reaction ClassificationPreparation
Reagentconc. hydrochloric acid, anhydrous CaCl2
Solventacetic acid
Other Conditions1) 20 deg C, 4 h, 2) 60 deg C, 30 min
Citation Pointer5631982; Journal; Lurik, B. B.; Volkov, Yu. P.; JOCYA9; J.Org.Chem.USSR (Engl.Transl.); EN; 1986; 338-341; ZORKAE; Zh.Org.Khim.; RU; 22; 2; 1986; 384-387;

Reaction (99 of 229)
Reaction ID1767836
Reactant BRN136380; 1210640
Reactant5-allyl-benzo[1,3]dioxole; trichloromethyl-phosphonic acid diethyl ester
Product BRN6820596
Product(4-benzo[1,3]dioxol-5-yl-1,1,3-trichloro-butyl)-phosphonic acid diethyl ester
No. of Reaction Details1
Reaction ClassificationPreparation
Yield45 percent (BRN=6820596)
Catalystelectrolytic copper powder, 1,10-phenanthroline hydrat
Solvent1,2-dichloro-ethane
Temperature93 - 100
Citation Pointer5893651; Journal; Villemin, Didier; Sauvaget, Frederique; Hajek, Milan; TELEAY; Tetrahedron Lett.; EN; 35; 21; 1994; 3537-3538;

Reaction (100 of 229)
Reaction ID1767837
Reactant BRN136380; 1616336
Reactant5-allyl-benzo[1,3]dioxole; 1-bromo-hex-1-yne
Product BRN4482556
Product1-benzo[1,3]dioxol-5-yl-nonan-4-one
No. of Reaction Details2
Reaction ClassificationPreparation
CommentYield given. Multistep reaction
Citation Pointer5572223; Journal; Kulkarni, Surendra U.; Lee, Hsiupu D.; Brown, Herbert C.; SYNTBF; Synthesis; EN; 3; 1982; 193-195;

Reaction (101 of 229)
Reaction ID1767838
Reactant BRN1732543; 136380
Reactantbromo-trichloro-methane; 5-allyl-benzo[1,3]dioxole
Product BRN5030224
Product1,2-methylenedioxy-4-(2-bromo-4,4,4-trichlorobutyl)benzene
No. of Reaction Details1
Reaction ClassificationPreparation
Yield52 percent (BRN=5030224)
ReagentK2CO3
CatalystPd(OAc)2, PPh3
Solventbenzene
Time9 hour(s)
Temperature80
Other ConditionsCO atmosphere
Citation Pointer5609012; Journal; Tsuji, Jiro; Sato, Koji; Nagashima, Hideo; TETRAB; Tetrahedron; EN; 41; 2; 1985; 393-398;

Reaction (102 of 229)
Reaction ID1767839
Reactant BRN136380; 1733649
Reactant5-allyl-benzo[1,3]dioxole; 1-iodo-but-1-yne
Product BRN4431189
Product5-hept-4-enyl-benzo[1,3]dioxole
No. of Reaction Details2
Reaction ClassificationPreparation
CommentYield given. Multistep reaction
Citation Pointer5572224; Journal; Brown, Herbert C.; Lee, Hsiupu D.; Kulkarni, Surendra U.; SYNTBF; Synthesis; EN; 3; 1982; 195-197;

Reaction (103 of 229)
Reaction ID1767840
Reactant BRN136380; 1751370
Reactant5-allyl-benzo[1,3]dioxole; malonic acid
Product BRN200446
Product4-benzo[1,3]dioxol-5-yl-butyric acid
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1., O3
Catalyst3., Pd-C/H2
Other Conditions1., Me2S; 2., piperidine-AcOH;
CommentYield given. Multistep reaction
Citation Pointer5664588; Journal; Tsuda, Yoshisuke; Hosoi, Shinzo; Ohshima, Takeshi; Kaneuchi, Satomi; Murata, Masami; et al.; CPBTAL; Chem.Pharm.Bull.; EN; 33; 8; 1985; 3574-3577;

Reaction (104 of 229)
Reaction ID1767841
Reactant BRN136380; 1766154
Reactant5-allyl-benzo[1,3]dioxole; 4-nitro-butyric acid methyl ester
Product BRN3627224
Product3-(5-benzo[1,3]dioxol-5-ylmethyl-4,5-dihydro-isoxazol-3-yl)-propionic acid methyl ester
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentphenyl isocyanate, Et3N
Solventbenzene
Other Conditions1) room temperature, 2) 2 h, reflux
Citation Pointer5513553; Journal; Baraldi, P. G.; Chiarini, A.; Leoni, A.; Manfredini, S.; Simoni, D.; Zanirato, V.; JHTCAD; J.Heterocycl.Chem.; EN; 27; 3; 1990; 557-561;

Reaction (105 of 229)
Reaction ID1767842
Reactant BRN136380; 1900390
Reactant5-allyl-benzo[1,3]dioxole; carbon dioxide
Product BRN200446
Product4-benzo[1,3]dioxol-5-yl-butyric acid
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1) n-propylmagnesium iodide
Catalyst1) TiCl4
Other Conditions1) ether, -20 deg C
CommentYield given. Multistep reaction
Citation Pointer5617279; Journal; Sanchez, I. H.; Mendoza, M. T.; Aguilar, M. A.; Martell, A. E.; Gonzalez, M. E.; Lemini, C.; CMLTAG; Chem.Lett.; EN; 1980; 1501-1502;

Reaction (106 of 229)
Reaction ID1767843
Reactant BRN136380; 2041680
Reactant5-allyl-benzo[1,3]dioxole; 4-methoxy-benzaldehyde (E)-oxime
Product BRN5122192
Product5-benzo[1,3]dioxol-5-ylmethyl-3-(4-methoxy-phenyl)-4,5-dihydro-isoxazole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield90 percent (BRN=5122192)
Reagentchloramine-T
Solventethanol
Time3 hour(s)
Other ConditionsHeating
Citation Pointer5642804; Journal; Hassner, Alfred; Rai, K. M. Lokanatha; SYNTBF; Synthesis; EN; 1; 1989; 57-59;

Reaction (107 of 229)
Reaction ID1767844
Reactant BRN2041800; 136380
Reactant5-bromo-tropolone; 5-allyl-benzo[1,3]dioxole
Product BRN4756061
Product5-(3-benzo[1,3]dioxol-5-yl-propenyl)-2-hydroxy-cyclohepta-2,4,6-trienone
No. of Reaction Details1
Reaction ClassificationPreparation
Yield83 percent (BRN=4756061)
ReagentEt3N
CatalystPd(PPh3)4
Solventtetrahydrofuran
Time20 hour(s)
Temperature100 - 110
Citation Pointer5586569; Journal; Horino, Hiroshi; Asao, Toyonobu; Inoue, Naoto; BCSJA8; Bull.Chem.Soc.Jpn.; EN; 64; 1; 1991; 183-190;

Reaction (108 of 229)
Reaction ID1767845
Reactant BRN2042662; 136380
Reactant3-iodo-tropolone; 5-allyl-benzo[1,3]dioxole
Product BRN4757270
Product3-(3-benzo[1,3]dioxol-5-yl-propenyl)-2-hydroxy-cyclohepta-2,4,6-trienone
No. of Reaction Details1
Reaction ClassificationPreparation
Yield34 percent (BRN=4757270)
ReagentEt3N
CatalystPd(PPh3)4
Solventtetrahydrofuran
Temperature100 - 110
Citation Pointer5586569; Journal; Horino, Hiroshi; Asao, Toyonobu; Inoue, Naoto; BCSJA8; Bull.Chem.Soc.Jpn.; EN; 64; 1; 1991; 183-190;

Reaction (109 of 229)
Reaction ID1767846
Reactant BRN136380; 2054576
Reactant5-allyl-benzo[1,3]dioxole; 3,4,5-trimethoxy-benzaldehyde (E)-oxime
Product BRN5148060
Product3-(3,4,5-Trimethoxy)phenyl-5-(3,4-methylenedioxy)benzyl-4,5-dihydroisoxazole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield93 percent (BRN=5148060)
Reagentchloramine-T
Solventethanol
Time3 hour(s)
Other ConditionsHeating
Citation Pointer5642804; Journal; Hassner, Alfred; Rai, K. M. Lokanatha; SYNTBF; Synthesis; EN; 1; 1989; 57-59;

Reaction (110 of 229)
Reaction ID1767847
Reactant BRN3317105; 136380
Reactant3,4,5-trimethoxy-benzaldehyde-oxime; 5-allyl-benzo[1,3]dioxole
Product BRN4826016
Product4-benzo[1,3]dioxol-5-ylmethyl-3-(3,4,5-trimethoxy-phenyl)-4,5-dihydro-isoxazole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1.) iodobenzene dichloride, pyridine
Other Conditions1.) chloroform, RT, 0.5 h, 2.) chloroform, reflux, 24 h
CommentYield given. Multistep reaction
Citation Pointer5589730; Journal; Radhakrishna, A S; Sivaprakash, K; Singh, B B; SYNCAV; Synth.Commun.; EN; 21; 15,16; 1991; 1625-1629;

Reaction (111 of 229)
Reaction ID1767848
Reactant BRN3535302; 136380
ReactantN-chloro-1-octylamine; 5-allyl-benzo[1,3]dioxole
Product BRN4608943
Product1-(1-octylamino)-3-[3,4-(methylenedioxy)phenyl]propane hydrochloride
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1.) BH3*THF 2.)aq. sodium bicarbonate
Other Conditions1.) THF, room temp., 1h 2.) 0 deg C, 5 min.
CommentYield given. Multistep reaction
Citation Pointer5575062; Journal; Kabalka, George W.; McCollum Gary W.; Kunda, Sastry A.; JOCEAH; J.Org.Chem.; EN; 49; 1984; 1656-1658;

Reaction (112 of 229)
Reaction ID1767849
Reactant BRN136380; 385737
Reactant5-allyl-benzo[1,3]dioxole; acetic acid anhydride
Product BRN6394729; 2451785; 6402099
Productacetic acid 2-methoxy-5-propyl-phenyl ester; 1-acetoxy-2-methoxy-4-propyl-benzene; acetic acid 2-acetoxy-5-propyl-phenyl ester
No. of Reaction Details2
Reaction ClassificationPreparation
Reagent1.) diisobutylaluminum hydride
Other Conditions1.) toluene, 60 deg C 2.) toluene
CommentYield given. Multistep reaction. Yields of byproduct given
Citation Pointer5805304; Journal; Takano, Seiichi; Akiyama, Masashi; Ogasawara, Kunio; HTCYAM; Heterocycles; EN; 20; 11; 1983; 2237-2238;

Reaction (113 of 229)
Reaction ID1767850
Reactant BRN4351907; 136380
Reactanttetrachlorothiophenedioxide; 5-allyl-benzo[1,3]dioxole
Product BRN4522339
Product5-(2,3,4,5-tetrachloro-cyclohexa-2,4-dienylmethyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield75 percent (BRN=4522339)
Time1 hour(s)
Temperature100
Citation Pointer5564718; Journal; Raasch, Maynard S.; JOCEAH; J.Org.Chem.; EN; 45; 5; 1980; 856-867;

Reaction (114 of 229)
Reaction ID1767851
Reactant BRN136380; 4361247
Reactant5-allyl-benzo[1,3]dioxole; N-chloro-2-octylamine
Product BRN4608937
Product1-(2-octylamino)-3-[3,4-(methylenedioxy)phenyl]propane hydrochloride
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1.) BH3*THF 2.) aq. sodium bicarbonate
Other Conditions1.) THF, room temp., 1 h 2.) 0 deg C, 5 min
CommentYield given. Multistep reaction
Citation Pointer5575062; Journal; Kabalka, George W.; McCollum Gary W.; Kunda, Sastry A.; JOCEAH; J.Org.Chem.; EN; 49; 1984; 1656-1658;

Reaction (115 of 229)
Reaction ID1767852
Reactant BRN136380; 505943
Reactant5-allyl-benzo[1,3]dioxole; chloro-methoxy-methane
Product BRN174506
Product5-allyl-6-chloromethyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield85 percent (BRN=174506)
Solventacetic acid
Citation Pointer5833049; Journal; Barreiro, Eliazer J.; Costa, Paulo R. R.; Coelho, Fernando A. S.; Farias, Florence M. C. de; JRMPDM; J.Chem.Res.Miniprint; EN; 7; 1985; 2301-2332;

Reaction (116 of 229)
Reaction ID1767853
Reactant BRN5289906; 136380
ReactantC18H17NO2; 5-allyl-benzo[1,3]dioxole
Product BRN5064451
ProductN-(3,4-methylenedioxycinnamyl)acetohydroxamic acid
No. of Reaction Details1
Reaction ClassificationPreparation
Time2 hour(s)
Temperature85 - 90
Citation Pointer5621440; Journal; Corrie, John E.T.; Kirby, Gordon W.; Mackinnon, John W.M.; JCPRB4; J.Chem.Soc.Perkin Trans.1; EN; 1985; 883-886;

Reaction (117 of 229)
Reaction ID1767854
Reactant BRN5299052; 136380
ReactantC23H19NO2; 5-allyl-benzo[1,3]dioxole
Product BRN5104551
ProductN-(3,4-methylenedioxycinnamyl)benzohydroxamic acid
No. of Reaction Details1
Reaction ClassificationPreparation
Yield65 percent (BRN=5104551)
Time1.5 hour(s)
Temperature85
Citation Pointer5621440; Journal; Corrie, John E.T.; Kirby, Gordon W.; Mackinnon, John W.M.; JCPRB4; J.Chem.Soc.Perkin Trans.1; EN; 1985; 883-886;

Reaction (118 of 229)
Reaction ID1767855
Reactant BRN136380; 5916133
Reactant5-allyl-benzo[1,3]dioxole; [13C]carbon monoxide
Product BRN6730169
ProductC10(13)CH12O4
No. of Reaction Details1
Reaction ClassificationPreparation
CommentYield given. Multistep reaction
Citation Pointer5866883; Journal; Kabalka, George W.; Delgado, Mark C.; Sastry, Usha; Sastry, Kunda A. R.; JCCCAT; J.Chem.Soc.Chem.Commun.; EN; 21; 1982; 1273-1274;

Reaction (119 of 229)
Reaction ID1767856
Reactant BRN644139; 136380
ReactantN-(toluene-4-sulfonyl)-sulfur imide oxide; 5-allyl-benzo[1,3]dioxole
Product BRN4563202
ProductN-[(E)-3-(1,3-Benzodioxol-5-yl)-2-propenylsulfinyl]-p-toluolsulfonamid
No. of Reaction Details1
Reaction ClassificationPreparation
Yield91 percent (BRN=4563202)
Solventtoluene
Time6 hour(s)
Temperature20
Citation Pointer5556893; Journal; Kresze, Guenter; Bussas, Reinhard; LACHDL; Liebigs Ann.Chem.; GE; 6; 1980; 843-857;

Reaction (120 of 229)
Reaction ID1767857
Reactant BRN701872; 136380
ReactantN,N'-bis-(toluene-4-sulfonyl)-sulfur diimide; 5-allyl-benzo[1,3]dioxole
Product BRN4613903
ProductN1,N2-Ditosyl-3-(1,3-benzodioxol-5-yl)-2-propen-sulfinamidin
No. of Reaction Details1
Reaction ClassificationPreparation
Yield69 percent (BRN=4613903)
Solventtoluene
Time30 hour(s)
Temperature-20
Citation Pointer5556801; Journal; Bussas, Reinhard; Kresze, Guenter; LACHDL; Liebigs Ann.Chem.; GE; 4; 1980; 629-649;

Reaction (121 of 229)
Reaction ID1767858
Reactant BRN136380; 774120
Reactant5-allyl-benzo[1,3]dioxole; trichloroacetyl chloride
Product BRN6808332
Product3-benzo[1,3]dioxol-5-ylmethyl-2,2-dichloro-cyclobutanone
No. of Reaction Details1
Reaction ClassificationPreparation
Yield66 percent (BRN=6808332)
ReagentPOCl3, zinc-copper
Solventdiethyl ether
Time2.5 hour(s)
Other ConditionsAmbient temperature
Citation Pointer5895649; Journal; Honda, Toshio; Kimura, Nobuaki; Sato, Shigeki; Kato, Daishiro; Tominaga, Hideo; JCPRB4; J.Chem.Soc.Perkin Trans.1; EN; 8; 1994; 1043-1046;

Reaction (122 of 229)
Reaction ID1767859
Reactant BRN136380; 907949
Reactant5-allyl-benzo[1,3]dioxole; phenoxyacetic acid
Product BRN205842
Product5-benzo[1,3]dioxol-5-yl-pentanoic acid
No. of Reaction Details1
Reaction ClassificationPreparation
CommentYield given. Multistep reaction
Citation Pointer5533170; Journal; Hara, Shoji; Kishimura, Kotaro; Suzuki, Akira; Dhillon, Ranjit S.; JOCEAH; J.Org.Chem.; EN; 55; 26; 1990; 6356-6360;

Reaction (123 of 229)
Reaction ID1767860
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN150196; 150252
Product2-benzo[1,3]dioxol-5-yl-1-methyl-ethylamine; 3-benzo[1,3]dioxol-5-yl-propylamine
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1.) BH3*THF, 2.) aq. NH4OH, NaOCl
Other Conditions1.) THF, 0 deg C to r.t., 1 h, 2.) 0 deg C, 15 min
CommentYield given. Multistep reaction. Yields of byproduct given
Citation Pointer5643971; Journal; Kabalka, George W.; Sastry, Kunda A. R.; McCollum, Gary W.; Yoshioka, Hiroaki; JOCEAH; J.Org.Chem.; EN; 46; 21; 1981; 4296-4298;

Reaction (124 of 229)
Reaction ID1767861
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN150253; 150198
Product3-benzo[1,3]dioxol-5-yl-propan-1-ol; 1-benzo[1,3]dioxol-5-yl-propan-2-ol
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1.) BH3, 2.) sodium perborate
Other Conditions1.) THF, from 0 deg C to RT, 2 h, 2.) H2O, 25 deg C, 2 h
CommentYield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts
Citation Pointer5568961; Journal; Kabalka, George W.; Shoup, Timothy M.; Goudgaon, Naganna M.; JOCEAH; J.Org.Chem.; EN; 54; 25; 1989; 5930-5933;

Reaction (125 of 229)
Reaction ID1767862
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN150219; 150287
Product5-(2-bromo-propyl)-benzo[1,3]dioxole; 5-(3-bromo-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1.) BH3, 2.) Br2
Other Conditions1.) 0 deg C, 1 h, THF, 2.) 0 deg C, 30 min, THF, H2O
CommentYield given. Multistep reaction. Yields of byproduct given
Citation Pointer5573752; Journal; Kabalka, George W.; Sastry, Kunda A. R.; Hsu, Henry C.; Hylarides, Mark D.; JOCEAH; J.Org.Chem.; EN; 46; 15; 1981; 3113-3115;

Reaction (126 of 229)
Reaction ID1767863
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN150251
Product3-benzo[1,3]dioxol-5-yl-prop-2-en-1-ol
No. of Reaction Details1
Reaction ClassificationPreparation
Yield33 percent (BRN=150251)
ReagentSeO2
SolventH2O; dioxane
Time5 min
Temperature85
Citation Pointer5571698; Journal; Pan, Hsi-Lung; Cole, Carol-Ann; Fletcher, T. Lloyd; SYNTBF; Synthesis; EN; 10; 1980; 813-814;

Reaction (127 of 229)
Reaction ID1767864
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN150252
Product3-benzo[1,3]dioxol-5-yl-propylamine
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1.) BH3-THF, 2.) trimethylsilylazide, methanol
Other Conditions1.) reflux, 2.) reflux, 40 h
CommentYield given. Multistep reaction
Citation Pointer5738537; Journal; Kabalka, George W.; Goudgaon, Naganna M.; Liang, Yanhong; SYNCAV; Synth.Commun.; EN; 18; 12; 1988; 1363-1370;

Reaction (128 of 229)
Reaction ID1767865
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN150253
Product3-benzo[1,3]dioxol-5-yl-propan-1-ol
No. of Reaction Details7
Reaction ClassificationPreparation
Reagent1.) B2H6, 2.) 10 percent NaOH, 30 percent H2O2
Other Conditions1.) THF, 0 deg C, 2 h, 2.) MeOH, H2O, 60 deg C, 12 h
CommentYield given; Multistep reaction
Citation Pointer6159391; Journal; Araujo-Junior, Joao X. de; Barreiro, Eliezer J.; Parente, Jose P.; Fraga, Carlos A. M.; SYNCAV; Synth.Commun.; EN; 29; 2; 1999; 263 - 274;

Reaction (129 of 229)
Reaction ID1767866
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN156510
Product3-benzo[1,3]dioxol-5-yl-propionaldehyde
No. of Reaction Details3
Reaction ClassificationPreparation
Reagent1.) disiamylborane; 2.) PCC
Other Conditions1.) ether, 2 h, 0 deg C; 2.) CH2Cl2, reflux, 2 h
CommentYield given. Multistep reaction
Citation Pointer5620640; Journal; Brown, Herbert C.; Kulkarni, Surendra U.; Rao, C. Gundu; Patil, Vemanna D.; TETRAB; Tetrahedron; EN; 42; 20; 1986; 5515-5522;

Reaction (130 of 229)
Reaction ID1767867
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN164033
Productbenzo[1,3]dioxol-5-yl-propan-2-one
No. of Reaction Details1
Reaction ClassificationPreparation
Yield85 percent (BRN=164033)
ReagentPdCl2, tri(4-bromophenyl)amine
Solventacetonitrile; H2O
Other ConditionsAmbient temperature; electrochemical oxidation, 0.5 M Et4NOTs-(Pt)-(Pt) system
Citation Pointer5895944; Journal; Inokuchi, Tsutomu; Ping, Liu; Hamaue, Fumihiro; Izawa, Miyoko; Torii, Sigeru; CMLTAG; Chem.Lett.; EN; 1; 1994; 121-124;

Reaction (131 of 229)
Reaction ID1767868
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN5078664; 5022958; 164033
Product5-(2-methoxy-3-nitrooxy-propyl)-benzo[1,3]dioxole; 5-(2,3-dimethoxy-propyl)-benzo[1,3]dioxole; benzo[1,3]dioxol-5-yl-propan-2-one
No. of Reaction Details1
Reaction ClassificationPreparation
Yield10 percent (BRN=164033); 30 percent (BRN=5078664); 38 percent (BRN=5022958)
Reagentthallium(III) nitrate trihydrate
Solventmethanol
Citation Pointer5617635; Journal; Niwa, Masatake; Noda, Hitoshi; Kobayashi, Hiroki; Yamamura, Shosuke; CMLTAG; Chem.Lett.; EN; 1980; 85-88;

Reaction (132 of 229)
Reaction ID1767869
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN4180990
Product1-benzo[1,3]dioxol-5-yl-propenone
No. of Reaction Details1
Reaction ClassificationPreparation
Yield65.1 percent (BRN=4180990)
Reagent<Ru(IV)(trpy)(bpy)O>(2+)
SolventH2O; 2-methyl-propan-2-ol
Other ConditionsAmbient temperature; electrolysis in phosphate buffer (pH 6.8)
Citation Pointer5550690; Journal; Madurro, Joao Marcos; Chiericato, Glaico Jr.; Giovani, Wagner F.De; Romero, Jose Ricardo; TELEAY; Tetrahedron Lett.; EN; 29; 7; 1988; 765-768;

Reaction (133 of 229)
Reaction ID1767870
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN4675203
Product5-(3-iodo-propyl)-benzo[1,3]dioxole
No. of Reaction Details4
Reaction ClassificationPreparation
Reagent1.) dicyclohexylborane, 2.) NaOAc, I2
Other Conditions1.) 0 deg C -> 25 deg C, 2 h, 2.) MeOH, 1 h
CommentYield given. Multistep reaction
Citation Pointer5772399; Journal; Kabalka, George W.; Sastry, K. A. R.; Sastry, K. Usha; SYNCAV; Synth.Commun.; EN; 12; 2; 1982; 101-106;

Reaction (134 of 229)
Reaction ID1767871
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN82642; 82641
Product5-trans-propenyl-benzo[1,3]dioxole; 5-cis-propenyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour
ReagentKOH-Aliquat 336 (5percent)
Time5 min
Temperature80
Other Conditionsother aryl-olefines; var. basic system, var. time and temp.
Citation Pointer5752478; Journal; Thach, Le Ngoc; Hanh, Duong-Lieu; Hiep, Nguyen Ba; Radhakrishna, A.S.; Singh, B.B.; Loupy, A.; SYNCAV; Synth.Commun.; EN; 23; 10; 1993; 1379-1384;

Reaction (135 of 229)
Reaction ID1767872
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN82642
Product5-trans-propenyl-benzo[1,3]dioxole
No. of Reaction Details4
Reaction ClassificationPreparation
Yield98 percent (BRN=82642)
ReagentKOH
Solventbutan-1-ol
Time3 hour(s)
Other ConditionsAmbient temperature
Citation Pointer5713517; Journal; Barreiro, Eliezer J.; Lima, Marco E.F.; JPMSAE; J.Pharm.Sci.; EN; 81; 12; 1992; 1219-1222;

Reaction (136 of 229)
Reaction ID1869601
Reactant BRN171593
Reactant5-(2,3-dibromo-propyl)-benzo[1,3]dioxole
Product BRN136380
Product5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield95 percent (BRN=136380)
Reagent<2-<(dimethylamino)methyl>phenyl>dimethyltin hydride
Solventtetrahydrofuran
Temperature20
Citation Pointer5754765; Journal; Vedejs, E.; Duncan, S. M.; Haight, A. R.; JOCEAH; J.Org.Chem.; EN; 58; 11; 1993; 3046-3050;

Reaction (137 of 229)
Reaction ID2557648
Reactant BRN4438102
Reactant1-benzo[1,3]dioxol-5-yl-3-trimethylsilanyl-propan-1-ol
Product BRN136380
Product5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield43 percent (BRN=136380)
ReagentBF3*AcOH
SolventCH2Cl2
Time5 min
Temperature25
Citation Pointer5570012; Journal; Wilson, Stephen R.; Shedrinsky, Alexander; JOCEAH; J.Org.Chem.; EN; 47; 10; 1982; 1983-1984;

Reaction (138 of 229)
Reaction ID3197078
Reactant BRN5750319
Reactant4R-(-)-illicinone-A
Product BRN5750311; 5740842; 5750312; 136380
Product2S,4R-(-)-illicinone-B; 4-allyl-6-hydroxy-6-(3-methyl-but-2-enyl)-cyclohex-2-enone; 2R,4R-(-)-illicinone-B; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details4
Reaction ClassificationPreparation
Yield0.2 g (BRN=5750311); 90 mg (BRN=5740842); 0.11 g (BRN=5750312); 175 mg (BRN=136380)
ReagentNaBH4
Solventmethanol
Time1 hour(s)
Other ConditionsAmbient temperature
CommentFurther byproducts given
Citation Pointer5682747; Journal; Yakushijin, Kenichi; Tohshima, Tomoko; Kitagawa, Eiji; Suzuki, Rika; Sekikawa, Junko; et al.; CPBTAL; Chem.Pharm.Bull.; EN; 32; 1; 1984; 11-22;

Reaction (139 of 229)
Reaction ID3197079
Reactant BRN5750319
Reactant4R-(-)-illicinone-A
Product BRN5750311; 136380; 5750312; 5740843
Product2S,4R-(-)-illicinone-B; 5-allyl-benzo[1,3]dioxole; 2R,4R-(-)-illicinone-B; 4-allyl-6-hydroxy-6-(3-methyl-but-2-enyl)-cyclohex-2-enone
No. of Reaction Details1
Reaction ClassificationPreparation
Yield0.2 g (BRN=5750311); 175 mg (BRN=136380); 0.11 g (BRN=5750312); 60 mg (BRN=5740843)
ReagentNaBH4
Solventmethanol
Time1 hour(s)
Other ConditionsAmbient temperature
CommentFurther byproducts given
Citation Pointer5682747; Journal; Yakushijin, Kenichi; Tohshima, Tomoko; Kitagawa, Eiji; Suzuki, Rika; Sekikawa, Junko; et al.; CPBTAL; Chem.Pharm.Bull.; EN; 32; 1; 1984; 11-22;

Reaction (140 of 229)
Reaction ID3951296
Reactant BRN136380; 3587243
Reactant5-allyl-benzo[1,3]dioxole; hydrocyanic acid; sodium salt
Product BRN7096375
Product4-(6-bromo-benzo[1,3]dioxol-5-yl)-3-hydroxy-butyramide
No. of Reaction Details1
Reaction ClassificationPreparation
CommentYield given. Multistep reaction
Citation Pointer5940347; Journal; Barreiro, Eliezer J.; Costa, Paulo R. R.; Barros, Perola Regina V. R.; Queiroz, Waldemir M.; JRMPDM; J.Chem.Res.Miniprint; EN; 4; 1982; 1142-1165;

Reaction (141 of 229)
Reaction ID3951297
Reactant BRN136380; 7094329
Reactant5-allyl-benzo[1,3]dioxole; h5-cyclopentadienylbis(carbonyl)(1-phenylthioethyl)iron(II)
Product BRN7111867; 7111866
Product5-(2-methyl-cyclopropylmethyl)-benzo[1,3]dioxole; 5-(2-methyl-cyclopropylmethyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagenttrimethyloxonium tetrafluoroborate (TMO)
SolventCH2Cl2
Temperature25
CommentYield given. Yields of byproduct given. Title compound not separated from byproducts
Citation Pointer5934802; Journal; Kremer, Kenneth A. M.; Helquist, Paul; JORCAI; J.Organomet.Chem.; EN; 285; 1985; 231-252;

Reaction (142 of 229)
Reaction ID3951298
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN150198
Product1-benzo[1,3]dioxol-5-yl-propan-2-ol
No. of Reaction Details2
Reaction ClassificationPreparation
Reagent1.) Hg(OAc)2; 2.) NaBH4, 3M NaOH
Other Conditions1.) THF/H2O, room temp., 1 h; 2.) THF/H2O, 1 h
CommentYield given. Multistep reaction
Citation Pointer5940347; Journal; Barreiro, Eliezer J.; Costa, Paulo R. R.; Barros, Perola Regina V. R.; Queiroz, Waldemir M.; JRMPDM; J.Chem.Res.Miniprint; EN; 4; 1982; 1142-1165;

Reaction (143 of 229)
Reaction ID3951299
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN197708; 7094342; 197687
Product2-bromo-3-(6-bromo-benzo[1,3]dioxol-5-yl)-propan-1-ol; 3-bromo-2-(6-bromo-benzo[1,3]dioxol-5-yl)-propan-1-ol; 1-bromo-3-(6-bromo-benzo[1,3]dioxol-5-yl)-propan-2-ol
No. of Reaction Details3
Reaction ClassificationPreparation
Yield40 percent (BRN=197687); 12 percent (BRN=197708)
ReagentNBS
Solventacetone; H2O
Time1.5 hour(s)
Other ConditionsAmbient temperature
Citation Pointer5940347; Journal; Barreiro, Eliezer J.; Costa, Paulo R. R.; Barros, Perola Regina V. R.; Queiroz, Waldemir M.; JRMPDM; J.Chem.Res.Miniprint; EN; 4; 1982; 1142-1165;

Reaction (144 of 229)
Reaction ID4153086
Reactant BRN393006; 136380
Reactant2,3,5,6-tetrachloro-[1,4]benzoquinone; 5-allyl-benzo[1,3]dioxole
Product BRN7226817
Product5-allyl-2-(4-hydroxy-2,3,5,6-tetrachlorophenoxy)-1,3-benzodioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield94 percent (BRN=7226817)
Solventbenzene
Time8 hour(s)
Other ConditionsIrradiation
Citation Pointer5959025; Journal; Yan, Bao-Zhen; Zhang, Zhao-Guo; Yuan, Han-Cheng; Wang, Long-Cheng; Xu, Jian-Hua; JCPKBH; J.Chem.Soc.Perkin Trans.2; EN; 12; 1994; 2545-2550;

Reaction (145 of 229)
Reaction ID4465107
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN197707
Product5-bromo-6-(2,3-dibromo-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield91 percent (BRN=197707)
ReagentKMnO4, aq. HBr
Solventacetonitrile
Citation Pointer6016381; Journal; Liu, Lilian Kao; Lin-Ching-Shan; JCCTAC; J.Chin.Chem.Soc.(Taipei); EN; 43; 1; 1996; 61-66;

Reaction (146 of 229)
Reaction ID4465108
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN7480546
Product5-chloro-6-(2,3-dichloro-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield85 percent (BRN=7480546)
ReagentKMnO4, aq. HCl
Solventacetonitrile
Citation Pointer6016381; Journal; Liu, Lilian Kao; Lin-Ching-Shan; JCCTAC; J.Chin.Chem.Soc.(Taipei); EN; 43; 1; 1996; 61-66;

Reaction (147 of 229)
Reaction ID4512387
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN200446
Product4-benzo[1,3]dioxol-5-yl-butyric acid
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1.) TiCl4, 2.) CH3CH2CH2Br
Other Conditions1.) Et2O, THF, a.) RT, 3h,b.) reflux 9h
CommentYield given. Multistep reaction
Citation Pointer6022611; Journal; Tsuda, Yoshisuke; Ohshima, Takeshi; Hosoi, Shinzo; Kaneuchi, Satomi; Kiuchi, Fumiyuki; et al.; CPBTAL; Chem.Pharm.Bull.; EN; 44; 3; 1996; 500-508;

Reaction (148 of 229)
Reaction ID4669193
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN383839
Product2-benzo[1,3]dioxol-5-yl-ethanol
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1.) O3; 2.) NaBH4
Other Conditions1.) CH2Cl2, EtOH, -78 deg C
CommentYield given. Multistep reaction
Citation Pointer6052217; Journal; Oliveira, Eduardo R. de; Dumas, Francoise; d'Angelo, Jean; TELEAY; Tetrahedron Lett.; EN; 38; 21; 1997; 3723-3726;

Reaction (149 of 229)
Reaction ID4762963
Reactant BRN1825034; 136380
ReactantN-phenyl-N'-(3,4,5-trimethoxy-benzylidene)-hydrazine; 5-allyl-benzo[1,3]dioxole
Product BRN7836293
Product5-benzo[1,3]dioxol-5-ylmethyl-1-phenyl-3-(3,4,5-trimethoxy-phenyl)-4,5-dihydro-1H-pyrazole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield85 percent (BRN=7836293)
ReagentHg(OAc)2
Solventethanol
Time3 hour(s)
Other ConditionsHeating
Citation Pointer6072223; Journal; Rai, K. M. Lokanatha; Linganna, N.; SYNCAV; Synth.Commun.; EN; 27; 21; 1997; 3737-3744;

Reaction (150 of 229)
Reaction ID4762964
Reactant BRN136380; 1843623
Reactant5-allyl-benzo[1,3]dioxole; 3,4-dimethoxy-benzaldehyde phenylhydrazone
Product BRN7833881
Product5-benzo[1,3]dioxol-5-ylmethyl-3-(3,4-dimethoxy-phenyl)-1-phenyl-4,5-dihydro-1H-pyrazole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield80 percent (BRN=7833881)
ReagentHg(OAc)2
Solventethanol
Time3 hour(s)
Other ConditionsHeating
Citation Pointer6072223; Journal; Rai, K. M. Lokanatha; Linganna, N.; SYNCAV; Synth.Commun.; EN; 27; 21; 1997; 3737-3744;

Reaction (151 of 229)
Reaction ID4762965
Reactant BRN743427; 136380
Reactantbenzaldehyde phenylhydrazone; 5-allyl-benzo[1,3]dioxole
Product BRN3008857
Product5-benzo[1,3]dioxol-5-ylmethyl-1,3-diphenyl-4,5-dihydro-1H-pyrazole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield80 percent (BRN=3008857)
ReagentHg(OAc)2
Solventethanol
Time3 hour(s)
Other ConditionsHeating
Citation Pointer6072223; Journal; Rai, K. M. Lokanatha; Linganna, N.; SYNCAV; Synth.Commun.; EN; 27; 21; 1997; 3737-3744;

Reaction (152 of 229)
Reaction ID4770515
Reactant BRN136380; 23562
Reactant5-allyl-benzo[1,3]dioxole; benzo[1,3]dioxole-5-carbaldehyde phenylhydrazone
Product BRN7833880
Product3-benzo[1,3]dioxol-5-yl-5-benzo[1,3]dioxol-5-ylmethyl-1-phenyl-4,5-dihydro-1H-pyrazole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield80 percent (BRN=7833880)
ReagentHg(OAc)2
Solventethanol
Time3 hour(s)
Other ConditionsHeating
Citation Pointer6072223; Journal; Rai, K. M. Lokanatha; Linganna, N.; SYNCAV; Synth.Commun.; EN; 27; 21; 1997; 3737-3744;

Reaction (153 of 229)
Reaction ID4862860
Reactant BRN136380; 1098501
Reactant5-allyl-benzo[1,3]dioxole; allylbenzene
Product BRN7939142; 2206992; 7928961
ProductC18H16O4; cis-1,4-Diphenylbut-2-en; 5-(4-phenyl-but-2-enyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
CatalystCl2(PCy3)2Ru=CHPh
SolventCH2Cl2
Time6 hour(s)
Temperature45 - 50
CommentTitle compound not separated from byproducts
Citation Pointer6095331; Journal; Giger, Thomas; Wigger, Maria; Audetat, Stephan; Benner, Steven A.; SYNLES; Syn.Lett.; EN; 6; 1998; 688-691;

Reaction (154 of 229)
Reaction ID4862861
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN7928961; 7939142
Product5-(4-phenyl-but-2-enyl)-benzo[1,3]dioxole; C18H16O4
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentallylbenzene
CatalystCl2(PCy3)2Ru=CHPh
SolventCH2Cl2
Time6 hour(s)
Temperature45 - 50
CommentTitle compound not separated from byproducts
Citation Pointer6095331; Journal; Giger, Thomas; Wigger, Maria; Audetat, Stephan; Benner, Steven A.; SYNLES; Syn.Lett.; EN; 6; 1998; 688-691;

Reaction (155 of 229)
Reaction ID4928009
Reactant BRN136380; 385737
Reactant5-allyl-benzo[1,3]dioxole; acetic acid anhydride
Product BRN8041917; 8041916
Productacetic acid 1-acetoxymethyl-2-benzo[1,3]dioxol-5-yl-ethyl ester; (R)-(-)-5-(2,3-diacetoxypropyl)-1,3-benzodioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1.) AD-mix-b, methanesulfonamide, H2O, 2.) pyridine
Other Conditions1.) t-BuOH, 0 deg C, 30 h, 2.) 25 deg C, 12 h
CommentYield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts
Citation Pointer6100568; Journal; Mohan, H. Rama; Rao, A. S.; IJSBDB; Indian J.Chem.Sect.B; EN; 37; 1; 1998; 78-79;

Reaction (156 of 229)
Reaction ID4928010
Reactant BRN136380; 607898
Reactant5-allyl-benzo[1,3]dioxole; toluene-4-sulfonyl chloride
Product BRN8043091; 8043090
Producttoluene-4-sulfonic acid 3-benzo[1,3]dioxol-5-yl-2-hydroxy-propyl ester; toluene-4-sulfonic acid 3-benzo[1,3]dioxol-5-yl-2-hydroxy-propyl ester
No. of Reaction Details1
Reaction ClassificationPreparation
Reagent1.) AD-mix-b, methanesulfonamide, H2O, 2.) Et3N, 4-dimethylaminopyridine
Other Conditions1.) t-BuOH, 0 deg C, 30 h, 2.) CH2Cl2, 0 deg C, 36 h
CommentYield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts
Citation Pointer6100568; Journal; Mohan, H. Rama; Rao, A. S.; IJSBDB; Indian J.Chem.Sect.B; EN; 37; 1; 1998; 78-79;

Reaction (157 of 229)
Reaction ID4928011
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN174506
Product5-allyl-6-chloromethyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Citation Pointer6097742; Journal; Cave, Christian; Valancogne, Ingrid; Casas, Ramon; d'Angelo, Jean; TELEAY; Tetrahedron Lett.; EN; 39; 20; 1998; 3133-3136;

Reaction (158 of 229)
Reaction ID4928012
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN8037969; 8037970
Product3-benzo[1,3]dioxol-5-yl-propane-1,2-diol; (R)-(+)-5-(2,3-dihydroxypropyl)-1,3-benzodioxole
No. of Reaction Details1
Reaction ClassificationPreparation
ReagentAD-mix-b, methanesulfonamide, H2O
Solvent2-methyl-propan-2-ol
Time30 hour(s)
Temperature0
CommentYield given. Yields of byproduct given. Title compound not separated from byproducts
Citation Pointer6100568; Journal; Mohan, H. Rama; Rao, A. S.; IJSBDB; Indian J.Chem.Sect.B; EN; 37; 1; 1998; 78-79;

Reaction (159 of 229)
Reaction ID5249089
Reactant BRN136380; 1072149
Reactant5-allyl-benzo[1,3]dioxole; 4-methoxy-benzaldehyde oxime
Product BRN5122192
Product5-benzo[1,3]dioxol-5-ylmethyl-3-(4-methoxy-phenyl)-4,5-dihydro-isoxazole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield75 percent (BRN=5122192)
ReagentHg(OAc)2
Solventethanol
Time3 hour(s)
Other ConditionsHeating
Reaction TypeAddition
Citation Pointer6199383; Journal; Rai, K. M. Lokanatha; Linganna, N.; Hassner, Alfred; Anjanamurthy, C.; OPPIAK; Org.Prep.Proced.Int.; EN; 24; 1; 1992; 91 - 94;

Reaction (160 of 229)
Reaction ID5249090
Reactant BRN136380; 8138647
Reactant5-allyl-benzo[1,3]dioxole; benzo[1,3]dioxole-5-carbaldehyde oxime
Product BRN8396127
Product3-benzo[1,3]dioxol-5-yl-5-benzo[1,3]dioxol-5-ylmethyl-4,5-dihydro-isoxazole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield70 percent (BRN=8396127)
ReagentHg(OAc)2
Solventethanol
Time3 hour(s)
Other ConditionsHeating
Reaction TypeAddition
Citation Pointer6199383; Journal; Rai, K. M. Lokanatha; Linganna, N.; Hassner, Alfred; Anjanamurthy, C.; OPPIAK; Org.Prep.Proced.Int.; EN; 24; 1; 1992; 91 - 94;

Reaction (161 of 229)
Reaction ID5249091
Reactant BRN136380; 8312775
Reactant5-allyl-benzo[1,3]dioxole; 3,4,5-trimethoxy-benzaldehyde oxime
Product BRN5148060
Product3-(3,4,5-Trimethoxy)phenyl-5-(3,4-methylenedioxy)benzyl-4,5-dihydroisoxazole
No. of Reaction Details1
Reaction ClassificationPreparation
Yield80 percent (BRN=5148060)
ReagentHg(OAc)2
Solventethanol
Time3 hour(s)
Other ConditionsHeating
Reaction TypeAddition
Citation Pointer6199383; Journal; Rai, K. M. Lokanatha; Linganna, N.; Hassner, Alfred; Anjanamurthy, C.; OPPIAK; Org.Prep.Proced.Int.; EN; 24; 1; 1992; 91 - 94;

Reaction (162 of 229)
Reaction ID5317987
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN1937030
Product4-allyl-pyrocatechol
No. of Reaction Details1
Reaction ClassificationPreparation
Yield88 percent (BRN=1937030)
Reagentn-Bu4NI; BCl3
SolventCH2Cl2
Time1 hour(s)
Temperature-78
Reaction Typedealkylation
Citation Pointer6222371; Journal; Brooks, Paige R.; Wirtz, Michael C.; Vetelino, Michael G.; Rescek, Diane M.; Woodworth, Graeme F.; Morgan, Bradley P.; Coe, Jotham W.; JOCEAH; J.Org.Chem.; EN; 64; 26; 1999; 9719 - 9721;

Reaction (163 of 229)
Reaction ID5368297
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
No. of Reaction Details4
Reaction ClassificationChemical behaviour (half reaction)
Other Conditionsin Gegenwart von anderen ungesaettigten Verbindungen.Hydrogenation
Subject StudiedKinetics
CommentHandbook
Citation Pointer506396; Journal; Lebedew; Platonow; JCSOA9; J.Chem.Soc.; 1930; 332, 333; ZRKOAC; Zh.Russ.Fiz.-Khim.O-va; 61; 1929; 2165, 2166;506397; Journal; Lebedew; Jakubtschik; ZRKOAC; Zh.Russ.Fiz.-Khim.O-va; 60; 1928; 816, 827; CHZEA6; Chem.Zentralbl.; GE; 99; II; 1928; 1315;

Reaction (164 of 229)
Reaction ID5368298
Reactant BRN1098295; 136380
Reactanttetrachloromethane; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Temperature0
Other Conditionsim diffusen Tageslicht
Subject StudiedKinetics
CommentHandbook
Citation Pointer509494; Journal; Waterman; Priester; RTCPA3; Recl.Trav.Chim.Pays-Bas; 47; 1928; 849 Anm. 3; 1033;

Reaction (165 of 229)
Reaction ID5368299
Reactant BRN1098464; 136380
Reactantperoxyacetic acid; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
CommentHandbook
Citation Pointer506384; Journal; Boeeseken; Elsen; RTCPA3; Recl.Trav.Chim.Pays-Bas; 48; 1929; 367;

Reaction (166 of 229)
Reaction ID5372129
Reactant BRN1210120; 1731042; 136380
Reactantperoxybenzoic acid; trichloromethane; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Temperature0
Subject StudiedKinetics
CommentHandbook
Citation Pointer1543242; Journal; Meerwein; JPCEAO; J.Prakt.Chem.; <2> 113; 1926; 11, 25;

Reaction (167 of 229)
Reaction ID5380162
Reactant BRN3587193; 1731042; 136380
ReactantBr2; trichloromethane; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Temperature25
Subject StudiedKinetics
CommentHandbook
Citation Pointer504613; Journal; Abati; GCITA9; Gazz.Chim.Ital.; 40 II; 1910; 92;

Reaction (168 of 229)
Reaction ID5380244
Reactant BRN3587194; 136380
Reactantiodine; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
CommentHandbook
Citation Pointer509494; Journal; Waterman; Priester; RTCPA3; Recl.Trav.Chim.Pays-Bas; 47; 1928; 849 Anm. 3; 1033;

Reaction (169 of 229)
Reaction ID5380312
Reactant BRN3587310; 136380
ReactantNitric acid; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Other Conditionsverpufft heftig
CommentHandbook
Citation Pointer500471; Journal; Schiff; CHBEAM; Chem.Ber.; 17; 1884; 1937;500501; Journal; Eijkman; RTCPA3; Recl.Trav.Chim.Pays-Bas; 4; 1885; 39;

Reaction (170 of 229)
Reaction ID5395876
Reactant BRN1718733; 136380
Reactanthydrogen; colloidal palladium; ethanol; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Other ConditionsHydrogenation
Subject StudiedRate constant
CommentHandbook
Citation Pointer1531088; Journal; Albright; JACSAT; J.Amer.Chem.Soc.; 36; 1914; 2197;

Reaction (171 of 229)
Reaction ID5396445
Reactant BRN136380
Reactantnickel; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Temperature140 - 180
Other ConditionsHydrogenation
Subject StudiedKinetics
CommentHandbook
Citation Pointer506399; Journal; Armstrong; Hilditch; PRLAAZ; Proc.R.Soc.London A; 98; 1921; 29; CHZEA6; Chem.Zentralbl.; GE; 92; I; 1921; 650;

Reaction (172 of 229)
Reaction ID5396632
Reactant BRN1718733; 136380
Reactantethanol; palladium black; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Temperature25
Pressure1520 - 2280
Other ConditionsHydrogenation
Subject StudiedKinetics
CommentHandbook
Citation Pointer506360; Journal; Kern; Shriner; Adams; JACSAT; J.Amer.Chem.Soc.; 47; 1925; 1149;

Reaction (173 of 229)
Reaction ID5396813
Reactant BRN1718733; 136380
Reactantethanol; platinum black; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Temperature25
Pressure1520 - 2280
Other ConditionsHydrogenation
Subject StudiedKinetics
CommentHandbook
Citation Pointer506360; Journal; Kern; Shriner; Adams; JACSAT; J.Amer.Chem.Soc.; 47; 1925; 1149;

Reaction (174 of 229)
Reaction ID5396825
Reactant BRN507540; 1718733; 136380
Reactantnitrobenzene; platinum black; ethanol; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Other ConditionsHydrogenation
CommentHandbook
Citation Pointer1537940; Journal; Adams; Cohen; Rees; JACSAT; J.Amer.Chem.Soc.; 49; 1927; 1095;

Reaction (175 of 229)
Reaction ID5397652
Reactant BRN506007; 1098295; 136380
Reactantacetic acid; tetrachloromethane; thiocyanato; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Other Conditionsim Dunkeln
CommentHandbook
Citation Pointer1136363; Journal; Kaufmann; CHBEAM; Chem.Ber.; 59; 1926; 1391; ARPMAS; Arch.Pharm.(Weinheim Ger.); 1925; 714;

Reaction (176 of 229)
Reaction ID5399138
Reactant BRN3563831; 1696894; 136380
Reactantacetic acid; mercury(II) salt; diethyl ether; sodium chloride; 5-allyl-benzo[1,3]dioxole
Productb-chloromercuri-b-piperonyl-ethanol
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
CommentHandbook
Citation Pointer506391; Journal; Waterman; Priester; RTCPA3; Recl.Trav.Chim.Pays-Bas; 47; 1928; 1033;

Reaction (177 of 229)
Reaction ID5399139
Reactant BRN136380
Reactantaqueous mercury acetate; sodium chloride; 5-allyl-benzo[1,3]dioxole
Productb-chloromercuri-b-piperonyl-ethanol
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Temperature50
CommentHandbook
Citation Pointer500487; Journal; Manchot; JLACBF; Justus Liebigs Ann. Chem.; 421; 1920; 320;

Reaction (178 of 229)
Reaction ID5399140
Reactant BRN3563831; 1696894; 136380
Reactantacetic acid; mercury(II) salt; diethyl ether; sodium chloride; 5-allyl-benzo[1,3]dioxole
Productb-chloromercurimethyl-piperonylcarbinol
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
CommentHandbook
Citation Pointer506391; Journal; Waterman; Priester; RTCPA3; Recl.Trav.Chim.Pays-Bas; 47; 1928; 1033;

Reaction (179 of 229)
Reaction ID5399141
Reactant BRN136380
Reactantaqueous mercury acetate; sodium chloride; 5-allyl-benzo[1,3]dioxole
Productb-chloromercurimethyl-piperonylcarbinol
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Temperature50
CommentHandbook
Citation Pointer500487; Journal; Manchot; JLACBF; Justus Liebigs Ann. Chem.; 421; 1920; 320;

Reaction (180 of 229)
Reaction ID5399657
Reactant BRN1787170; 1098229; 136380
Reactantbromo-trinitro-methane; methanol; 5-allyl-benzo[1,3]dioxole
Productg-bromo-b-methoxy-dihydrosafrole
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
CommentHandbook
Citation Pointer506390; Journal; Schmidt; Bartholome; CHBEAM; Chem.Ber.; 57; 1924; 2040;

Reaction (181 of 229)
Reaction ID5431944
Reactant BRN136380
ReactantRaney nickel; 5-allyl-benzo[1,3]dioxole
Product BRN131188
Product5-propyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour
Temperature15
Pressure58840.6
Other ConditionsHydrogenation
CommentHandbook
Citation Pointer1585208; Journal; Gauthier; ANCPAC; Ann.Chim.(Paris); <11> 20; 1945; 581, 608; COREAF; C.R.Hebd.Seances Acad.Sci.; 217; 1943; 28;

Reaction (182 of 229)
Reaction ID5432373
Reactant BRN506007; 4921393; 136380
Reactantacetic acid; O3; 5-allyl-benzo[1,3]dioxole
Product BRN131691
Productbenzo[1,3]dioxole-5-carbaldehyde
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer500503; Patent; Otto; Verley; DE 97620; FTFVA6; Fortschr.Teerfarbenfabr.Verw.Industriezweige; DE; GE; 4; 1281;

Reaction (183 of 229)
Reaction ID5432383
Reactant BRN2037554; 136380
Reactantpotassium dichromate; sulfuric acid; 5-allyl-benzo[1,3]dioxole
Product BRN131691
Productbenzo[1,3]dioxole-5-carbaldehyde
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer500495; Journal; Power; Lees; JCSOA9; J.Chem.Soc.; 85; 1904; 638;

Reaction (184 of 229)
Reaction ID5436203
Product BRN136380
Product5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation (half reaction)
Citation Pointer3214879; Journal; Feugeas; BSCFAS; Bull.Soc.Chim.Fr.; 1964; 1892;3281959; Journal; Fujita; Yamashita; BCSJA8; Bull.Chem.Soc.Jpn.; 46; 1973; 3553;

Reaction (185 of 229)
Reaction ID5436204
Reactantcamphor redoil
Product BRN136380
Product5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation (half reaction)
CommentHandbook
Citation Pointer500512; Book Review / Secondary Ref.; Knoll,R.; Synthetische und isolierte Riechstoffe <Halle 1908>, S. 63;

Reaction (186 of 229)
Reaction ID5436205
Reactantsassafras oil
Product BRN136380
Product5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation (half reaction)
CommentHandbook
Citation Pointer500512; Book Review / Secondary Ref.; Knoll,R.; Synthetische und isolierte Riechstoffe <Halle 1908>, S. 63;

Reaction (187 of 229)
Reaction ID5446367
Reactant BRN3587158; 136380
Reactanthydrogen bromide; 5-allyl-benzo[1,3]dioxole
Product BRN150196
Product2-benzo[1,3]dioxol-5-yl-1-methyl-ethylamine
No. of Reaction Details1
Reaction ClassificationChemical behaviour
Temperature0
Other ConditionsErhitzen des Reaktionsprodukts mit waessr. Ammoniak auf 120
CommentHandbook
Citation Pointer500347; Patent; Merck; DE 274350; FTFVA6; Fortschr.Teerfarbenfabr.Verw.Industriezweige; DE; GE; 12; 768;

Reaction (188 of 229)
Reaction ID5462328
Reactant BRN1071207; 956581; 635760; 136380
Reactantacetamide; phosphorus oxychloride; methylbenzene; 5-allyl-benzo[1,3]dioxole
Product BRN172577
Product5,7-dimethyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer542450; Journal; Kametani; YKKZAJ; Yakugaku Zasshi; 72; 1952; 1090, 1092; Chem.Abstr.; 1953; 10538;

Reaction (189 of 229)
Reaction ID5462330
Reactant BRN1209252; 956581; 969212; 136380
Reactantacetaldehyde oxime; phosphorus oxychloride; benzene; 5-allyl-benzo[1,3]dioxole
Product BRN172577
Product5,7-dimethyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer781478; Journal; Kametani; YKKZAJ; Yakugaku Zasshi; 73; 1953; 12, 14; Chem.Abstr.; 1953; 10539;

Reaction (190 of 229)
Reaction ID5466659
Reactant BRN635680; 136380
Reactantpotassium permanganate; propan-2-one; 5-allyl-benzo[1,3]dioxole
Product BRN150206; 177740
Productbenzo[1,3]dioxole-5-carboxylic acid; homopiperonylic acid
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer504615; Journal; Luff; Perkin; Robinson; JCSOA9; J.Chem.Soc.; 97; 1910; 1139;

Reaction (191 of 229)
Reaction ID5466661
Reactant BRN136380
Reactantpotassium permanganate; 5-allyl-benzo[1,3]dioxole
Product BRN131691; 150206; 177740
Product12.13-dioxy-3.4-methylene-dioxy-1-propyl-benzene; benzo[1,3]dioxole-5-carbaldehyde; benzo[1,3]dioxole-5-carboxylic acid; homopiperonylic acid
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer500496; Journal; Miller; ARPMAS; Arch.Pharm.(Weinheim Ger.); 240; 1902; 377;500497; Journal; Wagner; Bouschmakin; CHBEAM; Chem.Ber.; 24; 1891; 3489;500498; Journal; Tiemann; CHBEAM; Chem.Ber.; 24; 1891; 2881;1110985; Journal; Wagner; CHBEAM; Chem.Ber.; 21; 1888; 3351;500500; Journal; Poleck; CHBEAM; Chem.Ber.; 19; 1886; 1094; CHBEAM; Chem.Ber.; 22; 1889; 2862;500501; Journal; Eijkman; RTCPA3; Recl.Trav.Chim.Pays-Bas; 4; 1885; 39;

Reaction (192 of 229)
Reaction ID5492834
Reactant BRN136380
Reactantsulfur; 5-allyl-benzo[1,3]dioxole
Product BRN212873
Product5-benzo[1,3]dioxol-5-yl-[1,2]dithiol-3-thione
No. of Reaction Details1
Reaction ClassificationChemical behaviour
Temperature200
CommentHandbook
Citation Pointer512464; Journal; Lozac'h; BSCFAS; Bull.Soc.Chim.Fr.; 1949; 840, 844;

Reaction (193 of 229)
Reaction ID5499567
Reactant BRN136380
Reactantcharcoal; 5-allyl-benzo[1,3]dioxole
Product BRN131188; 2247186; 1305151
Product5-propyl-benzo[1,3]dioxole; 4-propyl-pyrocatechol; 4-methyl-phenol
No. of Reaction Details1
Reaction ClassificationChemical behaviour
Temperature190
CommentHandbook
Citation Pointer1550731; Journal; Kimura; BCSJA8; Bull.Chem.Soc.Jpn.; 10; 1935; 330, 333;

Reaction (194 of 229)
Reaction ID5537056
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole; 4-methoxy-benzimidoyl chloride
Product BRN294781
Product5-(4-methoxy-phenyl)-7-methyl-7,8-dihydro-[1,3]dioxolo[4,5-g]isoquinoline
No. of Reaction Details1
Reaction ClassificationPreparation
CommentHandbook
Citation Pointer781478; Journal; Kametani; YKKZAJ; Yakugaku Zasshi; 73; 1953; 12, 14; Chem.Abstr.; 1953; 10539;

Reaction (195 of 229)
Reaction ID5540444
Reactant BRN3563831; 136380
Reactantacetic acid; mercury(II) salt; 5-allyl-benzo[1,3]dioxole
Product2-benzo<1,3>dioxol-5-yl-1-hydroxymethyl-ethylmercury-acetate
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
CommentHandbook
Citation Pointer500485; Journal; Balbiano; Paolini; Luzzi; AANLAW; Atti Accad.Naz.Lincei Cl.Sci.Fis.Mat.Nat.Rend.; <5> 11 II; 1902; 69; CHBEAM; Chem.Ber.; 35; 1902; 2997;500486; Journal; Balbiano; Paolini; Luzzi; CHBEAM; Chem.Ber.; 36; 1903; 3579; GCITA9; Gazz.Chim.Ital.; 36 I; 1906; 270;500487; Journal; Manchot; JLACBF; Justus Liebigs Ann. Chem.; 421; 1920; 320;500488; Journal; Tsukamoto; Journ. Pharm. Soc. of Japan; 1930; 3;

Reaction (196 of 229)
Reaction ID5543157
Reactant BRN2049534; 1696894; 136380
Reactant4-nitroso-benzoic acid ethyl ester; diethyl ether; 5-allyl-benzo[1,3]dioxole
Product3.4-methylenedioxy-cinnamaldoxim-N-<4-ethoxycarbonyl-phenyl ether >
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Temperature20
Other Conditionsim Dunkeln
CommentHandbook
Citation Pointer506383; Journal; Alessandri; GCITA9; Gazz.Chim.Ital.; 54; 1924; 449;

Reaction (197 of 229)
Reaction ID5558918
Reactant BRN136380
Reactantalcoholic KOH-solution; 5-allyl-benzo[1,3]dioxole
Product BRN3285051
Product2-ethoxymethoxy-4-propenyl-phenol
No. of Reaction Details1
Reaction ClassificationChemical behaviour
Temperature150
Other Conditionsunter Druck
CommentHandbook
Citation Pointer500490; Patent; Pomeranz; DE 122701;

Reaction (198 of 229)
Reaction ID5605307
Reactant BRN136380; 1209228
Reactant5-allyl-benzo[1,3]dioxole; formaldehyde
Product BRN16713
Product4x-benzo<1,3>dioxol-5-yl-but-3-en-1-ol; formic acid-(4x-benzo[1,3]dioxol-5-yl-but-3-enyl ester)
No. of Reaction Details1
Reaction ClassificationPreparation
Temperature220
CommentHandbook
Citation Pointer514831; Journal; Kuraoka; Sugawara; NPKZAZ; Nippon Kagaku Zasshi; 79; 1958; 1161; Chem.Abstr.; 1960; 4479;

Reaction (199 of 229)
Reaction ID5697251
Reactant BRN1696894; 136380
Reactantmixture of gaseous nitrogen oxides; diethyl ether; 5-allyl-benzo[1,3]dioxole
Product BRN72253
Productsafrole-pseudo nitrosite
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer501854; Journal; Anderlini; GCITA9; Gazz.Chim.Ital.; 23 I; 1893; 130;

Reaction (200 of 229)
Reaction ID5697252
Reactant BRN136380
Reactantmixture of gaseous nitrogen oxides; petroleum ether; 5-allyl-benzo[1,3]dioxole
Product BRN72253
Productsafrole-pseudo nitrosite
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer501854; Journal; Anderlini; GCITA9; Gazz.Chim.Ital.; 23 I; 1893; 130;

Reaction (201 of 229)
Reaction ID5697253
Reactant BRN2037554; 136380
Reactantpetroleum ether; sodium nitrite; sulfuric acid; 5-allyl-benzo[1,3]dioxole
Product BRN72253
Productsafrole-pseudo nitrosite
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer501556; Journal; Angeli; Rimini; GCITA9; Gazz.Chim.Ital.; 25 II; 1895; 205;

Reaction (202 of 229)
Reaction ID5699324
Reactant BRN3530350; 136380
Reactant2,3-dimethyl-4-nitroso-aniline; 5-allyl-benzo[1,3]dioxole
Product BRN750281
Product3.4-methylenedioxy-cinnamaldehyde-<4-dimethylamino-anil>; tetra-N-methyl-4,4'-azo-di-aniline
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer508192; Journal; Quilico; Freri; GCITA9; Gazz.Chim.Ital.; 59; 1929; 274, 277;507506; Journal; Quilico; GCITA9; Gazz.Chim.Ital.; 58; 1928; 322;

Reaction (203 of 229)
Reaction ID5706792
Reactant BRN136380
Reactantalcoholic KOH-solution; 5-allyl-benzo[1,3]dioxole
Product BRN82640
Product5-propenyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer501380; Journal; Ciamician; Silber; GCITA9; Gazz.Chim.Ital.; 20; 1890; 571; CHBEAM; Chem.Ber.; 23; 1890; 1160;500454; Journal; Eijkman; CHBEAM; Chem.Ber.; 23; 1890; 862;

Reaction (204 of 229)
Reaction ID5706796
Reactant BRN136380
Reactantpotassium hydroxide; 5-allyl-benzo[1,3]dioxole
Product BRN82640
Product5-propenyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour
Other Conditionsbei der Destillation
CommentHandbook
Citation Pointer500494; Journal; Grimaux; Ruotte; BSCFAS; Bull.Soc.Chim.Fr.; <2> 11; 1869; 465; JLACBF; Justus Liebigs Ann. Chem.; 152; 1869; 91;

Reaction (205 of 229)
Reaction ID5706797
Reactant BRN3623272; 136380
Reactantpotassium hydroxide; formic acid ; potassium formate; 5-allyl-benzo[1,3]dioxole
Product BRN82640
Product5-propenyl-benzo[1,3]dioxole
No. of Reaction Details2
Reaction ClassificationChemical behaviour
Temperature200
Other Conditionsim Druckrohr
CommentHandbook
Citation Pointer500468; Journal; Poleck; CHBEAM; Chem.Ber.; 17; 1884; 1940;

Reaction (206 of 229)
Reaction ID5706798
Reactant BRN136380
Reactantsodium; 5-allyl-benzo[1,3]dioxole
Product BRN82640
Product5-propenyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour
Temperature200
Other Conditionsim Rohr
CommentHandbook
Citation Pointer500454; Journal; Eijkman; CHBEAM; Chem.Ber.; 23; 1890; 862;500471; Journal; Schiff; CHBEAM; Chem.Ber.; 17; 1884; 1937;

Reaction (207 of 229)
Reaction ID5706801
Reactant3,4-methylenedioxy-trans(?)-cinnamyl alcohol
Product BRN82640; 136380
Product5-propenyl-benzo[1,3]dioxole; 5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation (half reaction)
Reagentlithium alanate; Al2O3; diethyl ether
CommentHandbook
Citation Pointer514936; Journal; Birch; Slaytor; CHINAG; Chem.Ind.(London); 1956; 1524;

Reaction (208 of 229)
Reaction ID5729071
Reactant BRN471223; 136380
Reactantbenzaldehyde; 5-allyl-benzo[1,3]dioxole
Productcompound C17H16O3
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Other Conditionsbei Belichtung
CommentHandbook
Citation Pointer500452; Journal; Ciamician; Silber; AANLAW; Atti Accad.Naz.Lincei Cl.Sci.Fis.Mat.Nat.Rend.; <5> 18 I; 1909; 218; CHBEAM; Chem.Ber.; 42; 1909; 1389;

Reaction (209 of 229)
Reaction ID5732276
Reactant BRN136380
Reactantnickel; 5-allyl-benzo[1,3]dioxole
Product BRN1929705
Productdihydrosafrole; 3-Propyl-phenol
No. of Reaction Details1
Reaction ClassificationChemical behaviour
Temperature200
Other ConditionsHydrogenation
CommentHandbook
Citation Pointer500344; Journal; Henrard; CHZEA6; Chem.Zentralbl.; GE; 78; II; 1907; 1512;

Reaction (210 of 229)
Reaction ID5734590
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN177739
Producthomopiperonal; benzo[1,3]dioxol-5-yl-acetic acid
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentbenzene; water
Other Conditionsbei der Ozonisation
CommentHandbook
Citation Pointer500803; Journal; Semmler; Bartelt; CHBEAM; Chem.Ber.; 41; 1908; 2752;500505; Journal; Harries; Adam; CHBEAM; Chem.Ber.; 49; 1916; 1029;

Reaction (211 of 229)
Reaction ID5737451
Reactant BRN136380
Reactantmethanolic KOH-solution; 5-allyl-benzo[1,3]dioxole
Productmethoxymethyl ether of 4-propenyl-pyrocatechol
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Temperature130 - 140
CommentHandbook
Citation Pointer506385; Journal; Wagner; CZCAA5; Chem.-Ztg.Chem.Appar.; 52; 1928; 379; CHZEA6; Chem.Zentralbl.; GE; 99; I; 1928; 3056;506386; Patent; Riedel-de Haen; DE 505404; FTFVA6; Fortschr.Teerfarbenfabr.Verw.Industriezweige; DE; GE; 17; 569, 571;506387; Patent; Riedel-de Haen; DE 507796;506388; Patent; Riedel,J. D.; Boedecker; GB 285156;506389; Patent; Riedel,J. D.; Boedecker; GB 285551;

Reaction (212 of 229)
Reaction ID5740526
Reactant BRN605688; 136380
Reactantnitrosobenzene; 5-allyl-benzo[1,3]dioxole
ProductN-phenyl-3.4-methylenedioxy-cinnamaldehyde isoxime
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Other Conditionsim Dunkeln
CommentHandbook
Citation Pointer504612; Journal; Angeli; Alessandri; Pegna; AANLAW; Atti Accad.Naz.Lincei Cl.Sci.Fis.Mat.Nat.Rend.; <5> 19 I; 1910; 654;

Reaction (213 of 229)
Reaction ID5744856
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN171593
Productsafrole bromohydrin; 5-(2,3-dibromo-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentbromo potassium bromide solution
Temperature20
CommentHandbook
Citation Pointer1540945; Journal; Read; Reid; JCSOA9; J.Chem.Soc.; 1928; 1489;

Reaction (214 of 229)
Reaction ID5744859
Reactant BRN3632802; 506007; 136380
ReactantPyridinium-tribromid; acetic acid; 5-allyl-benzo[1,3]dioxole
Productsafrole dibromide
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Temperature3 - 6
CommentHandbook
Citation Pointer506322; Journal; Rosenmund; Kuhnhenn; CHBEAM; Chem.Ber.; 56; 1923; 1265;

Reaction (215 of 229)
Reaction ID5747248
Reactant BRN136380
ReactantRaney nickel; 5-allyl-benzo[1,3]dioxole
Productcis-4-propyl-cyclohexanol; trans-4-propyl-cyclohexanol
No. of Reaction Details1
Reaction ClassificationChemical behaviour (half reaction)
Temperature150
Pressure58840.6
Other ConditionsHydrogenation
CommentHandbook
Citation Pointer1585208; Journal; Gauthier; ANCPAC; Ann.Chim.(Paris); <11> 20; 1945; 581, 608; COREAF; C.R.Hebd.Seances Acad.Sci.; 217; 1943; 28;

Reaction (216 of 229)
Reaction ID6217465
Reactant BRN136380; 605688
Reactant5-allyl-benzo[1,3]dioxole; nitrosobenzene
Product BRN743984
ProductN-phenyl-<3.4-methylene-dioxy-cinnamaldehyde >-isooxime; diphenyldiazene N-oxide
No. of Reaction Details1
Reaction ClassificationChemical behaviour
Other Conditionsim Dunkeln; reagiert analog mit Eugenolaethylaether
CommentHandbook
Citation Pointer504612; Journal; Angeli; Alessandri; Pegna; AANLAW; Atti Accad.Naz.Lincei Cl.Sci.Fis.Mat.Nat.Rend.; <5> 19 I; 1910; 654;

Reaction (217 of 229)
Reaction ID7155062
Reactant BRN1696892; 635680; 1937030
Reactantdiiodomethane; propan-2-one; potassium carbonate; 4-allyl-pyrocatechol
Product BRN136380
Product5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer506403; Journal; Perkin; Trikojus; JCSOA9; J.Chem.Soc.; 1927; 1665;

Reaction (218 of 229)
Reaction ID7449654
Reactant BRN136380; 1696894; 2049534
Reactant5-allyl-benzo[1,3]dioxole; diethyl ether; 4-nitroso-benzoic acid ethyl ester
Product BRN964085
Product3.4-methylenedioxy-cinnamaldoxim-N-<4-ethoxycarbonyl-phenyl ether >; 4,4'-azoxy-di-benzoic acid diethyl ester
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer506383; Journal; Alessandri; GCITA9; Gazz.Chim.Ital.; 54; 1924; 449;

Reaction (219 of 229)
Reaction ID7977299
Reactant BRN5789338; 3921384
Reactantzinc; Pyridinsalz des Oxymaleinsaeureanhydrids; 2-benzo[1,3]dioxol-5-yl-1-hydroxymethyl-ethylmercury (1+); chloride
Product BRN136380
Product5-allyl-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationChemical behaviour
CommentHandbook
Citation Pointer503869; Journal; Paolini; Luzzi; Balbiano; GCITA9; Gazz.Chim.Ital.; 36 I; 1906; 273; CHBEAM; Chem.Ber.; 36; 1903; 3579;503873; Journal; Paolini; Luzzi; Balbiano; GCITA9; Gazz.Chim.Ital.; 36 I; 1906; 272; CHBEAM; Chem.Ber.; 36; 1903; 3579;

Reaction (220 of 229)
Reaction ID8099999
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN3203395
Product2-methoxymethoxy-4-trans-propenyl-phenol; isosafrole; 2-Methoxymethoxy-5-trans-propenyl-phenol
No. of Reaction Details6
Reaction ClassificationPreparation
Reagentmethanol. NaOH
Temperature200 - 210
CommentHandbook
Citation Pointer1587245; Journal; Ono; Imoto; BCSJA8; Bull.Chem.Soc.Jpn.; 10; 1935; 323, 327, 328;

Reaction (221 of 229)
Reaction ID8260946
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole
Product BRN3201978
Product6-methoxymethoxy-3-trans-propenyl-phenol; isosafrole; 2-Methoxymethoxy-4-trans-propenyl-phenol
No. of Reaction Details6
Reaction ClassificationPreparation
Reagentmethanol. NaOH
Temperature130 - 150
CommentHandbook
Citation Pointer1587061; Patent; Boedecker; US 1812132; 1926;1587234; Patent; Riedel-de Haen; DE 505404; 1925; FTFVA6; Fortschr.Teerfarbenfabr.Verw.Industriezweige; DE; GE; 17; 569, 18 3083;1587235; Patent; Riedel-de Haen; DE 555407; 1926;

Reaction (222 of 229)
Reaction ID8422871
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole; mercury (II)-chloride-solution
Product BRN4926219
Product3-benzo[1,3]dioxol-5-yl-2-hydroxy-propylmercury (1+); chloride
No. of Reaction Details1
Reaction ClassificationPreparation
Reagentpotassium hydroxide
CommentHandbook
Citation Pointer514787; Journal; Tsukamoto; YKKZAJ; Yakugaku Zasshi; 50; 1930; 7, 16, dtsch. Ref. S. 2, 4; Chem.Abstr.; 1930; 1853;

Reaction (223 of 229)
Reaction ID8475777
Reactant BRN136380
Reactant5-allyl-benzo[1,3]dioxole; concentrated mercuri acetate solution
Product BRN6112856
Product2-benzo[1,3]dioxol-5-yl-1-hydroxymethyl-ethylmercury (1+); acetate
No. of Reaction Details1
Reaction ClassificationPreparation
CommentHandbook
Citation Pointer503869; Journal; Paolini; Luzzi; Balbiano; GCITA9; Gazz.Chim.Ital.; 36 I; 1906; 273; CHBEAM; Chem.Ber.; 36; 1903; 3579;503870; Journal; Balbiano; Paolini; AANLAW; Atti Accad.Naz.Lincei Cl.Sci.Fis.Mat.Nat.Rend.; <5> 11 II; 1902; 69; CHBEAM; Chem.Ber.; 35; 1902; 2998;503873; Journal; Paolini; Luzzi; Balbiano; GCITA9; Gazz.Chim.Ital.; 36 I; 1906; 272; CHBEAM; Chem.Ber.; 36; 1903; 3579;

Reaction (224 of 229)
Reaction ID8549727
Reactant BRN136380; 2072908
Reactant5-allyl-benzo[1,3]dioxole; 1-Trimethylsilyl-3-methoxy-1-propin
Product BRN8566326
Product(5-benzo[1,3]dioxol-5-yl-2-methoxymethyl-penta-1,4-dienyl)-trimethyl-silane
No. of Reaction Details1
Reaction ClassificationPreparation
Yield83 percent (BRN=8566326)
CatalystCpRu(NCCH3)3+*PF6-
Solventacetone
Time2 hour(s)
Temperature20
Reaction Typecoupling
Citation Pointer6238050; Journal; Trost, Barry M.; Machacek, Michelle; Schnaderbeck, Matthew J.; ORLEF7; Org.Lett.; EN; 2; 12; 2000; 1761 - 1764;

Reaction (225 of 229)
Reaction ID8672259
Reactant BRN136380; 6149232
Reactant5-allyl-benzo[1,3]dioxole; [N-(p-nitrobenzenesulfonyl)imino]phenyliodinane
Product BRN8711894
Product2-benzo[1,3]dioxol-5-ylmethyl-1-(4-nitro-benzenesulfonyl)-aziridine
No. of Reaction Details1
Reaction ClassificationPreparation
ReagentCuOTf; 4 Angstroem sieves
Solventacetonitrile
Temperature0
Reaction TypeCycloaddition
Citation Pointer6267558; Journal; Dauban, Philippe; Ferry, Sandrine; Faure, Helene; Ruat, Martial; Dodd, Robert H.; BMCLE8; Bioorg.Med.Chem.Lett.; EN; 10; 17; 2000; 2001 - 2004;

Reaction (226 of 229)
Reaction ID8806397
Reactant BRN3599375; 136380
ReactantN-chloro-toluene-4-sulfonamide; sodium salt; 5-allyl-benzo[1,3]dioxole
Product BRN8852751
Product2-benzo[1,3]dioxol-5-ylmethyl-1-(toluene-4-sulfonyl)-aziridine
No. of Reaction Details1
Reaction ClassificationPreparation
Yield45 percent (BRN=8852751)
ReagentAgNO3
Solventtetrahydrofuran
Temperature20
Citation Pointer6292246; Journal; Kumar, K. Ajay; Rai, K. M. Lokanatha; Umesha, K. B.; TETRAB; Tetrahedron; EN; 57; 32; 2001; 6993 - 6996;

Reaction (227 of 229)
Reaction ID8934885
Reactant BRN136380; 1098229
Reactant5-allyl-benzo[1,3]dioxole; methanol
Product BRN8976056; 155814
Product5-(2-methoxy-propyl)-benzo[1,3]dioxole; 5-(3-methoxy-propyl)-benzo[1,3]dioxole
No. of Reaction Details1
Reaction ClassificationMultistage
Yield91 percent (BRN=8976056)
No. of Stages2
Stage 1
Stage 2
ReagentHg(OAc)2; Na
Solventmethanol
Temperature0; 0
Citation Pointer6320927; Journal; Kaur, Navdeep; Dhillon, Ranjit S.; IJSBDB; Indian J.Chem.Sect.B; EN; 40; 4; 2001; 327 - 328;

Reaction (228 of 229)
Reaction ID8997099
Reactant BRN7132008; 136380
ReactantN-(3-butynyl)-4-methyl-benzenesulfonamide; 5-allyl-benzo[1,3]dioxole
Product BRN9056838; 9058285
Product7-benzo[1,3]dioxol-5-yl-hepta-3,6-dien-1-ol; 6-benzo[1,3]dioxol-5-yl-3-methylene-hex-5-en-1-ol
No. of Reaction Details1
Reaction ClassificationPreparation
CatalystCpRu(CH3CN)PF6
Solventacetone
Temperature20
CommentTitle compound not separated from byproducts
Citation Pointer6336361; Journal; Trost, Barry M.; Pinkerton, Anthony B.; Toste, F. Dean; Sperrle, Martin; JACSAT; J.Amer.Chem.Soc.; EN; 123; 50; 2001; 12504 - 12509;

Reaction (229 of 229)
Reaction ID8997100
Reactant BRN773710; 136380
Reactantbut-3-yn-1-ol; 5-allyl-benzo[1,3]dioxole
Product BRN9058285; 9056838
Product6-benzo[1,3]dioxol-5-yl-3-methylene-hex-5-en-1-ol; 7-benzo[1,3]dioxol-5-yl-hepta-3,6-dien-1-ol
No. of Reaction Details1
Reaction ClassificationPreparation
CatalystCpRu(CH3CN)3PF6
Solventdimethylformamide
Temperature20
CommentTitle compound not separated from byproducts
Citation Pointer6336361; Journal; Trost, Barry M.; Pinkerton, Anthony B.; Toste, F. Dean; Sperrle, Martin; JACSAT; J.Amer.Chem.Soc.; EN; 123; 50; 2001; 12504 - 12509;

Isolation from Natural Product (1 of 51)
Isolation from Natural Productradix of Asiasarum heterotropoides var. mandshuricum (China)
Citation Pointer6188762; Journal; Takasaki, Midori; Konoshima, Takao; Yasuda, Ichiro; Hamano, Tomoko; Tokuda, Harukuni; BPBLEO; Biol.Pharm.Bull.; EN; 20; 7; 1997; 776 - 780;

Isolation from Natural Product (2 of 51)
Isolation from Natural ProductOcotea pretiosa
Citation Pointer6159391; Journal; Araujo-Junior, Joao X. de; Barreiro, Eliezer J.; Parente, Jose P.; Fraga, Carlos A. M.; SYNCAV; Synth.Commun.; EN; 29; 2; 1999; 263 - 274;

Isolation from Natural Product (3 of 51)
Isolation from Natural Productleaves of Piper aduncum
Citation Pointer6124808; Journal; Parmar, Virinder S.; Jain, Subhash C.; Gupta, Sangita; Talwar, Sangeeta; Rajwanshi, Vivek K.; et al.; PYTCAS; Phytochemistry; EN; 49; 4; 1998; 1069-1078;

Isolation from Natural Product (4 of 51)
Isolation from Natural ProductPiper aduncum
Citation Pointer6080863; Journal; Parmar, Virinder S.; Jain, Subhash C.; Bisht, Kirpal S.; Jain, Pajni; Taneja, Poonam; et al.; PYTCAS; Phytochemistry; EN; 46; 4; 1997; 597-674;

Isolation from Natural Product (5 of 51)
Isolation from Natural ProductIllicium dunnianum by extraction with CH2Cl2 in Soxhlet apparatus for 8 h, removal of solvent and chromatograophy
Citation Pointer6055384; Journal; Sy, Lai-King; Saunders, Richard M. K.; Brown, Geoffrey D.; PYTCAS; Phytochemistry; EN; 44; 6; 1997; 1099-1108;

Isolation from Natural Product (6 of 51)
Isolation from Natural ProductPiper auritum
Citation Pointer5884642; Journal; Nair, Muraleedharan G.; Sommerville, John; Burke, Basil A.; PYTCAS; Phytochemistry; EN; 28; 2; 1989; 654-655;

Isolation from Natural Product (7 of 51)
Isolation from Natural Productlhe petrol extract of the leaves of Drimys winteri
Citation Pointer5818808; Journal; Sierra, Jorge R.; Lopez, Jose T.; Cortes, Manuel J.; PYTCAS; Phytochemistry; EN; 25; 1; 1986; 253-254;

Isolation from Natural Product (8 of 51)
Isolation from Natural ProductClausena excavata
Citation Pointer5718667; Journal; Wu, Tian-Shung; Huang, Shiow-Chyn; Lai, Jeng-Shiow; Teng, Che-Ming; Ko, Feng-Nien; Kuoh, Chang-Sheng; PYTCAS; Phytochemistry; EN; 32; 2; 1993; 449-452;

Isolation from Natural Product (9 of 51)
Isolation from Natural Productleaves of Illicum tashiroi MAXIM., collected on Iriomote Island (Japan)
Citation Pointer5668828; Journal; Yakushijin, Kenichi; Tohshima, Tomoko; Suzuki, Rika; Murata, Hiroyuki; Lu, Sheng-Ten; Furukawa, Hiroshi; CPBTAL; Chem.Pharm.Bull.; EN; 31; 8; 1983; 2879-2883;

Isolation from Natural Product (10 of 51)
Isolation from Natural Productaus Anethum sowa KURZ
Citation Pointer3339630; Journal; Baslas; Baslas; RSARAQ; Riechst.Aromen; 22; 1972; 200,202;

Isolation from Natural Product (11 of 51)
Isolation from Natural Productaus Anethum graveolens
Citation Pointer4298940; Journal; Baslas; Baslas; RSARAQ; Riechst.Aromen; 22; 1972; 155,156,158;

Isolation from Natural Product (12 of 51)
Isolation from Natural Productaus Eugenia bracteata Roxb.
Citation Pointer3615219; Journal; Narasimha; Nigam; RSARAQ; Riechst.Aromen; 22; 1972; 231,236;

Isolation from Natural Product (13 of 51)
Isolation from Natural Productaus Pogostemon plectranthoides (Desf.)
Citation Pointer3737643; Journal; Nigam; Ramaiah; RSARAQ; Riechst.Aromen; 22; 1972; 378,388;

Isolation from Natural Product (14 of 51)
Isolation from Natural Productaus aether. Oel v. Saccopetalum tomentosum
Citation Pointer3339628; Journal; Ramaiah; Nigam; RSARAQ; Riechst.Aromen; 22; 1972; 71,74;

Isolation from Natural Product (15 of 51)
Isolation from Natural Productaus Acorus gramineus
Citation Pointer3958347; Journal; Fujita et al.; YKKZAJ; Yakugaku Zasshi; 90; 1970; 1367,1371; Chem.Abstr.; 74; 34553; 1971;

Isolation from Natural Product (16 of 51)
Isolation from Natural Productaus d. Blaettern v. Hamamelis virginiana L.
Citation Pointer3614964; Journal; Messerschmidt; ARZNAD; Arzneim.Forsch.; 18; 1968; 1618;

Isolation from Natural Product (17 of 51)
Isolation from Natural Productaus Magnolia salicifolia
Citation Pointer3614687; Journal; Fujita; Fujita; CPBTAL; Chem.Pharm.Bull.; 20; 1972; 2251;

Isolation from Natural Product (18 of 51)
Isolation from Natural ProductSchinus weinmanniae folius
Citation Pointer3181171; Journal; Fester et al.; RFIQA6; Rev.Fac.Ing.Quim.Univ.Nac.Litoral; 28; 1959; 9; Chem.Abstr.; 55; 10809; 1961;

Isolation from Natural Product (19 of 51)
Isolation from Natural Product........... Oil aus Myristica fraga.s
Citation Pointer3271861; Journal; Bejnarowicz; Kirch; JPMSAE; J.Pharm.Sci.; 52; 1963; 988;

Isolation from Natural Product (20 of 51)
Isolation from Natural Productaether. Oel aus Ocimum basilicum
Citation Pointer3831982; Journal; Hoerhammer et al.; JPMSAE; J.Pharm.Sci.; 53; 1964; 1033; Chem.Abstr.; 305; 1962;

Isolation from Natural Product (21 of 51)
Isolation from Natural ProductPetersiliensamenoel
Citation Pointer3219839; Journal; Dallacker et al.; MOCMB7; Monatsh.Chem.; 91; 1960; 1089,1096;

Isolation from Natural Product (22 of 51)
Isolation from Natural Productaetherisches Oel von Eremopleila Longifolia F.Muell.
Citation Pointer3271836; Journal; Della; Jefferies; AJCHAS; Aust.J.Chem.; 14; 1961; 663;

Isolation from Natural Product (23 of 51)
Isolation from Natural ProductBananenaromastoff, Gaschromat. Nachweis
Citation Pointer301089; Journal; Tressl,R. et al.; ZENBAX; Z.Naturforsch.B Anorg.Chem.Org.Chem.Biochem.Biophys.Biol.; GE; 24; 1969; 781-783;

Isolation from Natural Product (24 of 51)
Isolation from Natural Productim Wurzelholz und in der Wurzelrinde von Sassafras officinalis Nees (Sassafraswurzeloel)
CommentHandbook
Citation Pointer500521; Journal; Power; Kleber; CHZEA6; Chem.Zentralbl.; GE; 68; II; 1897; 42;500511; Journal; Flueckiger; ANPYA2; Ann.Phys.(Leipzig); 158; 1876; 248;500494; Journal; Grimaux; Ruotte; BSCFAS; Bull.Soc.Chim.Fr.; <2> 11; 1869; 465; JLACBF; Justus Liebigs Ann. Chem.; 152; 1869; 91;500524; Journal; Saint-Evre; ANCPAC; Ann.Chim.(Paris); <3> 12; 1844; 107; JLACBF; Justus Liebigs Ann. Chem.; 52; 1844; 397;500525; Book Review / Secondary Ref.; Binder; Buchners Repertorium fuer die Pharmacie 11 <1821>, 346;

Isolation from Natural Product (25 of 51)
Isolation from Natural Productals Hauptbestandteil des aether. Oels der Wurzel und des Wurzelstocks von Asarum arifolium
CommentHandbook
Citation Pointer500496; Journal; Miller; ARPMAS; Arch.Pharm.(Weinheim Ger.); 240; 1902; 377;

Isolation from Natural Product (26 of 51)
Isolation from Natural Productim Oel aus den Blaettern und den gruenen Fruechten von Illicium religiosum (Japanisches Sternanisoel)
CommentHandbook
Citation Pointer500501; Journal; Eijkman; RTCPA3; Recl.Trav.Chim.Pays-Bas; 4; 1885; 39;1518772; Journal; Tardy; BSCFAS; Bull.Soc.Chim.Fr.; <3> 27; 1902; 995;

Isolation from Natural Product (27 of 51)
Isolation from Natural Productim aether. Oel aus der Wurzelrinde von Cinnamomum ceylanicum
CommentHandbook
Citation Pointer500518; Journal; Pilgrim; CHZEA6; Chem.Zentralbl.; GE; 80; I; 1909; 534;

Isolation from Natural Product (28 of 51)
Isolation from Natural Productim Campheroel (Cinnamomum Camphora)
CommentHandbook
Citation Pointer500517; Book Review / Secondary Ref.; Schimmel & Co.; Bericht vom September 1885, 7;

Isolation from Natural Product (29 of 51)
Isolation from Natural Productim aether. Rindenoel von Cinnamomum pedatinervium
CommentHandbook
Citation Pointer500516; Journal; Goulding; JCSOA9; J.Chem.Soc.; 83; 1903; 1099;

Isolation from Natural Product (30 of 51)
Isolation from Natural Productim Massoirindenoel (Cinnamomum, Spezies unsicher)
CommentHandbook
Citation Pointer500368; Journal; Woy; ARPMAS; Arch.Pharm.(Weinheim Ger.); 228; 1890; 40;

Isolation from Natural Product (31 of 51)
Isolation from Natural Productim aether. Muskatnussoel (Ol. Nucis moschatae)
CommentHandbook
Citation Pointer1297408; Journal; Power; Salway; JCSOA9; J.Chem.Soc.; 91; 1907; 2045,2049;

Isolation from Natural Product (32 of 51)
Isolation from Natural ProductVorkommen von Safrol in weiteren aetherischen Oelen
CommentHandbook
Citation Pointer500513; Book Review / Secondary Ref.; Semmler; Die aetherischen Oele, Bd. IV <Leipzig 1907>, S. 144ff;

Isolation from Natural Product (33 of 51)
Isolation from Natural Productim californischen Lorbeerblaetteroel (von Umbellularia californica)
CommentHandbook
Citation Pointer500495; Journal; Power; Lees; JCSOA9; J.Chem.Soc.; 85; 1904; 638;

Isolation from Natural Product (34 of 51)
Isolation from Natural ProductVorkommen im Oel der Fruechte von Illicium verum (Sternanisoel)
CommentHandbook
Citation Pointer504621; Journal; Schimmel & Co.; CHZEA6; Chem.Zentralbl.; GE; 81; I; 1910; 1719;

Isolation from Natural Product (35 of 51)
Isolation from Natural ProductIm aether. Oel der Blaetter von Atherosperma moschatum Labill.
CommentHandbook
Citation Pointer504620; Journal; Scott; JCSOA9; J.Chem.Soc.; 101; 1912; 1613;

Isolation from Natural Product (36 of 51)
Isolation from Natural ProductIm aether. Oel des Holzes von Cinnamomum glanduliferum Meissn.
CommentHandbook
Citation Pointer504619; Journal; Pickles; JCSOA9; J.Chem.Soc.; 101; 1912; 1437;

Isolation from Natural Product (37 of 51)
Isolation from Natural ProductIm aether. Oel der Rinde von Cinnamomum Oliveri Bail.
CommentHandbook
Citation Pointer504618; Journal; Hargreaves; JCSOA9; J.Chem.Soc.; 109; 1916; 751;

Isolation from Natural Product (38 of 51)
Isolation from Natural ProductSafrol ist der Hauptbestandteil des Oeles aus dem Holz von Cinnamomum Parthenoxylon Meissn.
CommentHandbook
Citation Pointer504617; Journal; Schimmel & Co.; CHZEA6; Chem.Zentralbl.; GE; 82; I; 1911; 1837;

Isolation from Natural Product (39 of 51)
Isolation from Natural Productim aether. Oel aus den Blaettern von Doryphora Sassafras
CommentHandbook
Citation Pointer506411; Journal; Penfold; PEORAA; Perfum.Essent.Oil Rec.; 13; 273; CHZEA6; Chem.Zentralbl.; GE; 93; IV; 1922; 673;

Isolation from Natural Product (40 of 51)
Isolation from Natural Productim Pichurimbohnen-Oel
CommentHandbook
Citation Pointer506410; Journal; Roure-Bertrand fils; CHZEA6; Chem.Zentralbl.; GE; 93; I; 1922; 360;

Isolation from Natural Product (41 of 51)
Isolation from Natural Productbildet den Hauptbestandteil der aether. Oele aus der Rinde und den Blaettern von Laurelia serrata Bert.
CommentHandbook
Citation Pointer506408; Journal; Fester; Salgado; ANCEAD; Angew.Chem.; 42; 1929; 988;506409; Book Review / Secondary Ref.; Schimmel & Co.; Ber. Schimmel 1927, 61; C. 1927 II, 1518;

Isolation from Natural Product (42 of 51)
Isolation from Natural ProductVorkommen in verschiedenen japanischen aetherischen Oelen
CommentHandbook
Citation Pointer506407; Journal; Anonymus; CHZEA6; Chem.Zentralbl.; GE; 91; III; 1920; 597;

Isolation from Natural Product (43 of 51)
Isolation from Natural Productaus dem aetherischen Oel der Wurzeln von Asarum sieboldii
CommentHandbook
Citation Pointer542486; Journal; Kaku; Kondo; YKKZAJ; Yakugaku Zasshi; 51; 1931; 8, 16; dtsch. Ref. S. 3, 6; Chem.Abstr.; 1931; 1948;

Isolation from Natural Product (44 of 51)
Isolation from Natural Productaus dem aetherischen Oel der Blaetter von Boronia pinnata
CommentHandbook
Citation Pointer542485; Journal; Penfold; JPRSA5; J.Proc.R.Soc.N.S.W.; 62; 1928; 225, 230;

Isolation from Natural Product (45 of 51)
Isolation from Natural Productaus dem aetherischen Oel der Blaetter von Cinnamomum camphora
CommentHandbook
Citation Pointer1365400; Journal; Naito; NKAKB8; Nippon Kagaku Kaishi; 64; 1943; 1125; Chem.Abstr.; 1947; 3776;542484; Journal; Fujita; NKAKB8; Nippon Kagaku Kaishi; 63; 1942; 58, 62; Chem.Abstr.; 1947; 3509;

Isolation from Natural Product (46 of 51)
Isolation from Natural Productaus dem aetherischen Oel der Blaetter von Cinnamomum micranthum
CommentHandbook
Citation Pointer542482; Journal; Fujita; Tamashita; NKAKB8; Nippon Kagaku Kaishi; 65; 1944; 385, 388, 591; Chem.Abstr.; 1947; 3509;

Isolation from Natural Product (47 of 51)
Isolation from Natural Productaus dem aetherischen Oel der Blaetter von Illicium parviflorum
CommentHandbook
Citation Pointer542481; Journal; Foote; JPHAA3; J.Am.Pharm.Assoc.; 27; 1938; 573;

Isolation from Natural Product (48 of 51)
Isolation from Natural Productaus dem aetherischen Oel der Wurzeln von Ligusticum acutilobum
CommentHandbook
Citation Pointer592320; Journal; Noguchi; Kawanami; YKKZAJ; Yakugaku Zasshi; 57; 1937; 783, 788; dtsch. Ref. S. 196, 199; CHZEA6; Chem.Zentralbl.; GE; 108; II; 1937; 4050;512471; Journal; Noguchi et al.; YKKZAJ; Yakugaku Zasshi; 57; 1937; 769, 773; dtsch. Ref. S. 187; Chem.Abstr.; 1938; 3360;

Isolation from Natural Product (49 of 51)
Isolation from Natural Productaus dem aetherischen Oel der Rinde von Nemuaron humboldtii
CommentHandbook
Citation Pointer542478; Journal; Chabeau; Bl. Acad. Med. Belgique; <6> 3; 1938; 46, 52;

Isolation from Natural Product (50 of 51)
Isolation from Natural Productaus dem aetherischen Oel des Holzes von Ocotea pretiosa
CommentHandbook
Citation Pointer542448; Journal; Hickey; JOCEAH; J.Org.Chem.; 13; 1948; 443, 445;542477; Journal; Raoul; Jachan; Rev. Quim. ind.; 19; 1950; 12, 13;

Isolation from Natural Product (51 of 51)
Isolation from Natural Productaus dem aetherischen Oel des Holzes von Sassafras albidum
CommentHandbook
Citation Pointer542448; Journal; Hickey; JOCEAH; J.Org.Chem.; 13; 1948; 443, 445;

Derivative (1 of 4)
CommentPentabromid: F: 169.5
Citation Pointer3339630; Journal; Baslas; Baslas; RSARAQ; Riechst.Aromen; 22; 1972; 200,202;

Derivative (2 of 4)
CommentPentabromid: F: 169.5grad
Citation Pointer4298940; Journal; Baslas; Baslas; RSARAQ; Riechst.Aromen; 22; 1972; 155,156,158;

Derivative (3 of 4)
CommentBromderiv.: F: 169grad
Citation Pointer3737643; Journal; Nigam; Ramaiah; RSARAQ; Riechst.Aromen; 22; 1972; 378,388;

Derivative (4 of 4)
CommentMischungen m. Terpineol: D
Citation Pointer3615042; Journal; Koul; Nigam; RSARAQ; Riechst.Aromen; 17; 1967; 269,270;

Related Structure (1 of 1)
Related StructureZusammenfassende Darstellungen.
CommentHandbook
Citation Pointer542487; Book Review / Secondary Ref.; Guenther,E.; The Essential Oils, Bd. 2 <New York 1949> S. 526;542488; Book Review / Secondary Ref.; Gildemeister,E.; Hoffmann,F.; Die aetherischen Oele, 4. Aufl., Bd. 3d <Berlin 1966> S. 449;

Purification (1 of 2)
Purification (method)separation with silica gel or dilute H2SO4 in CHCl3
Citation Pointer5682747; Journal; Yakushijin, Kenichi; Tohshima, Tomoko; Kitagawa, Eiji; Suzuki, Rika; Sekikawa, Junko; et al.; CPBTAL; Chem.Pharm.Bull.; EN; 32; 1; 1984; 11-22;

Purification (2 of 2)
Citation Pointer3271838; Journal; Stahl; Trennheuser; APBDAJ; Arch.Pharm.Ber.Dtsch.Pharm.Ges.; 293; 1960; 826,831;4660380; Journal; Furukawa; NPKZAZ; Nippon Kagaku Zasshi; 80; 1959; 387,388, 389; Chem.Abstr.; 13938; 1960;

Crossfile Reference (1 of 9)
External Access ID94-59-7
Citation Pointer6222371; Journal; Brooks, Paige R.; Wirtz, Michael C.; Vetelino, Michael G.; Rescek, Diane M.; Woodworth, Graeme F.; Morgan, Bradley P.; Coe, Jotham W.; JOCEAH; J.Org.Chem.; EN; 64; 26; 1999; 9719 - 9721;

Crossfile Reference (2 of 9)
Data Type13C-NMR Spectrum
Name4-ALLYL-1,2-(METHYLENEDIOXY)BENZENE
Crossfile SourceSpecInfo Database
External Access IDSTCC-80886-665E
Citation Pointer2374766; Book Review / Secondary Ref.; SADTLER STANDARD CARBON-13 NMR SPECTRA;2375283; Book Review / Secondary Ref.; Formacek,V.; PHD-THESIS,WUERZBURG(1979);2366095; Book Review / Secondary Ref.; BRUKER 13-C DATA BANK VOL.1;

Crossfile Reference (3 of 9)
Name1-Allyl-3,4-methylenedioxybenzene; for synthesis
Crossfile SourceE.Merck, Darmstadt
External Access ID807675

Crossfile Reference (4 of 9)
NameSAFROLE, 97 PERCENT
Crossfile SourceAldrich
External Access IDS208

Crossfile Reference (5 of 9)
NameSafrole, purum ca.98 percent (GC)
Crossfile SourceFluka
External Access ID84130

Crossfile Reference (6 of 9)
Name5-allyl-1,3-benzodioxole
Crossfile SourceEINECS
External Access ID202-345-4

Crossfile Reference (7 of 9)
Name1,3-Benzodioxole, 5-(2-propenyl)-
Crossfile SourceCRC Handbook of Chemistry and Physics
External Access ID5738

Crossfile Reference (8 of 9)
Data Type13C-NMR Spectrum
Crossfile SourceCSEARCH
External Access IDSADT-959

Crossfile Reference (9 of 9)
Name Benzene, 4-allyl-1,2-(methylenedioxy)-
Crossfile SourceRTECS
External Access IDCY2800000

Melting Point (1 of 4)
Melting Point11.2
CommentHandbook
Citation Pointer500471; Journal; Schiff; CHBEAM; Chem.Ber.; 17; 1884; 1937;500507; Journal; Schimmel & Co.; CHZEA6; Chem.Zentralbl.; GE; 73; I; 1902; 1060;500511; Journal; Flueckiger; ANPYA2; Ann.Phys.(Leipzig); 158; 1876; 248;

Melting Point (2 of 4)
Melting Point11
CommentHandbook
Citation Pointer506400; Journal; Sanderson; Jones; JSCIAN; J.Soc.Chem.Ind.London; 42; 1923; 1 T;509494; Journal; Waterman; Priester; RTCPA3; Recl.Trav.Chim.Pays-Bas; 47; 1928; 849 Anm. 3; 1033;

Melting Point (3 of 4)
Melting Point11
Solventpetroleum ether
CommentHandbook
Citation Pointer542466; Journal; Hillmer; Schorning; ZPCAAI; Z.Phys.Chem.Abt.A; 167; 1934; 407, 415;

Melting Point (4 of 4)
Melting Point11
CommentHandbook
Citation Pointer512137; Journal; Naves; Ardizio; BSCFAS; Bull.Soc.Chim.Fr.; 1957; 1053, 1056;542473; Journal; Priester; RTCPA3; Recl.Trav.Chim.Pays-Bas; 57; 1938; 811, 813;

Boiling Point (1 of 18)
Boiling Point62 - 63
Pressure0.2
Citation Pointer3214879; Journal; Feugeas; BSCFAS; Bull.Soc.Chim.Fr.; 1964; 1892;

Boiling Point (2 of 18)
Boiling Point231 - 233
CommentHandbook
Citation Pointer500494; Journal; Grimaux; Ruotte; BSCFAS; Bull.Soc.Chim.Fr.; <2> 11; 1869; 465; JLACBF; Justus Liebigs Ann. Chem.; 152; 1869; 91;

Boiling Point (3 of 18)
Boiling Point232 - 233
CommentHandbook
Citation Pointer500368; Journal; Woy; ARPMAS; Arch.Pharm.(Weinheim Ger.); 228; 1890; 40;

Boiling Point (4 of 18)
Boiling Point234.5
Pressure760
CommentHandbook
Citation Pointer500510; Book Review / Secondary Ref.; v. Rechenberg,C.; Einfache und fraktionierte Destillation, 2. Aufl. <Miltitz 1923>, S. 261;

Boiling Point (5 of 18)
Boiling Point234.5
Pressure760
CommentHandbook
Citation Pointer1540276; Journal; Brauer bei v. Rechenberg; JPCEAO; J.Prakt.Chem.; <2> 101; 1921; 118;

Boiling Point (6 of 18)
Boiling Point235.9
Pressure760
CommentHandbook
Citation Pointer506363; Journal; Lecat,M.; RTCPA3; Recl.Trav.Chim.Pays-Bas; 47; 1928; 15, 16; Ann. Soc. scient. Bruxelles; 47 I; 1927; 154;

Boiling Point (7 of 18)
Boiling Point162.2
Pressure100
CommentHandbook
Citation Pointer500510; Book Review / Secondary Ref.; v. Rechenberg,C.; Einfache und fraktionierte Destillation, 2. Aufl. <Miltitz 1923>, S. 261;

Boiling Point (8 of 18)
Boiling Point114 - 115
Pressure15
CommentHandbook
Citation Pointer506360; Journal; Kern; Shriner; Adams; JACSAT; J.Amer.Chem.Soc.; 47; 1925; 1149;

Boiling Point (9 of 18)
Boiling Point112.81
Pressure14
CommentHandbook
Citation Pointer1540276; Journal; Brauer bei v. Rechenberg; JPCEAO; J.Prakt.Chem.; <2> 101; 1921; 118;

Boiling Point (10 of 18)
Boiling Point104
Pressure11
CommentHandbook
Citation Pointer500368; Journal; Woy; ARPMAS; Arch.Pharm.(Weinheim Ger.); 228; 1890; 40;

Boiling Point (11 of 18)
Boiling Point106.4
Pressure10
CommentHandbook
Citation Pointer500510; Book Review / Secondary Ref.; v. Rechenberg,C.; Einfache und fraktionierte Destillation, 2. Aufl. <Miltitz 1923>, S. 261;

Boiling Point (12 of 18)
Boiling Point104 - 105
Pressure6
Citation Pointer3215042; Journal; Bochwic; Kapuscinski; ROCHAC; Rocz.Chem.; 39; 1965; 1251,1255; Chem.Abstr.; 64; 12656;

Boiling Point (13 of 18)
Boiling Point93 - 93.2
Pressure5
Citation Pointer4298940; Journal; Baslas; Baslas; RSARAQ; Riechst.Aromen; 22; 1972; 155,156,158;

Boiling Point (14 of 18)
Boiling Point94 - 94.5
Pressure4
Citation Pointer3281959; Journal; Fujita; Yamashita; BCSJA8; Bull.Chem.Soc.Jpn.; 46; 1973; 3553;

Boiling Point (15 of 18)
Boiling Point140
Pressure4
Citation Pointer3339628; Journal; Ramaiah; Nigam; RSARAQ; Riechst.Aromen; 22; 1972; 71,74;3615219; Journal; Narasimha; Nigam; RSARAQ; Riechst.Aromen; 22; 1972; 231,236;

Boiling Point (16 of 18)
Boiling Point145
Pressure4.5
Citation Pointer3737643; Journal; Nigam; Ramaiah; RSARAQ; Riechst.Aromen; 22; 1972; 378,388;

Boiling Point (17 of 18)
Boiling Point69 - 70
Pressure1.5
CommentHandbook
Citation Pointer512137; Journal; Naves; Ardizio; BSCFAS; Bull.Soc.Chim.Fr.; 1957; 1053, 1056;

Boiling Point (18 of 18)
Boiling Point90
Pressure2
Citation Pointer4204275; Journal; Biniecki; Krajewski; APPHAX; Acta Pol.Pharm.; 17; 1960; 421,422, 423; Chem.Abstr.; 55; 14350; 1961;

Density of the Liquid (1 of 11)
Density of the Liquid1.104
Commentg/cm**3
Citation Pointer4298940; Journal; Baslas; Baslas; RSARAQ; Riechst.Aromen; 22; 1972; 155,156,158;3339630; Journal; Baslas; Baslas; RSARAQ; Riechst.Aromen; 22; 1972; 200,202;

Density of the Liquid (2 of 11)
Density of the Liquid1.114
Measurement Temperature0
Commentg/cm**3; Handbook
Citation Pointer500494; Journal; Grimaux; Ruotte; BSCFAS; Bull.Soc.Chim.Fr.; <2> 11; 1869; 465; JLACBF; Justus Liebigs Ann. Chem.; 152; 1869; 91;

Density of the Liquid (3 of 11)
Density of the Liquid1.11
Measurement Temperature12
Commentg/cm**3; Handbook
Citation Pointer500454; Journal; Eijkman; CHBEAM; Chem.Ber.; 23; 1890; 862;

Density of the Liquid (4 of 11)
Density of the Liquid1.106
Measurement Temperature15
Commentg/cm**3; Handbook
Citation Pointer500507; Journal; Schimmel & Co.; CHZEA6; Chem.Zentralbl.; GE; 73; I; 1902; 1060;

Density of the Liquid (5 of 11)
Density of the Liquid1.0988
Reference Temperature18
Measurement Temperature18
Citation Pointer3339628; Journal; Ramaiah; Nigam; RSARAQ; Riechst.Aromen; 22; 1972; 71,74;

Density of the Liquid (6 of 11)
Density of the Liquid1.103
Measurement Temperature18
Commentg/cm**3
Citation Pointer3615042; Journal; Koul; Nigam; RSARAQ; Riechst.Aromen; 17; 1967; 269,270;

Density of the Liquid (7 of 11)
Density of the Liquid1.1
Reference Temperature20
Measurement Temperature20
Citation Pointer3615219; Journal; Narasimha; Nigam; RSARAQ; Riechst.Aromen; 22; 1972; 231,236;

Density of the Liquid (8 of 11)
Density of the Liquid1.1
Reference Temperature4
Measurement Temperature20
CommentHandbook
Citation Pointer506391; Journal; Waterman; Priester; RTCPA3; Recl.Trav.Chim.Pays-Bas; 47; 1928; 1033;

Density of the Liquid (9 of 11)
Density of the Liquid1.0993
Reference Temperature4
Measurement Temperature20
CommentHandbook
Citation Pointer512137; Journal; Naves; Ardizio; BSCFAS; Bull.Soc.Chim.Fr.; 1957; 1053, 1056;

Density of the Liquid (10 of 11)
Density of the Liquid1.0329
Reference Temperature25
Measurement Temperature25
Citation Pointer3737643; Journal; Nigam; Ramaiah; RSARAQ; Riechst.Aromen; 22; 1972; 378,388;

Density of the Liquid (11 of 11)
Density of the Liquid1.095
Reference Temperature4
Measurement Temperature25
CommentHandbook
Citation Pointer1675032; Journal; Dunstan; Hilditch; ZEAPAA; Z.Elektrochem.Angew.Phys.Chem.; 18; 1912; 187;

Mechanical Properties (1 of 1)
DescriptionViscosity
Citation Pointer3615042; Journal; Koul; Nigam; RSARAQ; Riechst.Aromen; 17; 1967; 269,270;

Surface Tension (1 of 1)
Citation Pointer3615042; Journal; Koul; Nigam; RSARAQ; Riechst.Aromen; 17; 1967; 269,270;

Dynamic Viscosity (1 of 1)
Dynamic Viscosity0.0229
Temperature25
CommentHandbook
Citation Pointer1675032; Journal; Dunstan; Hilditch; ZEAPAA; Z.Elektrochem.Angew.Phys.Chem.; 18; 1912; 187;

Other Thermochemical Data (1 of 2)
DescriptionCryoscopic constant
Commentfuer 1 kg Loesungsmittel: 5.7.; Handbook
Citation Pointer506400; Journal; Sanderson; Jones; JSCIAN; J.Soc.Chem.Ind.London; 42; 1923; 1 T;

Other Thermochemical Data (2 of 2)
DescriptionHeat of combustion at constant volume
Comment1243.8 kcal/Mol.; Handbook
Citation Pointer500506; Journal; Stohmann; ZEPCAC; Z.Phys.Chem.Stoechiom.Verwandtschaftsl.; 10; 1892; 415;

Refractive Index (1 of 27)
Refractive Index1.53
Citation Pointer4298940; Journal; Baslas; Baslas; RSARAQ; Riechst.Aromen; 22; 1972; 155,156,158;

Refractive Index (2 of 27)
Refractive Index1.5369
Wavelength656.3
Temperature12
CommentHandbook
Citation Pointer500454; Journal; Eijkman; CHBEAM; Chem.Ber.; 23; 1890; 862;

Refractive Index (3 of 27)
Refractive Index1.5339
Wavelength656.3
Temperature19
CommentHandbook
Citation Pointer1528845; Journal; Cotton; Mouton; ANCPAC; Ann.Chim.(Paris); <8> 28; 1913; 215;

Refractive Index (4 of 27)
Refractive Index1.5331
Wavelength656.3
Temperature20
CommentHandbook
Citation Pointer506391; Journal; Waterman; Priester; RTCPA3; Recl.Trav.Chim.Pays-Bas; 47; 1928; 1033;

Refractive Index (5 of 27)
Refractive Index1.53191
Wavelength656.3
Temperature20
CommentHandbook
Citation Pointer512137; Journal; Naves; Ardizio; BSCFAS; Bull.Soc.Chim.Fr.; 1957; 1053, 1056;

Refractive Index (6 of 27)
Refractive Index1.536
Wavelength589
Citation Pointer3339630; Journal; Baslas; Baslas; RSARAQ; Riechst.Aromen; 22; 1972; 200,202;

Refractive Index (7 of 27)
Refractive Index1.542
Wavelength589
Temperature12
CommentHandbook
Citation Pointer500454; Journal; Eijkman; CHBEAM; Chem.Ber.; 23; 1890; 862;

Refractive Index (8 of 27)
Refractive Index1.543
Wavelength589
Temperature14
CommentHandbook
Citation Pointer504613; Journal; Abati; GCITA9; Gazz.Chim.Ital.; 40 II; 1910; 92;

Refractive Index (9 of 27)
Refractive Index1.5392
Wavelength589
Temperature17.5
CommentHandbook
Citation Pointer500507; Journal; Schimmel & Co.; CHZEA6; Chem.Zentralbl.; GE; 73; I; 1902; 1060;

Refractive Index (10 of 27)
Refractive Index1.536
Wavelength589
Temperature18
Citation Pointer3339628; Journal; Ramaiah; Nigam; RSARAQ; Riechst.Aromen; 22; 1972; 71,74;

Refractive Index (11 of 27)
Refractive Index1.5389
Wavelength589
Temperature18
Citation Pointer3214879; Journal; Feugeas; BSCFAS; Bull.Soc.Chim.Fr.; 1964; 1892;

Refractive Index (12 of 27)
Refractive Index1.539
Wavelength589
Temperature19
CommentHandbook
Citation Pointer1528845; Journal; Cotton; Mouton; ANCPAC; Ann.Chim.(Paris); <8> 28; 1913; 215;

Refractive Index (13 of 27)
Refractive Index1.538
Wavelength589
Temperature20
Citation Pointer3281959; Journal; Fujita; Yamashita; BCSJA8; Bull.Chem.Soc.Jpn.; 46; 1973; 3553;

Refractive Index (14 of 27)
Refractive Index1.5351
Wavelength589
Temperature20
Citation Pointer3615219; Journal; Narasimha; Nigam; RSARAQ; Riechst.Aromen; 22; 1972; 231,236;

Refractive Index (15 of 27)
Refractive Index1.5366
Wavelength589
Temperature20
Citation Pointer3614964; Journal; Messerschmidt; ARZNAD; Arzneim.Forsch.; 18; 1968; 1618;

Refractive Index (16 of 27)
Refractive Index1.5385
Wavelength589
Temperature20
Citation Pointer3215042; Journal; Bochwic; Kapuscinski; ROCHAC; Rocz.Chem.; 39; 1965; 1251,1255; Chem.Abstr.; 64; 12656;

Refractive Index (17 of 27)
Refractive Index1.5381
Wavelength589
Temperature20
CommentHandbook
Citation Pointer506403; Journal; Perkin; Trikojus; JCSOA9; J.Chem.Soc.; 1927; 1665;

Refractive Index (18 of 27)
Refractive Index1.5383
Wavelength589
Temperature20
CommentHandbook
Citation Pointer506391; Journal; Waterman; Priester; RTCPA3; Recl.Trav.Chim.Pays-Bas; 47; 1928; 1033;

Refractive Index (19 of 27)
Refractive Index1.53738
Wavelength589
Temperature20
CommentHandbook
Citation Pointer512137; Journal; Naves; Ardizio; BSCFAS; Bull.Soc.Chim.Fr.; 1957; 1053, 1056;

Refractive Index (20 of 27)
Refractive Index1.5378
Wavelength589
Temperature24
Citation Pointer4204275; Journal; Biniecki; Krajewski; APPHAX; Acta Pol.Pharm.; 17; 1960; 421,422, 423; Chem.Abstr.; 55; 14350; 1961;

Refractive Index (21 of 27)
Refractive Index1.536
Wavelength589
Temperature25
Citation Pointer3737643; Journal; Nigam; Ramaiah; RSARAQ; Riechst.Aromen; 22; 1972; 378,388;

Refractive Index (22 of 27)
Refractive Index1.5557
Wavelength486.1
Temperature12
CommentHandbook
Citation Pointer500454; Journal; Eijkman; CHBEAM; Chem.Ber.; 23; 1890; 862;

Refractive Index (23 of 27)
Refractive Index1.5526
Wavelength486.1
Temperature19
CommentHandbook
Citation Pointer1528845; Journal; Cotton; Mouton; ANCPAC; Ann.Chim.(Paris); <8> 28; 1913; 215;

Refractive Index (24 of 27)
Refractive Index1.5518
Wavelength486.1
Temperature20
CommentHandbook
Citation Pointer506391; Journal; Waterman; Priester; RTCPA3; Recl.Trav.Chim.Pays-Bas; 47; 1928; 1033;

Refractive Index (25 of 27)
Refractive Index1.55064
Wavelength486.1
Temperature20
CommentHandbook
Citation Pointer512137; Journal; Naves; Ardizio; BSCFAS; Bull.Soc.Chim.Fr.; 1957; 1053, 1056;

Refractive Index (26 of 27)
Refractive Index1.5679
Wavelength434
Temperature12
CommentHandbook
Citation Pointer500454; Journal; Eijkman; CHBEAM; Chem.Ber.; 23; 1890; 862;

Refractive Index (27 of 27)
Refractive Index1.5638
Wavelength434
Temperature20
CommentHandbook
Citation Pointer506391; Journal; Waterman; Priester; RTCPA3; Recl.Trav.Chim.Pays-Bas; 47; 1928; 1033;

Optics (1 of 2)
DescriptionMagnetic birefringence (Cotton-Mouton effect)
CommentHandbook
Citation Pointer1528845; Journal; Cotton; Mouton; ANCPAC; Ann.Chim.(Paris); <8> 28; 1913; 215;

Optics (2 of 2)
DescriptionElectric birefringence (Kerr effect)
CommentKerr-Konstante.; Handbook
Citation Pointer542472; Journal; Pauthenier; Bart; COREAF; C.R.Hebd.Seances Acad.Sci.; 192; 1931; 352;

Optical Rotatory Power (1 of 1)
Type[alpha]
Optical Rotatory Power0
Wavelength589
Temperature25
Citation Pointer3737643; Journal; Nigam; Ramaiah; RSARAQ; Riechst.Aromen; 22; 1972; 378,388;

Nuclear Magnetic Resonance (1 of 4)
DescriptionChemical shifts
Nucleus1H
SolventsCDCl3
Citation Pointer6055384; Journal; Sy, Lai-King; Saunders, Richard M. K.; Brown, Geoffrey D.; PYTCAS; Phytochemistry; EN; 44; 6; 1997; 1099-1108;

Nuclear Magnetic Resonance (2 of 4)
DescriptionChemical shifts
Nucleus13C
SolventsCDCl3
Citation Pointer6055384; Journal; Sy, Lai-King; Saunders, Richard M. K.; Brown, Geoffrey D.; PYTCAS; Phytochemistry; EN; 44; 6; 1997; 1099-1108;

Nuclear Magnetic Resonance (3 of 4)
DescriptionChemical shifts
Nucleus13C
Citation Pointer5668828; Journal; Yakushijin, Kenichi; Tohshima, Tomoko; Suzuki, Rika; Murata, Hiroyuki; Lu, Sheng-Ten; Furukawa, Hiroshi; CPBTAL; Chem.Pharm.Bull.; EN; 31; 8; 1983; 2879-2883;

Nuclear Magnetic Resonance (4 of 4)
DescriptionNMR
Citation Pointer3614708; Journal; Femino et al.; STEDAM; Steroids; 23; 1974; 869,876;

Infrared Spectra (1 of 5)
DescriptionSpectrum
Comment1700 - 700 cm**(-1); Handbook
Citation Pointer512137; Journal; Naves; Ardizio; BSCFAS; Bull.Soc.Chim.Fr.; 1957; 1053, 1056;

Infrared Spectra (2 of 5)
DescriptionBands
SolventCCl4
Comment2910 - 2780 cm**(-1); Handbook
Citation Pointer511899; Journal; Briggs et al.; ANCHAM; Anal.Chem.; 29; 1957; 904, 905;

Infrared Spectra (3 of 5)
DescriptionBands
Solventneat (no solvent)
Comment1440 - 710 cm**(-1); Handbook
Citation Pointer511899; Journal; Briggs et al.; ANCHAM; Anal.Chem.; 29; 1957; 904, 905;

Infrared Spectra (4 of 5)
DescriptionBands
Comment1640 - 770 cm**(-1); Handbook
Citation Pointer512137; Journal; Naves; Ardizio; BSCFAS; Bull.Soc.Chim.Fr.; 1957; 1053, 1056;

Infrared Spectra (5 of 5)
DescriptionIR
Citation Pointer3271856; Journal; Noguchi; Kitajima; NIRKAA; Nippon Rin Gakkaishi; 41; 1959; 488,489-494; Chem.Abstr.; 25075; 1960;3614687; Journal; Fujita; Fujita; CPBTAL; Chem.Pharm.Bull.; 20; 1972; 2251;3614964; Journal; Messerschmidt; ARZNAD; Arzneim.Forsch.; 18; 1968; 1618;3281959; Journal; Fujita; Yamashita; BCSJA8; Bull.Chem.Soc.Jpn.; 46; 1973; 3553;

Raman (1 of 1)
DescriptionBands
CommentHandbook
Citation Pointer542467; Journal; Chabeau; Bl. Acad. Med. Belgique; <6> 3; 1938; 46, 64;1996606; Journal; Susz; Perrottet; Briner; HCACAV; Helv.Chim.Acta; 19; 1936; 548,554,556;1702578; Journal; Dupont; Dulou; BSCFAS; Bull.Soc.Chim.Fr.; <5> 3; 1936; 1639, 1659;542470; Journal; Morris; Phys. Rad.; <2> 38; 1931; 141, 143;

Ultraviolet Spectra (1 of 9)
DescriptionSpectrum
Solventethanol
CommentHandbook
Citation Pointer504616; Journal; Crymble; Stewart; Wright; Glendinning; So.; 99; 455;

Ultraviolet Spectra (2 of 9)
DescriptionSpectrum
CommentHandbook
Citation Pointer506402; Journal; Ramart-Lucas; Amagat; COREAF; C.R.Hebd.Seances Acad.Sci.; 188; 1929; 639;

Ultraviolet Spectra (3 of 9)
DescriptionSpectrum
Comment1000 - 15000 nm; im Ultrarot.; Handbook
Citation Pointer506401; Book Review / Secondary Ref.; Coblentz,W. W.; Investigations of infra-red-spectra <Washington 1905>, S. 81, 140, 164, 241;

Ultraviolet Spectra (4 of 9)
DescriptionSpectrum
Solventhexane
Comment220 - 310 nm; Handbook
Citation Pointer520055; Journal; Herzog; Hillmer; CHBEAM; Chem.Ber.; 64; 1931; 1288, 1305;542466; Journal; Hillmer; Schorning; ZPCAAI; Z.Phys.Chem.Abt.A; 167; 1934; 407, 415;

Ultraviolet Spectra (5 of 9)
DescriptionSpectrum
Comment240 - 320 nm; Handbook
Citation Pointer1577138; Journal; Ramart-Lucas; Amagat; BSCFAS; Bull.Soc.Chim.Fr.; <4> 51; 1932; 108, 117;

Ultraviolet Spectra (6 of 9)
DescriptionAbsorption maxima
Solventethanol
Absorption Maxima236; 285
CommentHandbook
Citation Pointer512137; Journal; Naves; Ardizio; BSCFAS; Bull.Soc.Chim.Fr.; 1957; 1053, 1056;

Ultraviolet Spectra (7 of 9)
DescriptionAbsorption maxima
Solvent2,2,4-trimethyl-pentane
Absorption Maxima236.5; 285; 289
CommentHandbook
Citation Pointer512137; Journal; Naves; Ardizio; BSCFAS; Bull.Soc.Chim.Fr.; 1957; 1053, 1056;

Ultraviolet Spectra (8 of 9)
DescriptionAbsorption maxima
Solventethanol
Absorption Maxima237; 286
CommentHandbook
Citation Pointer519374; Journal; Patterson; Hibbert; JACSAT; J.Amer.Chem.Soc.; 65; 1943; 1862, 1864;

Ultraviolet Spectra (9 of 9)
DescriptionUV/VIS
Citation Pointer3614964; Journal; Messerschmidt; ARZNAD; Arzneim.Forsch.; 18; 1968; 1618;

Fluorescence (1 of 1)
DescriptionMaxima
Solventacetonitrile; various solvent(s)
Comment330 nm
Citation Pointer5812901; Journal; Schreiber-Deturmeny, E. M.; Pauli, A. M.; Pastor, J. L.; JPMSAE; J.Pharm.Sci.; EN; 82; 8; 1993; 813-816;

Mass Spectrum (1 of 1)
Descriptionspectrum; chemical ionization (CI)
Citation Pointer5710291; Journal; Lange, G.; Schultze, W.; ORMSBG; Org.Mass Spectrom.; EN; 27; 4; 1992; 481-488;

Electrochemical Characteristics (1 of 2)
Descriptionoxidation potential
Solventacetonitrile; various solvent(s)
Temperature20
Citation Pointer6191842; Journal; Rudenko, A. P.; Pragst, F.; RJOCEQ; Russ.J.Org.Chem.; EN; 34; 11; 1998; 1589 - 1626; ZORKAE; Zh.Org.Khim.; RU; 34; 11; 1998; 1660 - 1696;

Electrochemical Characteristics (2 of 2)
Descriptionredox potential
Solventacetonitrile
Product BRN1577733
Product4'-Allyl-1,3-benzodioxol
Comment1.4 V; Product: /BRN= 1577733/. Method: cyclovoltammetry. Description: Pt electrode vs. SCE, 0.1M Bu4NClO4
Citation Pointer5959025; Journal; Yan, Bao-Zhen; Zhang, Zhao-Guo; Yuan, Han-Cheng; Wang, Long-Cheng; Xu, Jian-Hua; JCPKBH; J.Chem.Soc.Perkin Trans.2; EN; 12; 1994; 2545-2550;

Further Information (1 of 1)
Citation Pointer3220457; Journal; Voronkov; Lapina; CHCCAL; Chem.Heterocycl.Compd.(Engl.Transl.); 2; 1966; 390,391; KGSSAQ; Khim.Geterotsikl.Soedin.; 2; 1966; 522;3614815; Journal; Takegami et al.; BCSJA8; Bull.Chem.Soc.Jpn.; 38; 1965; 1279,1281, 1282;3614816; Journal; ?orjaschtschew, Woronin; JACUAZ; J.Anal.Chem.USSR (Engl.Transl.); 18; 1963; 351; ZAKHA8; Zh.Anal.Khim.; 18; 1963; 401;

Liquid/Vapour Systems (MCS) (1 of 1)
DescriptionBoiling points of mixtures
Partner BRN969616
Partnerphenol
Pressure10
CommentHandbook
Citation Pointer542461; Journal; Brauer; Ber. Schimmel; 1929; 151, 160;

Azeotropes (MCS) (1 of 21)
Azeotropesglycol
Temperature190.1
Pressure760
CommentHandbook
Citation Pointer1543242; Journal; Meerwein; JPCEAO; J.Prakt.Chem.; <2> 113; 1926; 11, 25;

Azeotropes (MCS) (2 of 21)
Azeotropeswater
Temperature99.7
Pressure760
CommentHandbook
Citation Pointer1543242; Journal; Meerwein; JPCEAO; J.Prakt.Chem.; <2> 113; 1926; 11, 25;

Azeotropes (MCS) (3 of 21)
Azeotropesacetamide
Temperature208.8
Pressure760
CommentHandbook
Citation Pointer1543242; Journal; Meerwein; JPCEAO; J.Prakt.Chem.; <2> 113; 1926; 11, 25;

Azeotropes (MCS) (4 of 21)
Azeotropesglycerol
Temperature231.2
Pressure760
CommentHandbook
Citation Pointer1543242; Journal; Meerwein; JPCEAO; J.Prakt.Chem.; <2> 113; 1926; 11, 25;

Azeotropes (MCS) (5 of 21)
Azeotropespropionamide
Temperature213
Pressure760
CommentHandbook
Citation Pointer1543242; Journal; Meerwein; JPCEAO; J.Prakt.Chem.; <2> 113; 1926; 11, 25;

Azeotropes (MCS) (6 of 21)
Azeotropeso-phenetidine
Temperature232.4
Pressure760
CommentHandbook
Citation Pointer1543242; Journal; Meerwein; JPCEAO; J.Prakt.Chem.; <2> 113; 1926; 11, 25;

Azeotropes (MCS) (7 of 21)
Azeotropesbenzoic acid
Temperature234.8
Pressure760
CommentHandbook
Citation Pointer1543242; Journal; Meerwein; JPCEAO; J.Prakt.Chem.; <2> 113; 1926; 11, 25;

Azeotropes (MCS) (8 of 21)
Azeotropescaprylic acid
Temperature232.5
Pressure760
CommentHandbook
Citation Pointer1543242; Journal; Meerwein; JPCEAO; J.Prakt.Chem.; <2> 113; 1926; 11, 25;

Azeotropes (MCS) (9 of 21)
Azeotropespyrocatechol
Temperature233.6
Pressure760
CommentHandbook
Citation Pointer1543242; Journal; Meerwein; JPCEAO; J.Prakt.Chem.; <2> 113; 1926; 11, 25;

Azeotropes (MCS) (10 of 21)
Azeotropes4-nitro-toluene
Temperature234.5
Pressure760
CommentHandbook
Citation Pointer1543242; Journal; Meerwein; JPCEAO; J.Prakt.Chem.; <2> 113; 1926; 11, 25;

Azeotropes (MCS) (11 of 21)
Azeotropesethyl salicylate
Temperature233.8
Pressure760
CommentHandbook
Citation Pointer1543242; Journal; Meerwein; JPCEAO; J.Prakt.Chem.; <2> 113; 1926; 11, 25;

Azeotropes (MCS) (12 of 21)
Azeotropesquinoline
CommentHandbook
Citation Pointer533600; Book Review / Secondary Ref.; Lecat,M.; Tables azeotropiques, 2. Aufl. <Bruessel 1949>;

Azeotropes (MCS) (13 of 21)
Azeotropesheptanoic acid
CommentHandbook
Citation Pointer533600; Book Review / Secondary Ref.; Lecat,M.; Tables azeotropiques, 2. Aufl. <Bruessel 1949>;

Azeotropes (MCS) (14 of 21)
Azeotropeslevulinic acid
CommentHandbook
Citation Pointer533600; Book Review / Secondary Ref.; Lecat,M.; Tables azeotropiques, 2. Aufl. <Bruessel 1949>;

Azeotropes (MCS) (15 of 21)
Azeotropes4-bromo-phenetole
CommentHandbook
Citation Pointer533600; Book Review / Secondary Ref.; Lecat,M.; Tables azeotropiques, 2. Aufl. <Bruessel 1949>;

Azeotropes (MCS) (16 of 21)
Azeotropesdiethylene glycol
CommentHandbook
Citation Pointer533600; Book Review / Secondary Ref.; Lecat,M.; Tables azeotropiques, 2. Aufl. <Bruessel 1949>;

Azeotropes (MCS) (17 of 21)
Azeotropes3-phenyl-propan-1-ol
CommentHandbook
Citation Pointer533600; Book Review / Secondary Ref.; Lecat,M.; Tables azeotropiques, 2. Aufl. <Bruessel 1949>;

Azeotropes (MCS) (18 of 21)
AzeotropesO-methyl-triethylene glycol
CommentHandbook
Citation Pointer533600; Book Review / Secondary Ref.; Lecat,M.; Tables azeotropiques, 2. Aufl. <Bruessel 1949>;

Azeotropes (MCS) (19 of 21)
Azeotropesbis-<2-hydroxy-propyl>-ether
CommentHandbook
Citation Pointer533600; Book Review / Secondary Ref.; Lecat,M.; Tables azeotropiques, 2. Aufl. <Bruessel 1949>;

Azeotropes (MCS) (20 of 21)
Azeotropescarbonic acid diisopentyl ether
CommentHandbook
Citation Pointer533600; Book Review / Secondary Ref.; Lecat,M.; Tables azeotropiques, 2. Aufl. <Bruessel 1949>;

Azeotropes (MCS) (21 of 21)
Azeotropesbenzyl alcohol
CommentHandbook
Citation Pointer542459; Journal; Brauer; Ber. Schimmel; 1929; 151, 156;

Transport Phenomena (MCS) (1 of 2)
DescriptionViscosity
Citation Pointer3615042; Journal; Koul; Nigam; RSARAQ; Riechst.Aromen; 17; 1967; 269,270;

Transport Phenomena (MCS) (2 of 2)
DescriptionViscosity
Partner BRN1744750
Partner1-acetoxy-3-methyl-butane
CommentHandbook
Citation Pointer1675032; Journal; Dunstan; Hilditch; ZEAPAA; Z.Elektrochem.Angew.Phys.Chem.; 18; 1912; 187;

Energy Data (MCS) (1 of 1)
DescriptionEnthalpy of mixtures
Partner BRN4921393
PartnerO3
CommentHandbook
Citation Pointer1568862; Journal; Briner; Ryffel; de Nemitz; HCACAV; Helv.Chim.Acta; 21; 1938; 357, 362;

Association (MCS) (1 of 3)
DescriptionStability constant of the complex with ...
Partner BRN393006
Partner2,3,5,6-tetrachloro-[1,4]benzoquinone
SolventCCl4
Citation Pointer5959025; Journal; Yan, Bao-Zhen; Zhang, Zhao-Guo; Yuan, Han-Cheng; Wang, Long-Cheng; Xu, Jian-Hua; JCPKBH; J.Chem.Soc.Perkin Trans.2; EN; 12; 1994; 2545-2550;

Association (MCS) (2 of 3)
DescriptionNMR spectrum of the complex
Partner BRN393006
Partner2,3,5,6-tetrachloro-[1,4]benzoquinone
Solventbenzene-d6
Citation Pointer5959025; Journal; Yan, Bao-Zhen; Zhang, Zhao-Guo; Yuan, Han-Cheng; Wang, Long-Cheng; Xu, Jian-Hua; JCPKBH; J.Chem.Soc.Perkin Trans.2; EN; 12; 1994; 2545-2550;

Association (MCS) (3 of 3)
DescriptionUV/VIS spectrum of the complex
Partner BRN393006
Partner2,3,5,6-tetrachloro-[1,4]benzoquinone
SolventCCl4
Citation Pointer5959025; Journal; Yan, Bao-Zhen; Zhang, Zhao-Guo; Yuan, Han-Cheng; Wang, Long-Cheng; Xu, Jian-Hua; JCPKBH; J.Chem.Soc.Perkin Trans.2; EN; 12; 1994; 2545-2550;

Pharmacological Data (1 of 41)
Citation Pointer6337204; Journal; Uchida, Mihoko; Nakajin, Shizuo; Toyoshima, Satoshi; Shinoda, Masato; BPBLEO; Biol.Pharm.Bull.; EN; 19; 4; 1996; 623 - 626;

Pharmacological Data (2 of 41)
Citation Pointer6337204; Journal; Uchida, Mihoko; Nakajin, Shizuo; Toyoshima, Satoshi; Shinoda, Masato; BPBLEO; Biol.Pharm.Bull.; EN; 19; 4; 1996; 623 - 626;

Pharmacological Data (3 of 41)
Citation Pointer6337204; Journal; Uchida, Mihoko; Nakajin, Shizuo; Toyoshima, Satoshi; Shinoda, Masato; BPBLEO; Biol.Pharm.Bull.; EN; 19; 4; 1996; 623 - 626;

Pharmacological Data (4 of 41)
Citation Pointer6337204; Journal; Uchida, Mihoko; Nakajin, Shizuo; Toyoshima, Satoshi; Shinoda, Masato; BPBLEO; Biol.Pharm.Bull.; EN; 19; 4; 1996; 623 - 626;

Pharmacological Data (5 of 41)
Citation Pointer6326931; Journal; Johnson, Benjamin M.; Bolton, Judy L.; Breemen, Richard B. van; CRTOEC; Chem.Res.Toxicol.; EN; 14; 11; 2001; 1546 - 1551;

Pharmacological Data (6 of 41)
CommentNo effect
Citation Pointer6293904; Journal; Gardner, Iain; Bergin, Pauline; Stening, Peter; Kenna, J. Gerald; Caldwell, John; CRTOEC; Chem.Res.Toxicol.; EN; 9; 4; 1996; 713 - 721;

Pharmacological Data (7 of 41)
Citation Pointer6293904; Journal; Gardner, Iain; Bergin, Pauline; Stening, Peter; Kenna, J. Gerald; Caldwell, John; CRTOEC; Chem.Res.Toxicol.; EN; 9; 4; 1996; 713 - 721;

Pharmacological Data (8 of 41)
Citation Pointer6285944; Journal; Daimon, Hirohiko; Sawada, Shigeki; Asakura, Shoji; Sagami, Fumio; TCMUD8; Teratoc.Carcinog.Mutagen.; EN; 17; 1; 1997; 7 - 18;

Pharmacological Data (9 of 41)
Citation Pointer6260236; Journal; Lee, Mei-Sie; CRTOEC; Chem.Res.Toxicol.; EN; 9; 7; 1996; 1072 - 1078;

Pharmacological Data (10 of 41)
Citation Pointer6252128; Journal; Uhl, Maria; Helma, Christoph; Knasmueller, Siegfried; MUREAV; Mutat.Res.; EN; 468; 2; 2000; 213 - 226;

Pharmacological Data (11 of 41)
CommentNo effect
Citation Pointer6231639; Journal; Watanabe, Kazuko; Sasaki, Toshiaki; Kawakami, Kumiko; MUREAV; Mutat.Res.; EN; 416; 3; 1998; 169 - 182;

Pharmacological Data (12 of 41)
CommentNo effect
Citation Pointer6231639; Journal; Watanabe, Kazuko; Sasaki, Toshiaki; Kawakami, Kumiko; MUREAV; Mutat.Res.; EN; 416; 3; 1998; 169 - 182;

Pharmacological Data (13 of 41)
CommentNo effect
Citation Pointer6231639; Journal; Watanabe, Kazuko; Sasaki, Toshiaki; Kawakami, Kumiko; MUREAV; Mutat.Res.; EN; 416; 3; 1998; 169 - 182;

Pharmacological Data (14 of 41)
CommentNo effect
Citation Pointer6231639; Journal; Watanabe, Kazuko; Sasaki, Toshiaki; Kawakami, Kumiko; MUREAV; Mutat.Res.; EN; 416; 3; 1998; 169 - 182;

Pharmacological Data (15 of 41)
Citation Pointer6212399; Journal; Liu, T. Y.; Chen, C. C.; Chen, C. L.; Chi, C. W.; FCTOD7; Food Chem.Toxicol.; EN; 37; 7; 1999; 697 - 702;

Pharmacological Data (16 of 41)
Citation Pointer6212314; Journal; Nesslany, Fabrice; Marzin, Daniel; MUTAEX; Mutagenesis; EN; 14; 4; 1999; 403 - 410;

Pharmacological Data (17 of 41)
Citation Pointer6212314; Journal; Nesslany, Fabrice; Marzin, Daniel; MUTAEX; Mutagenesis; EN; 14; 4; 1999; 403 - 410;

Pharmacological Data (18 of 41)
Citation Pointer6206531; Journal; Zacchino, Susana A.; Lopez, Silvia N.; Pezzenati, German D.; Furlan, Ricardo L.; Santecchia, Carina B.; Munoz, Lorena; Giannini, Fernando A.; Rodriguez, Ana M.; Enriz, Ricardo D.; JNPRDF; J.Nat.Prod.; EN; 62; 10; 1999; 1353 - 1357;

Pharmacological Data (19 of 41)
Citation Pointer6206531; Journal; Zacchino, Susana A.; Lopez, Silvia N.; Pezzenati, German D.; Furlan, Ricardo L.; Santecchia, Carina B.; Munoz, Lorena; Giannini, Fernando A.; Rodriguez, Ana M.; Enriz, Ricardo D.; JNPRDF; J.Nat.Prod.; EN; 62; 10; 1999; 1353 - 1357;

Pharmacological Data (20 of 41)
Citation Pointer6206531; Journal; Zacchino, Susana A.; Lopez, Silvia N.; Pezzenati, German D.; Furlan, Ricardo L.; Santecchia, Carina B.; Munoz, Lorena; Giannini, Fernando A.; Rodriguez, Ana M.; Enriz, Ricardo D.; JNPRDF; J.Nat.Prod.; EN; 62; 10; 1999; 1353 - 1357;

Pharmacological Data (21 of 41)
Citation Pointer6206531; Journal; Zacchino, Susana A.; Lopez, Silvia N.; Pezzenati, German D.; Furlan, Ricardo L.; Santecchia, Carina B.; Munoz, Lorena; Giannini, Fernando A.; Rodriguez, Ana M.; Enriz, Ricardo D.; JNPRDF; J.Nat.Prod.; EN; 62; 10; 1999; 1353 - 1357;

Pharmacological Data (22 of 41)
Citation Pointer6206531; Journal; Zacchino, Susana A.; Lopez, Silvia N.; Pezzenati, German D.; Furlan, Ricardo L.; Santecchia, Carina B.; Munoz, Lorena; Giannini, Fernando A.; Rodriguez, Ana M.; Enriz, Ricardo D.; JNPRDF; J.Nat.Prod.; EN; 62; 10; 1999; 1353 - 1357;

Pharmacological Data (23 of 41)
CommentNo effect
Citation Pointer6198523; Journal; Oberly, T. J.; Hoffman, W. P.; Garriott, M. L.; MUREAV; Mutat.Res.; EN; 369; 3,4; 1996; 221 - 232;

Pharmacological Data (24 of 41)
Citation Pointer6195092; Journal; Tayama, Sumiko; MUREAV; Mutat.Res.; EN; 368; 3-4; 1996; 249 - 260;

Pharmacological Data (25 of 41)
Citation Pointer6195092; Journal; Tayama, Sumiko; MUREAV; Mutat.Res.; EN; 368; 3-4; 1996; 249 - 260;

Pharmacological Data (26 of 41)
Citation Pointer6195092; Journal; Tayama, Sumiko; MUREAV; Mutat.Res.; EN; 368; 3-4; 1996; 249 - 260;

Pharmacological Data (27 of 41)
Citation Pointer6195092; Journal; Tayama, Sumiko; MUREAV; Mutat.Res.; EN; 368; 3-4; 1996; 249 - 260;

Pharmacological Data (28 of 41)
Citation Pointer6188762; Journal; Takasaki, Midori; Konoshima, Takao; Yasuda, Ichiro; Hamano, Tomoko; Tokuda, Harukuni; BPBLEO; Biol.Pharm.Bull.; EN; 20; 7; 1997; 776 - 780;

Pharmacological Data (29 of 41)
Citation Pointer6151740; Journal; Uno, Yoshifumi; Takasawa, Hironao; Miyagawa, Makoto; Inoue, Yuki; Murata, Taeko; Yoshikawa, Kunie; MUREAV; Mutat.Res.; EN; 320; 3; 1994; 189 - 206;

Pharmacological Data (30 of 41)
CommentNo effect
Citation Pointer6151677; Journal; Fritzenschaf, H.; Kohlpoth, M.; Rusche, B.; Schiffmann, D.; MUREAV; Mutat.Res.; EN; 319; 1; 1993; 47 - 54;

Pharmacological Data (31 of 41)
Citation Pointer6143321; Journal; Galli, Alvaro; Schiestl, Robert H.; MUREAV; Mutat.Res.; EN; 419; 1998; 53 - 68;

Pharmacological Data (32 of 41)
Citation Pointer6143321; Journal; Galli, Alvaro; Schiestl, Robert H.; MUREAV; Mutat.Res.; EN; 419; 1998; 53 - 68;

Pharmacological Data (33 of 41)
Citation Pointer6141950; Journal; Qato, Mazen K.; Guenthner, Thomas M.; TOLED5; Toxicol.Lett.; EN; 75; 1-3; 1995; 201 - 208;

Pharmacological Data (34 of 41)
Citation Pointer6131309; Journal; Sugimoto, Naoki; Goto, Yoshihisa; Akao, Nobuaki; Kiuchi, Fumiyuki; Kondo, Kaoru; Tsuda, Yoshisuke; BPBLEO; Biol.Pharm.Bull.; EN; 18; 4; 1995; 605 - 609;

Pharmacological Data (35 of 41)
Commentgenotoxic effects in the Drosofila melanogaster wing spot test at conc. 0.1-1.0 mM
Citation Pointer5960977; Journal; Batiste-Alentorn, M.; Xamena, N.; Creus, A.; Marcos, R.; EXPEAM; Experientia; EN; 51; 1; 1995; 73-76;

Pharmacological Data (36 of 41)
Commentinhibited the N-oxidation of diethylcarbamazine in male rats (intraperitoneally); enhancement in female rats (intraperitoneally)
Citation Pointer5941200; Journal; Joseph, C. A.; Dixon, P. A. F.; JPPMAB; J.Pharm.Pharmacol.; EN; 36; 36; 1984; 711-712;

Pharmacological Data (37 of 41)
CommentTribolium castaneum Herbst.; synergistic effects with natural pyrethrins
Citation Pointer5876781; Journal; Tomar, S. S.; Saxena, V. S.; ABCHA6; Agric.Biol.Chem.; EN; 50; 8; 1986; 2115-2116;

Pharmacological Data (38 of 41)
Commentantifungal effects at 27 deg C and 1.0-2.0 mM on growth of Blastomyces dermatitidis, Histoplasma capsulatum, Trichophyton rubrum (H), Fonsecaea pedrosoi (T), Penicillium frequentans, Penicillium cyclopium, no activity against Aspergillus nidulans
Citation Pointer5874320; Journal; Kurita, Nobuyuki; Miyaji, Makoto; Kurane, Ryuichiro; Takahara, Yoshimasa; ABCHA6; Agric.Biol.Chem.; EN; 45; 4; 1981; 945-952;

Pharmacological Data (39 of 41)
Commentno antifungal effect in the presence of 7-10percent NaCl against Aspergillus oryzae, niger and ochraceus, Penicillium citrinum, viridicatum and cyclopium, Fusarium graminearum, Aureobasidium pullulans, Paecilomyces lilacinus
Citation Pointer5873643; Journal; Kurita, Nobuyuki; Koike, Shigeru; ABCHA6; Agric.Biol.Chem.; EN; 46; 1; 1982; 159-166;

Pharmacological Data (40 of 41)
CommentMIC >200 mg/ml (against Streptococcus mutans)
Citation Pointer5725987; Journal; Hattori, Masao; Hada, Sumitra; Watahiki, Akiko; Ihara, Hitomi; Shu, Yue-Zhong; et al.; CPBTAL; Chem.Pharm.Bull.; EN; 34; 9; 1986; 3885-3893;

Pharmacological Data (41 of 41)
Commentantiplatelet aggregative activity (rabbit)
Citation Pointer5718667; Journal; Wu, Tian-Shung; Huang, Shiow-Chyn; Lai, Jeng-Shiow; Teng, Che-Ming; Ko, Feng-Nien; Kuoh, Chang-Sheng; PYTCAS; Phytochemistry; EN; 32; 2; 1993; 449-452;